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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3S,4R)-3-methyl-4-morpholin-4-ylpyrrolidin-1-yl]methanone —— C18H24N2O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3S,4R)-3-methyl-4-morpholin-4-ylpyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(3S,4S)-3-(dimethylamino)-4-methylpyrrolidin-1-yl]methanone —— C16H22N2O2S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(3S,4S)-3-(dimethylamino)-4-methylpyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(3S,4R)-3-(dimethylamino)-4-methylpyrrolidin-1-yl]methanone —— C16H22N2O2S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(3S,4R)-3-(dimethylamino)-4-methylpyrrolidin-1-yl]methanone
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(3R,4R)-3-(dimethylamino)-4-methylpyrrolidin-1-yl]methanone —— C16H22N2O2S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(3R,4R)-3-(dimethylamino)-4-methylpyrrolidin-1-yl]methanone
    —— N-benzyl-3-(3,4-dimethylphenyl)sulfanylpropanamide —— C18H21NOS
    N-benzyl-3-(3,4-dimethylphenyl)sulfanylpropanamide
    —— N-[(R)-phenyl(thiophen-2-yl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H18N4OS3
    N-[(R)-phenyl(thiophen-2-yl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[4-(2-methylbutan-2-yl)cyclohexyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H30N4OS2
    N-[4-(2-methylbutan-2-yl)cyclohexyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-(1-adamantyl)-2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(2-cyanoethyl)acetamide —— C21H31N5O2S
    N-(1-adamantyl)-2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(2-cyanoethyl)acetamide
    —— 2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide —— C19H22N4O2S2
    2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide
    —— 3-[2-(azocan-1-yl)-2-oxoethyl]sulfanyl-4-butyl-1H-1,2,4-triazol-5-one —— C15H26N4O2S
    3-[2-(azocan-1-yl)-2-oxoethyl]sulfanyl-4-butyl-1H-1,2,4-triazol-5-one
    —— N-[(2-fluorophenyl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H15FN4OS2
    N-[(2-fluorophenyl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(2-fluorophenyl)ethyl]acetamide —— C16H21FN4O2S
    2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(2-fluorophenyl)ethyl]acetamide
    —— N-[(S)-phenyl(thiophen-2-yl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H18N4OS3
    N-[(S)-phenyl(thiophen-2-yl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-methylphenyl)methyl]acetamide —— C16H22N4O2S
    2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-methylphenyl)methyl]acetamide
    —— 2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide —— C17H24N4O2S2
    2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide
    —— N-[(1R)-1-(furan-2-yl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C13H16N4O2S2
    N-[(1R)-1-(furan-2-yl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]acetamide —— C19H21FN4O2S2
    2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]acetamide
    —— 2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-fluorophenyl)methyl]acetamide —— C15H19FN4O2S
    2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-fluorophenyl)methyl]acetamide
    —— N-[(1R)-1-cyclopropylethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C12H18N4OS2
    N-[(1R)-1-cyclopropylethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H20N4OS3
    N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide —— C19H22N4O2S2
    2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide
    —— N-[(2S)-5-methylhexan-2-yl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H24N4OS2
    N-[(2S)-5-methylhexan-2-yl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2-methylphenyl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H18N4OS2
    N-[(2-methylphenyl)methyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[2-(2-fluorophenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H17FN4OS2
    N-[2-(2-fluorophenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[2-(2-methylphenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H20N4OS2
    N-[2-(2-methylphenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-prop-2-enyl-5-[(1-propyltetrazol-5-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C10H15N7S2
    N-prop-2-enyl-5-[(1-propyltetrazol-5-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-[(2-fluorophenyl)methyl]-N-methyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H17FN4OS2
    N-[(2-fluorophenyl)methyl]-N-methyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 1-(Azocan-1-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C14H22N4OS2
    1-(Azocan-1-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— N-benzyl-N-(furan-2-ylmethyl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H20N4O2S2
    N-benzyl-N-(furan-2-ylmethyl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-(1-adamantyl)-N-(2-cyanoethyl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H27N5OS2
    N-(1-adamantyl)-N-(2-cyanoethyl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone —— C16H18N4O2S
    [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone
    —— [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone —— C16H18N4O2S
    [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone —— C16H18N4O2S
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone —— C16H18N4O2S
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone —— C16H18N4O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone —— C16H18N4O2S
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone —— C16H18N4O2S
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(5-methyl-1H-1,2,4-triazol-3-yl)morpholin-4-yl]methanone
    —— [2-[2-(4-Bromophenyl)sulfanylethylamino]-2-oxoethyl] cyclopropanecarboxylate —— C14H16BrNO3S
    [2-[2-(4-Bromophenyl)sulfanylethylamino]-2-oxoethyl] cyclopropanecarboxylate
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C18H21N3O2S
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C18H21N3O2S
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— N-[2-(2-fluorophenyl)ethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C15H18FN3OS3
    N-[2-(2-fluorophenyl)ethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C18H21N3O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— N-[(2-fluorophenyl)methyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C14H16FN3OS3
    N-[(2-fluorophenyl)methyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C8H13N3OS3
    (2R)-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C18H21N3O2S
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[(2S)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C18H21N3O2S
    [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C18H21N3O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C16H20FN3OS3
    (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C8H13N3OS3
    (2S)-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C17H19N3O3S
    [(2R)-2,3-dihydro-1,4-benzoxathiin-2-yl]-[(2S)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone