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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C20H25N3O4S
    [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— (2-Phenyl-1,3-thiazol-4-yl)methyl 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C20H21N3O2S2
    (2-Phenyl-1,3-thiazol-4-yl)methyl 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— (3R)-1-methyl-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]piperazine —— C10H19N5S
    (3R)-1-methyl-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]piperazine
    —— (3S)-1-methyl-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]piperazine —— C10H19N5S
    (3S)-1-methyl-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]piperazine
    —— [2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C18H27N3O4S
    [2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— (3R)-3-[(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]-1-methylpiperazine —— C12H21N5S
    (3R)-3-[(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]-1-methylpiperazine
    —— [2-Oxo-2-(2-phenylethylamino)ethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C20H25N3O3S
    [2-Oxo-2-(2-phenylethylamino)ethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— [2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C17H25N3O4S
    [2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— [2-(Cyclopentylamino)-2-oxoethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C17H25N3O3S
    [2-(Cyclopentylamino)-2-oxoethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— [2-oxo-2-[[(2S)-4-phenylbutan-2-yl]amino]ethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C22H29N3O3S
    [2-oxo-2-[[(2S)-4-phenylbutan-2-yl]amino]ethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— (3S)-3-[(4-methyl-5-phenylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine —— C14H18N4OS
    (3S)-3-[(4-methyl-5-phenylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine
    —— [2-oxo-2-[[(2R)-4-phenylbutan-2-yl]amino]ethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C22H29N3O3S
    [2-oxo-2-[[(2R)-4-phenylbutan-2-yl]amino]ethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— (3S)-3-[(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine —— C11H18N4OS
    (3S)-3-[(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine
    —— (3R)-3-[(4-methyl-5-phenylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine —— C14H18N4OS
    (3R)-3-[(4-methyl-5-phenylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine
    —— [(3S)-2-oxooxolan-3-yl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C14H18N2O4S
    [(3S)-2-oxooxolan-3-yl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— (3R)-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine —— C9H16N4OS
    (3R)-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine
    —— (3S)-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine —— C9H16N4OS
    (3S)-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine
    —— (3R)-3-[(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine —— C11H18N4OS
    (3R)-3-[(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]morpholine
    —— [2-(1-Adamantylamino)-2-oxoethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C22H31N3O3S
    [2-(1-Adamantylamino)-2-oxoethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— [2-(Furan-2-ylmethylamino)-2-oxoethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C17H21N3O4S
    [2-(Furan-2-ylmethylamino)-2-oxoethyl] 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— 3-[2-(2-Chlorophenyl)sulfanylethylsulfonyl]propanamide —— C11H14ClNO3S2
    3-[2-(2-Chlorophenyl)sulfanylethylsulfonyl]propanamide
    —— Carbamoylmethyl 3-[4,6-dimethyl-2-(methylsulfanyl)pyrimidin-5-yl]propanoate —— C12H17N3O3S
    Carbamoylmethyl 3-[4,6-dimethyl-2-(methylsulfanyl)pyrimidin-5-yl]propanoate
    —— Cyanomethyl 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C12H15N3O2S
    Cyanomethyl 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— 3-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]-N-(2-phenylsulfanylethyl)propanamide —— C20H21N3O2S
    3-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]-N-(2-phenylsulfanylethyl)propanamide
    —— N-(2-phenylsulfanylethyl)-3-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)propanamide —— C17H17N3O2S2
