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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-ethyl-N-[(3-fluorophenyl)methyl]-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H19FN4O2S2
    N-ethyl-N-[(3-fluorophenyl)methyl]-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-(3,4-difluorophenyl)sulfanyl-N-[(1R)-1-(furan-2-yl)ethyl]acetamide —— C14H13F2NO2S
    2-(3,4-difluorophenyl)sulfanyl-N-[(1R)-1-(furan-2-yl)ethyl]acetamide
    —— N-benzyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetamide —— C19H17F2NO3S2
    N-benzyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetamide
    —— N-benzyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetamide —— C19H17F2NO3S2
    N-benzyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetamide
    —— 2-(3,4-difluorophenyl)sulfanyl-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)ethanone —— C17H14F2O3S
    2-(3,4-difluorophenyl)sulfanyl-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)ethanone
    —— 2-[(3,4-Difluorophenyl)sulfanylmethyl]-5-(3-methylphenyl)-1,3,4-oxadiazole —— C16H12F2N2OS
    2-[(3,4-Difluorophenyl)sulfanylmethyl]-5-(3-methylphenyl)-1,3,4-oxadiazole
    —— (2R)-N-[(4-methylphenyl)methyl]-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C20H21N3OS3
    (2R)-N-[(4-methylphenyl)methyl]-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-(2-cyanoethyl)-N-methyl-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C16H18N4OS3
    (2S)-N-(2-cyanoethyl)-N-methyl-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)propanamide —— C16H21N3OS3
    (2R)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)propanamide
    —— (2S)-N-[(4-methylphenyl)methyl]-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C20H21N3OS3
    (2S)-N-[(4-methylphenyl)methyl]-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-N-(2-cyanoethyl)-N-methyl-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C16H18N4OS3
    (2R)-N-(2-cyanoethyl)-N-methyl-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-N-cycloheptyl-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C19H25N3OS3
    (2R)-N-cycloheptyl-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-cycloheptyl-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C19H25N3OS3
    (2S)-N-cycloheptyl-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylpropanamide —— C15H19N3OS3
    (2S)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylpropanamide
    —— (2R)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)propanamide —— C18H25N3OS3
    (2R)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)propanamide
    —— (2S)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)propanamide —— C16H21N3OS3
    (2S)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)propanamide
    —— (2S)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide —— C15H17N3OS3
    (2S)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide
    —— (2R)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide —— C15H17N3OS3
    (2R)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide
    —— (2R)-N-tert-butyl-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C16H21N3OS3
    (2R)-N-tert-butyl-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— [(2R)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] pyrrolidine-1-carbodithioate —— C20H22N2OS3
    [(2R)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] pyrrolidine-1-carbodithioate
    —— (2R)-N-(2-methoxyethyl)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C15H19N3O2S3
    (2R)-N-(2-methoxyethyl)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— [(2S)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] pyrrolidine-1-carbodithioate —— C20H22N2OS3
    [(2S)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] pyrrolidine-1-carbodithioate
    —— methyl N-[(2R)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]carbamate —— C14H15N3O3S3
    methyl N-[(2R)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]carbamate
    —— methyl N-[(2S)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]carbamate —— C14H15N3O3S3
    methyl N-[(2S)-2-[[4-(2-methylphenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]carbamate
    —— 2-[(5Z)-4-oxo-3-(2-phenylsulfanylethyl)-5-(thiophen-3-ylmethylidene)-1,3-thiazolidin-2-ylidene]propanedinitrile —— C19H13N3OS3
    2-[(5Z)-4-oxo-3-(2-phenylsulfanylethyl)-5-(thiophen-3-ylmethylidene)-1,3-thiazolidin-2-ylidene]propanedinitrile
    —— 2-[(5Z)-5-[(3-methylphenyl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile —— C22H17N3OS2
    2-[(5Z)-5-[(3-methylphenyl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile
    —— 2-[(5Z)-5-[(2,5-dimethylphenyl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile —— C23H19N3OS2
    2-[(5Z)-5-[(2,5-dimethylphenyl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile
    —— 2-[(5Z)-5-[(3-methylthiophen-2-yl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile —— C20H15N3OS3
    2-[(5Z)-5-[(3-methylthiophen-2-yl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile
    —— 2-[(5Z)-5-[(5-methylthiophen-2-yl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile —— C20H15N3OS3
    2-[(5Z)-5-[(5-methylthiophen-2-yl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile
    —— N-[[5-[2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide —— C13H15N3O2S4
    N-[[5-[2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide
    —— 2-[(5Z)-5-[(4-methylphenyl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile —— C22H17N3OS2
    2-[(5Z)-5-[(4-methylphenyl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile
    —— 2-[(5Z)-5-[(4-ethylphenyl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile —— C23H19N3OS2
    2-[(5Z)-5-[(4-ethylphenyl)methylidene]-4-oxo-3-(2-phenylsulfanylethyl)-1,3-thiazolidin-2-ylidene]propanedinitrile
    —— N-[(1R)-3-methyl-1-phenylbutyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C17H22N2OS2
    N-[(1R)-3-methyl-1-phenylbutyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— 2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide —— C17H23N3OS3
    2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide
    —— N-[[5-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide —— C13H14N2O2S3
    N-[[5-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide
    —— 2,2-dimethyl-N-[[5-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]propanamide —— C16H20N2O2S3
    2,2-dimethyl-N-[[5-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]propanamide
    —— N-[(1S)-3-methyl-1-phenylbutyl]-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H21F3N4OS
    N-[(1S)-3-methyl-1-phenylbutyl]-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[[5-[2-(1,3,4-thiadiazol-2-ylsulfanyl)acetyl]thiophen-2-yl]methyl]acetamide —— C11H11N3O2S3
    N-[[5-[2-(1,3,4-thiadiazol-2-ylsulfanyl)acetyl]thiophen-2-yl]methyl]acetamide
    —— N-[(1R)-3-methyl-1-phenylbutyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C15H19N3OS2
    N-[(1R)-3-methyl-1-phenylbutyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— N-[(1S)-3-methyl-1-phenylbutyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C15H19N3OS2
    N-[(1S)-3-methyl-1-phenylbutyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— N-[[5-[2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide —— C12H13N3O2S3
    N-[[5-[2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide
    —— N-[(1S)-3-methyl-1-phenylbutyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C22H25N3O2S
    N-[(1S)-3-methyl-1-phenylbutyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[[5-[2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide —— C18H17N3O3S2
    N-[[5-[2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide
    —— N-methyl-N-(4-methylcyclohexyl)-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H25N3O2S
    N-methyl-N-(4-methylcyclohexyl)-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enyl-N-(thiophen-2-ylmethyl)acetamide —— C17H18N4O2S2
    2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enyl-N-(thiophen-2-ylmethyl)acetamide
    —— N-[[5-[2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide —— C16H16N4O3S2
    N-[[5-[2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide
    —— N-[[5-[2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide —— C18H17N3O3S2
    N-[[5-[2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide
    —— N-(cyclohexen-1-yl)-N-cyclopropyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H23N3O2S
    N-(cyclohexen-1-yl)-N-cyclopropyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-(cyclohexen-1-yl)-N-ethyl-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H22N4O2S
    N-(cyclohexen-1-yl)-N-ethyl-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— ethyl (2Z)-2-[4-oxo-3-[2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]ethyl]-1,3-thiazolidin-2-ylidene]acetate —— C18H18N2O3S3
    ethyl (2Z)-2-[4-oxo-3-[2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]ethyl]-1,3-thiazolidin-2-ylidene]acetate