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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(3-Ethylphenyl)-3-[3-(4-fluorophenyl)sulfanylpropanoylamino]thiourea —— C18H20FN3OS2
    1-(3-Ethylphenyl)-3-[3-(4-fluorophenyl)sulfanylpropanoylamino]thiourea
    —— (R)-(4-fluorophenyl)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methanol —— C11H12FN3OS
    (R)-(4-fluorophenyl)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methanol
    —— 1-(3-Fluoro-4-methylphenyl)-3-[3-(4-fluorophenyl)sulfanylpropanoylamino]thiourea —— C17H17F2N3OS2
    1-(3-Fluoro-4-methylphenyl)-3-[3-(4-fluorophenyl)sulfanylpropanoylamino]thiourea
    —— 1-(2-Ethylphenyl)-3-[[2-(4-methylphenyl)sulfanylacetyl]amino]thiourea —— C18H21N3OS2
    1-(2-Ethylphenyl)-3-[[2-(4-methylphenyl)sulfanylacetyl]amino]thiourea
    —— (S)-(4-fluorophenyl)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methanol —— C11H12FN3OS
    (S)-(4-fluorophenyl)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methanol
    —— 1-(2-Ethylphenyl)-3-[3-(4-fluorophenyl)sulfanylpropanoylamino]thiourea —— C18H20FN3OS2
    1-(2-Ethylphenyl)-3-[3-(4-fluorophenyl)sulfanylpropanoylamino]thiourea
    —— 1-(3-Fluoro-4-methylphenyl)-3-[[2-(2-fluorophenyl)sulfanylacetyl]amino]thiourea —— C16H15F2N3OS2
    1-(3-Fluoro-4-methylphenyl)-3-[[2-(2-fluorophenyl)sulfanylacetyl]amino]thiourea
    —— (R)-(4-fluorophenyl)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methanamine —— C11H13FN4S
    (R)-(4-fluorophenyl)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methanamine
    —— (R)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-pyridin-4-ylmethanamine —— C10H13N5S
    (R)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-pyridin-4-ylmethanamine
    —— (S)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-pyridin-4-ylmethanamine —— C10H13N5S
    (S)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-pyridin-4-ylmethanamine
    —— (S)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-pyridin-4-ylmethanol —— C10H12N4OS
    (S)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-pyridin-4-ylmethanol
    —— 1-[3-(Dimethylamino)propyl]-3-[4-[3-(dimethylamino)propylcarbamothioylamino]cyclohexyl]thiourea —— C18H38N6S2
    1-[3-(Dimethylamino)propyl]-3-[4-[3-(dimethylamino)propylcarbamothioylamino]cyclohexyl]thiourea
    —— (R)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-pyridin-4-ylmethanol —— C10H12N4OS
    (R)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-pyridin-4-ylmethanol
    —— N-(4-ethylphenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C20H19N5OS2
    N-(4-ethylphenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-phenyl-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C18H15N5OS2
    N-phenyl-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-phenyl-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C18H15N5OS2
    N-phenyl-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C18H18N4OS3
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C16H16N4OS3
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C19H20N4OS3
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— 4-[(4-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine —— C15H17N5S2
    4-[(4-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine
    —— N-(3-methylphenyl)-5-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H26N4OS2
    N-(3-methylphenyl)-5-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— (R)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-phenylmethanol —— C11H13N3OS
    (R)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-phenylmethanol
    —— (S)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-phenylmethanol —— C11H13N3OS
    (S)-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-phenylmethanol
    —— 4-methyl-3-methylsulfanyl-5-[(2R)-2-phenyloxiran-2-yl]-1,2,4-triazole —— C12H13N3OS
    4-methyl-3-methylsulfanyl-5-[(2R)-2-phenyloxiran-2-yl]-1,2,4-triazole
    —— (2R)-4-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanenitrile —— C16H13N5OS3
    (2R)-4-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanenitrile
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylacetamide —— C16H23N5OS
    N-[[4-(dimethylamino)phenyl]methyl]-2-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylacetamide
    —— N-(3-methylphenyl)-5-[[(2R)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H27N4OS2+
    N-(3-methylphenyl)-5-[[(2R)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-(2,4-dimethylphenyl)-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C15H16N4OS2
    N-(2,4-dimethylphenyl)-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-(4-methylphenyl)-5-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H26N4OS2
    N-(4-methylphenyl)-5-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C18H20N4OS3
    2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— N-(4-methylphenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C19H17N5OS2
    N-(4-methylphenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-(2-methylphenyl)-5-[[(2R)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H27N4OS2+
    N-(2-methylphenyl)-5-[[(2R)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-(4-methylphenyl)-5-[[(2S)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H27N4OS2+
    N-(4-methylphenyl)-5-[[(2S)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-phenyl-5-[(2-thiophen-3-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C16H12N4S4
    N-phenyl-5-[(2-thiophen-3-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one —— C19H20N4O2S2
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one
    —— 2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C19H20N4OS3
    2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one —— C19H20N4O2S2
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one
    —— 3-[2-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]-1,3-oxazolidin-2-one —— C13H12N4O3S2
    3-[2-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]-1,3-oxazolidin-2-one
    —— N-(2,3-dimethylphenyl)-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C20H19N5OS2
    N-(2,3-dimethylphenyl)-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-phenyl-5-[(5-thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C16H12N4OS3
    N-phenyl-5-[(5-thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— (3R)-3-(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidine —— C11H18N4S
    (3R)-3-(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidine
    —— N-(2,4-dimethylphenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C20H19N5OS2
    N-(2,4-dimethylphenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-(4-methylphenyl)-5-[[(2R)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H27N4OS2+
    N-(4-methylphenyl)-5-[[(2R)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-(3-methylphenyl)-5-[[(2S)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H27N4OS2+
    N-(3-methylphenyl)-5-[[(2S)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C18H20N4OS3
    2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— N-(2-methylphenyl)-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C19H17N5OS2
    N-(2-methylphenyl)-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-(4-methylphenyl)-5-[[(2R)-4-(2-methylpropyl)morpholin-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C18H26N4OS2
    N-(4-methylphenyl)-5-[[(2R)-4-(2-methylpropyl)morpholin-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-(3,4-dimethylphenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C20H19N5OS2
    N-(3,4-dimethylphenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-(2-methylphenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C19H17N5OS2
    N-(2-methylphenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— 3-[2-[[5-(3,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-1,3-oxazolidin-2-one —— C15H16N4O3S2
    3-[2-[[5-(3,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-1,3-oxazolidin-2-one