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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(5-Methylthiophen-2-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone —— C15H12N2O2S2
    1-(5-Methylthiophen-2-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone
    —— 1-(5-Ethylthiophen-2-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone —— C16H14N2O2S2
    1-(5-Ethylthiophen-2-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone
    —— (1S,2S,3R)-2,3-dimethyl-1-oxo-N-(3-phenylsulfanylpropyl)-1,4-thiazinane-4-carboxamide —— C16H24N2O2S2
    (1S,2S,3R)-2,3-dimethyl-1-oxo-N-(3-phenylsulfanylpropyl)-1,4-thiazinane-4-carboxamide
    —— [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(5-methyl-1H-1,2,4-triazol-3-yl)methyl]piperazin-1-yl]methanone —— C17H21N5O2S
    [(2S)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(5-methyl-1H-1,2,4-triazol-3-yl)methyl]piperazin-1-yl]methanone
    —— (1S,2R,3S)-2,3-dimethyl-1-oxo-N-(3-phenylsulfanylpropyl)-1,4-thiazinane-4-carboxamide —— C16H24N2O2S2
    (1S,2R,3S)-2,3-dimethyl-1-oxo-N-(3-phenylsulfanylpropyl)-1,4-thiazinane-4-carboxamide
    —— (1S,2R,3R)-2,3-dimethyl-1-oxo-N-(3-phenylsulfanylpropyl)-1,4-thiazinane-4-carboxamide —— C16H24N2O2S2
    (1S,2R,3R)-2,3-dimethyl-1-oxo-N-(3-phenylsulfanylpropyl)-1,4-thiazinane-4-carboxamide
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(5-methyl-1H-1,2,4-triazol-3-yl)methyl]piperazin-1-yl]methanone —— C17H21N5O2S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[4-[(5-methyl-1H-1,2,4-triazol-3-yl)methyl]piperazin-1-yl]methanone
    —— (2S)-N-[(3S)-1,1-dioxo-2,3-dihydro-1-benzothiophen-3-yl]-2,3-dihydro-1,4-benzoxathiine-2-carboxamide —— C17H15NO4S2
    (2S)-N-[(3S)-1,1-dioxo-2,3-dihydro-1-benzothiophen-3-yl]-2,3-dihydro-1,4-benzoxathiine-2-carboxamide
    —— (2S)-N-[(3R)-1,1-dioxo-2,3-dihydro-1-benzothiophen-3-yl]-2,3-dihydro-1,4-benzoxathiine-2-carboxamide —— C17H15NO4S2
    (2S)-N-[(3R)-1,1-dioxo-2,3-dihydro-1-benzothiophen-3-yl]-2,3-dihydro-1,4-benzoxathiine-2-carboxamide
    —— (2R)-N-[(3R)-1,1-dioxo-2,3-dihydro-1-benzothiophen-3-yl]-2,3-dihydro-1,4-benzoxathiine-2-carboxamide —— C17H15NO4S2
    (2R)-N-[(3R)-1,1-dioxo-2,3-dihydro-1-benzothiophen-3-yl]-2,3-dihydro-1,4-benzoxathiine-2-carboxamide
    —— 1-methyl-2-[(2R)-2-phenylpropyl]sulfanylimidazole —— C13H16N2S
    1-methyl-2-[(2R)-2-phenylpropyl]sulfanylimidazole
    —— 1-methyl-2-[(2S)-2-phenylpropyl]sulfanylimidazole —— C13H16N2S
    1-methyl-2-[(2S)-2-phenylpropyl]sulfanylimidazole
    —— 2-(2-methyl-4-oxoquinazolin-3-yl)-N-(2-phenylsulfanylphenyl)acetamide —— C23H19N3O2S
    2-(2-methyl-4-oxoquinazolin-3-yl)-N-(2-phenylsulfanylphenyl)acetamide
    —— 1-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-[[(2R)-oxolan-2-yl]methyl]thiourea —— C15H18ClN5OS2
    1-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-[[(2R)-oxolan-2-yl]methyl]thiourea
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-[3-(dimethylamino)propyl]thiourea —— C15H21ClN6S2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-[3-(dimethylamino)propyl]thiourea
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-(furan-2-ylmethyl)thiourea —— C15H14ClN5OS2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-(furan-2-ylmethyl)thiourea
    —— 2-[[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]carbamothioylamino]ethyl-dimethylazanium —— C14H20ClN6S2+
    2-[[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]carbamothioylamino]ethyl-dimethylazanium
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-cyclopropylthiourea —— C13H14ClN5S2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-cyclopropylthiourea
    —— 3-[[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]carbamothioylamino]propyl-dimethylazanium —— C15H22ClN6S2+
    3-[[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]carbamothioylamino]propyl-dimethylazanium
    —— 1-Benzyl-3-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]thiourea —— C17H16ClN5S2
    1-Benzyl-3-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]thiourea
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-(2-morpholin-4-ium-4-ylethyl)thiourea —— C16H22ClN6OS2+
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-(2-morpholin-4-ium-4-ylethyl)thiourea
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-(2-fluorophenyl)thiourea —— C16H13ClFN5S2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-(2-fluorophenyl)thiourea
    —— 1-Butyl-3-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]thiourea —— C14H18ClN5S2
    1-Butyl-3-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]thiourea
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-methylthiourea —— C11H12ClN5S2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-methylthiourea