    N-(2-phenylsulfanylethyl)-3-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)propanamide
    —— (3S)-1,1-dioxo-N-(2-phenylsulfanylethyl)thiolane-3-carboxamide —— C13H17NO3S2
    (3S)-1,1-dioxo-N-(2-phenylsulfanylethyl)thiolane-3-carboxamide
    —— (E)-3-phenylsulfanyl-N-(2-phenylsulfanylethyl)prop-2-enamide —— C17H17NOS2
    (E)-3-phenylsulfanyl-N-(2-phenylsulfanylethyl)prop-2-enamide
    —— N-methyl-N-(4-methylcyclohexyl)-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C16H21N3O2S2
    N-methyl-N-(4-methylcyclohexyl)-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (E)-3-(1-benzylpyrazol-4-yl)-N-(2-phenylsulfanylethyl)prop-2-enamide —— C21H21N3OS
    (E)-3-(1-benzylpyrazol-4-yl)-N-(2-phenylsulfanylethyl)prop-2-enamide
    —— N-(2-phenylsulfanylethyl)-3-(3-thiophen-3-yl-1,2,4-oxadiazol-5-yl)propanamide —— C17H17N3O2S2
    N-(2-phenylsulfanylethyl)-3-(3-thiophen-3-yl-1,2,4-oxadiazol-5-yl)propanamide
    —— N-[(1S)-3-methyl-1-phenylbutyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C19H21N3O2S2
    N-[(1S)-3-methyl-1-phenylbutyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (1S)-2-amino-1-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethanol —— C6H12N4OS
    (1S)-2-amino-1-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethanol
    —— (1R)-2-amino-1-(4-methyl-5-phenylsulfanyl-1,2,4-triazol-3-yl)ethanol —— C11H14N4OS
    (1R)-2-amino-1-(4-methyl-5-phenylsulfanyl-1,2,4-triazol-3-yl)ethanol
    —— N-(cyclohexen-1-yl)-N-cyclopropyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H23N3O2S
    N-(cyclohexen-1-yl)-N-cyclopropyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (1S)-2-amino-1-(4-benzyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethanol —— C12H16N4OS
    (1S)-2-amino-1-(4-benzyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethanol
    —— (1R)-2-amino-1-(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethanol —— C8H14N4OS
    (1R)-2-amino-1-(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethanol
    —— N-[(1R)-3-methyl-1-phenylbutyl]-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C22H25N3O2S
    N-[(1R)-3-methyl-1-phenylbutyl]-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C20H20FN3O2S
    (2R)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (1S)-2-amino-1-(4-methyl-5-phenylsulfanyl-1,2,4-triazol-3-yl)ethanol —— C11H14N4OS
    (1S)-2-amino-1-(4-methyl-5-phenylsulfanyl-1,2,4-triazol-3-yl)ethanol
    —— (2S)-3-(4-methylphenyl)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C19H17N3OS
    (2S)-3-(4-methylphenyl)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— (1R)-2-amino-1-(4-benzyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethanol —— C12H16N4OS
    (1R)-2-amino-1-(4-benzyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethanol
    —— (1S)-2-amino-1-(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethanol —— C8H14N4OS
    (1S)-2-amino-1-(4-cyclopropyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethanol
    —— Ethyl 2-[2-[2-[5-(acetamidomethyl)thiophen-2-yl]-2-oxoethyl]sulfanyl-1,3-thiazol-4-yl]acetate —— C16H18N2O4S3
    Ethyl 2-[2-[2-[5-(acetamidomethyl)thiophen-2-yl]-2-oxoethyl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— (2R)-2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C17H18FN5O2S
    (2R)-2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— (2S)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile —— C18H14BrN3OS
    (2S)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— 2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-3-methyl-1-phenylbutyl]acetamide —— C19H23N5O2S
    2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-3-methyl-1-phenylbutyl]acetamide
    —— 2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide —— C19H23N5O2S
    2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide
    —— ethyl 2-[2-[(1R)-1-cyano-2-(4-methylphenyl)ethyl]sulfanyl-1,3-thiazol-4-yl]acetate —— C17H18N2O2S2
    ethyl 2-[2-[(1R)-1-cyano-2-(4-methylphenyl)ethyl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— (2S)-1-amino-3-(4-methyl-5-phenylsulfanyl-1,2,4-triazol-3-yl)propan-2-ol —— C12H16N4OS
    (2S)-1-amino-3-(4-methyl-5-phenylsulfanyl-1,2,4-triazol-3-yl)propan-2-ol
    —— (2S)-1-amino-3-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)propan-2-ol —— C7H14N4OS
    (2S)-1-amino-3-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)propan-2-ol