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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-(7-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate —— C15H19N4O4S-
    (2R)-2-(7-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate
    —— 7-Cyclohexyl-1,3-dimethyl-5-(3-methylbutylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C19H28N4O2S
    7-Cyclohexyl-1,3-dimethyl-5-(3-methylbutylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 7-cyclohexyl-5-((2-(diethylamino)ethyl)thio)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione —— C20H31N5O2S
    7-cyclohexyl-5-((2-(diethylamino)ethyl)thio)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione
    —— 7-Butyl-5-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C17H24N4O4S
    7-Butyl-5-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— methyl (2R)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate —— C16H22N4O4S
    methyl (2R)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate
    —— 1,3-dimethyl-7-(2-methylpropyl)-5-[(1R)-1-phenylethyl]sulfanylpyrimido[4,5-d]pyrimidine-2,4-dione —— C20H24N4O2S
    1,3-dimethyl-7-(2-methylpropyl)-5-[(1R)-1-phenylethyl]sulfanylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 1,3-Dimethyl-7-(2-methylpropyl)-5-propylsulfanylpyrimido[4,5-d]pyrimidine-2,4-dione —— C15H22N4O2S
    1,3-Dimethyl-7-(2-methylpropyl)-5-propylsulfanylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— N-(furan-2-ylmethyl)-2-[1-(furan-2-ylmethyl)imidazol-2-yl]sulfanylacetamide —— C15H15N3O3S
    N-(furan-2-ylmethyl)-2-[1-(furan-2-ylmethyl)imidazol-2-yl]sulfanylacetamide
    —— 7-(Methoxymethyl)-1,3-dimethyl-5-(3-methylbutylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C15H22N4O3S
    7-(Methoxymethyl)-1,3-dimethyl-5-(3-methylbutylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 2-[[5-(4-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C15H11FN2O2S2
    2-[[5-(4-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— methyl (2S)-2-[7-(methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate —— C14H18N4O5S
    methyl (2S)-2-[7-(methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate
    —— 5-Ethylsulfanyl-7-(methoxymethyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C12H16N4O3S
    5-Ethylsulfanyl-7-(methoxymethyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 1,3-Dimethyl-5-[(2-methylphenyl)methylsulfanyl]-7-(2-methylpropyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C20H24N4O2S
    1,3-Dimethyl-5-[(2-methylphenyl)methylsulfanyl]-7-(2-methylpropyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— Ethyl 2-(7-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylacetate —— C16H22N4O4S
    Ethyl 2-(7-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylacetate
    —— (2S)-2-(7-cyclopentyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate —— C16H19N4O4S-
    (2S)-2-(7-cyclopentyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate
    —— 5-[(2,5-Dimethylphenyl)methylsulfanyl]-7-(methoxymethyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C19H22N4O3S
    5-[(2,5-Dimethylphenyl)methylsulfanyl]-7-(methoxymethyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— ethyl (2R)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate —— C17H24N4O4S
    ethyl (2R)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate
    —— methyl (2S)-2-[7-(methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylbutanoate —— C15H20N4O5S
    methyl (2S)-2-[7-(methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylbutanoate
    —— ethyl (2R)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanyl-3-oxobutanoate —— C18H24N4O5S
    ethyl (2R)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanyl-3-oxobutanoate
    —— 5-(2-Methoxyethylsulfanyl)-7-(methoxymethyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C13H18N4O4S
    5-(2-Methoxyethylsulfanyl)-7-(methoxymethyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 1-(5-Ethylthiophen-2-yl)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C16H13FN2O2S2
    1-(5-Ethylthiophen-2-yl)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— 1,3-Dimethyl-7-(2-methylpropyl)-5-(2-piperidin-1-ylethylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C19H29N5O2S
    1,3-Dimethyl-7-(2-methylpropyl)-5-(2-piperidin-1-ylethylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— methyl (2R)-2-[7-(methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylbutanoate —— C15H20N4O5S
    methyl (2R)-2-[7-(methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylbutanoate
    —— 7-butyl-5-(ethylthio)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione —— C14H20N4O2S
    7-butyl-5-(ethylthio)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione
    —— 1,3-Dimethyl-5-[(3-methylphenyl)methylsulfanyl]-7-(2-methylpropyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C20H24N4O2S
    1,3-Dimethyl-5-[(3-methylphenyl)methylsulfanyl]-7-(2-methylpropyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 7-cyclopentyl-5-((2-fluorobenzyl)thio)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione —— C20H21FN4O2S
    7-cyclopentyl-5-((2-fluorobenzyl)thio)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione
    —— 5-[(2S)-butan-2-yl]sulfanyl-7-(methoxymethyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C14H20N4O3S
    5-[(2S)-butan-2-yl]sulfanyl-7-(methoxymethyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 2-[1-[(4-chlorophenyl)methyl]imidazol-2-yl]sulfanyl-N-[(4-fluorophenyl)methyl]acetamide —— C19H17ClFN3OS
    2-[1-[(4-chlorophenyl)methyl]imidazol-2-yl]sulfanyl-N-[(4-fluorophenyl)methyl]acetamide
    —— (2S)-2-(7-cyclopentyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoic acid —— C17H22N4O4S
    (2S)-2-(7-cyclopentyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoic acid
    —— 7-(Methoxymethyl)-1,3-dimethyl-5-[(3-methylphenyl)methylsulfanyl]pyrimido[4,5-d]pyrimidine-2,4-dione —— C18H20N4O3S
    7-(Methoxymethyl)-1,3-dimethyl-5-[(3-methylphenyl)methylsulfanyl]pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 7-Butyl-5-(2-hydroxyethylsulfanyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C14H20N4O3S
    7-Butyl-5-(2-hydroxyethylsulfanyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— (2R)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylbutanoic acid —— C16H22N4O4S
    (2R)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylbutanoic acid
    —— 2-(7-Butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylethyl-diethylazanium —— C18H30N5O2S+
    2-(7-Butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylethyl-diethylazanium
    —— 5-[(2S)-butan-2-yl]sulfanyl-1,3-dimethyl-7-(2-methylpropyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C16H24N4O2S
    5-[(2S)-butan-2-yl]sulfanyl-1,3-dimethyl-7-(2-methylpropyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— (2R)-2-(7-cyclopentyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoic acid —— C16H20N4O4S
    (2R)-2-(7-cyclopentyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoic acid
    —— 2-[1,3-Dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylacetic acid —— C14H18N4O4S
    2-[1,3-Dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylacetic acid
    —— 2-[1-[(4-Fluorophenyl)methyl]imidazol-2-yl]sulfanylacetamide —— C12H12FN3OS
    2-[1-[(4-Fluorophenyl)methyl]imidazol-2-yl]sulfanylacetamide
    —— N-methyl-2-[1-[(4-methylphenyl)methyl]imidazol-2-yl]sulfanylacetamide —— C14H17N3OS
    N-methyl-2-[1-[(4-methylphenyl)methyl]imidazol-2-yl]sulfanylacetamide
    —— N-[(2-chlorophenyl)methyl]-2-[1-[(4-chlorophenyl)methyl]imidazol-2-yl]sulfanylacetamide —— C19H17Cl2N3OS
    N-[(2-chlorophenyl)methyl]-2-[1-[(4-chlorophenyl)methyl]imidazol-2-yl]sulfanylacetamide
    —— 2-[1-[(4-methylphenyl)methyl]imidazol-2-yl]sulfanyl-N-propan-2-ylacetamide —— C16H21N3OS
    2-[1-[(4-methylphenyl)methyl]imidazol-2-yl]sulfanyl-N-propan-2-ylacetamide
    —— 2-(1-benzylimidazol-2-yl)sulfanyl-N-methylacetamide —— C13H15N3OS
    2-(1-benzylimidazol-2-yl)sulfanyl-N-methylacetamide
    —— N-tert-butyl-2-[1-[(4-fluorophenyl)methyl]imidazol-2-yl]sulfanylacetamide —— C16H20FN3OS
    N-tert-butyl-2-[1-[(4-fluorophenyl)methyl]imidazol-2-yl]sulfanylacetamide
    —— 2-[1-[(4-fluorophenyl)methyl]imidazol-2-yl]sulfanyl-N-methylacetamide —— C13H14FN3OS
    2-[1-[(4-fluorophenyl)methyl]imidazol-2-yl]sulfanyl-N-methylacetamide
    —— 2-[1-[(4-Methylphenyl)methyl]imidazol-2-yl]sulfanylacetamide —— C13H15N3OS
    2-[1-[(4-Methylphenyl)methyl]imidazol-2-yl]sulfanylacetamide
    —— 1-[[(1S)-cyclohex-3-en-1-yl]methyl]-3-(2,2-dimethyl-4-methylsulfonylbutyl)urea —— C15H28N2O3S
    1-[[(1S)-cyclohex-3-en-1-yl]methyl]-3-(2,2-dimethyl-4-methylsulfonylbutyl)urea
    —— 3-nitro-4-[(1R)-1-thiophen-2-ylethyl]sulfanylpyridine —— C11H10N2O2S2
    3-nitro-4-[(1R)-1-thiophen-2-ylethyl]sulfanylpyridine
    —— 2-[1-[(4-fluorophenyl)methyl]imidazol-2-yl]sulfanyl-N-propan-2-ylacetamide —— C15H18FN3OS
    2-[1-[(4-fluorophenyl)methyl]imidazol-2-yl]sulfanyl-N-propan-2-ylacetamide
    —— 3-nitro-4-[(1S)-1-thiophen-2-ylethyl]sulfanylpyridine —— C11H10N2O2S2
    3-nitro-4-[(1S)-1-thiophen-2-ylethyl]sulfanylpyridine
    —— 2-[[5-(Butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C13H17N3OS3
    2-[[5-(Butylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— (1S,2S,3S)-2,3-dimethyl-1-oxo-N-(3-phenylsulfanylpropyl)-1,4-thiazinane-4-carboxamide —— C16H24N2O2S2
    (1S,2S,3S)-2,3-dimethyl-1-oxo-N-(3-phenylsulfanylpropyl)-1,4-thiazinane-4-carboxamide