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-ethylthiourea —— C12H14ClN5S2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-ethylthiourea
    —— N-(2-benzylsulfanylethyl)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H20N4OS2
    N-(2-benzylsulfanylethyl)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C11H13N3OS2
    2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— 2-[[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C14H12N2O3S2
    2-[[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— N-(2-benzylsulfanylethyl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H19N3O3S2
    N-(2-benzylsulfanylethyl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N'-(5-chlorothiophen-2-yl)sulfonyl-2-(4-methylphenyl)sulfanylacetohydrazide —— C13H13ClN2O3S3
    N'-(5-chlorothiophen-2-yl)sulfonyl-2-(4-methylphenyl)sulfanylacetohydrazide
    —— N'-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]-2-(4-methylphenyl)sulfanylacetohydrazide —— C14H17N3O4S2
    N'-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]-2-(4-methylphenyl)sulfanylacetohydrazide
    —— N'-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfonyl)-2-(4-methylphenyl)sulfanylacetohydrazide —— C18H20N2O5S2
    N'-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfonyl)-2-(4-methylphenyl)sulfanylacetohydrazide
    —— 2-(4-methylphenyl)sulfanyl-N'-thiophen-2-ylsulfonylacetohydrazide —— C13H14N2O3S3
    2-(4-methylphenyl)sulfanyl-N'-thiophen-2-ylsulfonylacetohydrazide
    —— N'-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]-2-(2-fluorophenyl)sulfanylacetohydrazide —— C13H14FN3O4S2
    N'-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]-2-(2-fluorophenyl)sulfanylacetohydrazide
    —— 3-chloro-4-[[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pyridine —— C17H19ClN2S
    3-chloro-4-[[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pyridine
    —— 2-[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]acetonitrile —— C13H16N2S
    2-[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]acetonitrile
    —— (2R)-2-[[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pentanedinitrile —— C17H21N3S
    (2R)-2-[[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pentanedinitrile
    —— 3-chloro-4-[[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pyridine —— C17H19ClN2S
    3-chloro-4-[[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pyridine
    —— N-[2-[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]ethyl]methanesulfonamide —— C14H22N2O2S2
    N-[2-[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]ethyl]methanesulfonamide
    —— 3-[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]propanenitrile —— C14H18N2S
    3-[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]propanenitrile
    —— 5-hydroxy-2-[[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pyran-4-one —— C17H19NO3S
    5-hydroxy-2-[[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pyran-4-one
    —— (3R)-1-(2-methylsulfonylethyl)-3-(phenylsulfanylmethyl)pyrrolidine —— C14H21NO2S2
    (3R)-1-(2-methylsulfonylethyl)-3-(phenylsulfanylmethyl)pyrrolidine
    —— 2-[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]acetonitrile —— C13H16N2S
    2-[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]acetonitrile
    —— (3S)-1-(2-methylsulfonylethyl)-3-(phenylsulfanylmethyl)pyrrolidine —— C14H21NO2S2
    (3S)-1-(2-methylsulfonylethyl)-3-(phenylsulfanylmethyl)pyrrolidine
    —— (2R)-2-[[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pentanedinitrile —— C17H21N3S
    (2R)-2-[[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pentanedinitrile
    —— 5-hydroxy-2-[[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pyran-4-one —— C17H19NO3S
    5-hydroxy-2-[[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]methyl]pyran-4-one
    —— N-[2-[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]ethyl]methanesulfonamide —— C14H22N2O2S2
    N-[2-[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]ethyl]methanesulfonamide
    —— 2-(5-cyano-3,4-dimethyl-6-oxopyridazin-1-yl)-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide —— C18H20N4O2S
    2-(5-cyano-3,4-dimethyl-6-oxopyridazin-1-yl)-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide
    —— 2-(5-cyano-3,4-dimethyl-6-oxopyridazin-1-yl)-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C18H20N4O2S
    2-(5-cyano-3,4-dimethyl-6-oxopyridazin-1-yl)-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— N-[2-(4-chlorophenyl)sulfanylethyl]-2-(5-cyano-3,4-dimethyl-6-oxopyridazin-1-yl)acetamide —— C17H17ClN4O2S
    N-[2-(4-chlorophenyl)sulfanylethyl]-2-(5-cyano-3,4-dimethyl-6-oxopyridazin-1-yl)acetamide