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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-[(1-cyanocyclohexyl)amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C18H20N2O3S
    [2-[(1-cyanocyclohexyl)amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] (E)-3-phenylsulfanylprop-2-enoate —— C15H17NO3S
    [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-oxo-2-(1,2,5-trimethylpyrrol-3-yl)ethyl] (E)-3-phenylsulfanylprop-2-enoate —— C18H19NO3S
    [2-oxo-2-(1,2,5-trimethylpyrrol-3-yl)ethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-[[(1R,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C18H23NO3S
    [2-[[(1R,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-oxo-2-(propylamino)ethyl] (E)-3-phenylsulfanylprop-2-enoate —— C14H17NO3S
    [2-oxo-2-(propylamino)ethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C15H17NO5S2
    [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C17H20N2O3S
    [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-(2-acetylhydrazinyl)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C13H14N2O4S
    [2-(2-acetylhydrazinyl)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-(2-cyanoethylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C14H14N2O3S
    [2-(2-cyanoethylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-oxo-2-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethylamino]ethyl] (E)-3-phenylsulfanylprop-2-enoate —— C16H16N2O4S3
    [2-oxo-2-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethylamino]ethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C20H23NO4S
    [2-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-(ethoxycarbonylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C14H15NO5S
    [2-(ethoxycarbonylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C15H17NO5S2
    [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-oxo-2-(2,2,2-trifluoroethylamino)ethyl] (E)-3-phenylsulfanylprop-2-enoate —— C13H12F3NO3S
    [2-oxo-2-(2,2,2-trifluoroethylamino)ethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C18H23NO3S
    [2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-oxo-2-(propan-2-ylamino)ethyl] (E)-3-phenylsulfanylprop-2-enoate —— C14H17NO3S
    [2-oxo-2-(propan-2-ylamino)ethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-(2-methylpropylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C15H19NO3S
    [2-(2-methylpropylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-(tert-butylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C15H19NO3S
    [2-(tert-butylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— (1R)-1-(4-cyclopentylsulfanylphenyl)-2-pyrrolidin-1-ylethanamine —— C17H26N2S
    (1R)-1-(4-cyclopentylsulfanylphenyl)-2-pyrrolidin-1-ylethanamine
    —— [2-(cyclohexylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C17H21NO3S
    [2-(cyclohexylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-(2-methoxyethylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C14H17NO4S
    [2-(2-methoxyethylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— 3-[2-oxo-2-(2-oxopyrrolidin-1-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C11H16N4O3S
    3-[2-oxo-2-(2-oxopyrrolidin-1-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— (2R)-2-(4-cyclopentylsulfanylphenyl)-2-pyrrolidin-1-ylethanamine —— C17H26N2S
    (2R)-2-(4-cyclopentylsulfanylphenyl)-2-pyrrolidin-1-ylethanamine
    —— ethyl 2,5-dimethyl-4-[2-[(E)-3-phenylsulfanylprop-2-enoyl]oxyacetyl]-1H-pyrrole-3-carboxylate —— C20H21NO5S
    ethyl 2,5-dimethyl-4-[2-[(E)-3-phenylsulfanylprop-2-enoyl]oxyacetyl]-1H-pyrrole-3-carboxylate
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 4-oxopentanoate —— C19H19NO4S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 4-oxopentanoate
    —— [2-(cyclopropylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C14H15NO3S
    [2-(cyclopropylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-(cyclopentylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C16H19NO3S
    [2-(cyclopentylamino)-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [2-[(2-chlorophenyl)methylamino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate —— C18H16ClNO3S
    [2-[(2-chlorophenyl)methylamino]-2-oxoethyl] (E)-3-phenylsulfanylprop-2-enoate
    —— (2S)-2-(4-cyclopentylsulfanylphenyl)-2-pyrrolidin-1-ylethanamine —— C17H26N2S
    (2S)-2-(4-cyclopentylsulfanylphenyl)-2-pyrrolidin-1-ylethanamine
    —— [(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl] (E)-3-phenylsulfanylprop-2-enoate —— C17H14N2O3S2
    [(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl] (E)-3-phenylsulfanylprop-2-enoate
    —— [(3R)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl] (E)-3-phenylsulfanylprop-2-enoate —— C17H14N2O3S2
    [(3R)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl] (E)-3-phenylsulfanylprop-2-enoate
    —— (1S)-1-(4-cyclopentylsulfanylphenyl)-2-pyrrolidin-1-ylethanamine —— C17H26N2S
    (1S)-1-(4-cyclopentylsulfanylphenyl)-2-pyrrolidin-1-ylethanamine
    —— N-(cyclopropylmethyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-propylacetamide —— C14H24N4O2S
    N-(cyclopropylmethyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-propylacetamide
    —— N-ethyl-N-(2-methylprop-2-enyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H22N4O2S
    N-ethyl-N-(2-methylprop-2-enyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile —— C9H14N4OS
    4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile
    —— N,N-diethyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H20N4O2S
    N,N-diethyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— [2-[4-(3,4-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 4-oxopentanoate —— C21H23NO4S
    [2-[4-(3,4-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 4-oxopentanoate
    —— N-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C8H14N4O2S
    N-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-(3-methylbutyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H22N4O2S
    N-(3-methylbutyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-(3-methoxypropyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H20N4O3S
    N-(3-methoxypropyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-[2-[2,5-dimethyl-1-(thiophen-2-ylmethyl)pyrrol-3-yl]-2-oxoethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C18H22N4O2S2
    3-[2-[2,5-dimethyl-1-(thiophen-2-ylmethyl)pyrrol-3-yl]-2-oxoethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— N-butyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H20N4O2S
    N-butyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 4-oxopentanoate —— C21H23NO4S
    [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 4-oxopentanoate
    —— N-(2-methoxyethyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C10H18N4O3S
    N-(2-methoxyethyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(2-methylphenyl)methyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H24N4OS
    N-[(2-methylphenyl)methyl]-2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-[(3-fluorophenyl)methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one —— C12H14FN3OS
    3-[(3-fluorophenyl)methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one
    —— N-(2-cyanoethyl)-N-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H17N5O2S
    N-(2-cyanoethyl)-N-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(2S)-butan-2-yl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H20N4O2S
    N-[(2S)-butan-2-yl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[5-(4-cyclopentylsulfanylphenyl)-1,3,4-oxadiazol-2-yl]ethanol —— C15H18N2O2S
    2-[5-(4-cyclopentylsulfanylphenyl)-1,3,4-oxadiazol-2-yl]ethanol
    —— 2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide —— C20H24N4OS2
    2-[(4-pentyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide