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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[2-(4-Chlorophenyl)sulfanylphenyl]carbamothioylamino]ethyl-dimethylazanium —— C17H21ClN3S2+
    2-[[2-(4-Chlorophenyl)sulfanylphenyl]carbamothioylamino]ethyl-dimethylazanium
    —— N-methyl-N-[(1S,2R)-2-methylsulfonylcyclohexyl]acetamide —— C10H19NO3S
    N-methyl-N-[(1S,2R)-2-methylsulfonylcyclohexyl]acetamide
    —— N-methyl-N-[(1R,2S)-2-methylsulfonylcyclohexyl]acetamide —— C10H19NO3S
    N-methyl-N-[(1R,2S)-2-methylsulfonylcyclohexyl]acetamide
    —— N-methyl-N-[(1S,2S)-2-methylsulfonylcyclohexyl]acetamide —— C10H19NO3S
    N-methyl-N-[(1S,2S)-2-methylsulfonylcyclohexyl]acetamide
    —— N-methyl-N-[(1R,2R)-2-methylsulfonylcyclohexyl]acetamide —— C10H19NO3S
    N-methyl-N-[(1R,2R)-2-methylsulfonylcyclohexyl]acetamide
    —— ethyl (4S)-2-amino-4-(4-methylsulfanylphenyl)-5-oxo-4,6,7,8-tetrahydrochromene-3-carboxylate —— C19H21NO4S
    ethyl (4S)-2-amino-4-(4-methylsulfanylphenyl)-5-oxo-4,6,7,8-tetrahydrochromene-3-carboxylate
    —— ethyl (4R)-5-acetyl-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-4H-pyran-3-carboxylate —— C18H21NO4S
    ethyl (4R)-5-acetyl-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-4H-pyran-3-carboxylate
    —— diethyl (4R)-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-4H-pyran-3,5-dicarboxylate —— C19H23NO5S
    diethyl (4R)-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-4H-pyran-3,5-dicarboxylate
    —— ethyl (4S)-5-acetyl-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-4H-pyran-3-carboxylate —— C18H21NO4S
    ethyl (4S)-5-acetyl-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-4H-pyran-3-carboxylate
    —— [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] 4-oxopentanoate —— C19H18ClNO4S
    [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] 4-oxopentanoate
    —— N-[(3-chlorophenyl)methyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H17ClN4O2S
    N-[(3-chlorophenyl)methyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-(4-oxo-4-thiophen-2-ylbutyl)sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C13H17N3O2S2
    3-(4-oxo-4-thiophen-2-ylbutyl)sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H24N4O2S
    N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— ethyl 2,5-dimethyl-4-[2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1H-pyrrole-3-carboxylate —— C16H22N4O4S
    ethyl 2,5-dimethyl-4-[2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1H-pyrrole-3-carboxylate
    —— N-[(1S)-1-(4-bromophenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H19BrN4O2S
    N-[(1S)-1-(4-bromophenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(2-bromophenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H19BrN4O2S
    N-[(1S)-1-(2-bromophenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-[2-[2,5-dimethyl-1-[(1S)-1-phenylethyl]pyrrol-3-yl]-2-oxoethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C21H26N4O2S
    3-[2-[2,5-dimethyl-1-[(1S)-1-phenylethyl]pyrrol-3-yl]-2-oxoethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— 3-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one —— C12H13N5O3S
    3-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one
    —— N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H20N4O4S2
    N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H24N4O2S
    N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-(4-cyclopentylsulfanylphenyl)pyrazine-2-carbonitrile —— C16H15N3S
    3-(4-cyclopentylsulfanylphenyl)pyrazine-2-carbonitrile
    —— N'-acetyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetohydrazide —— C9H15N5O3S
    N'-acetyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetohydrazide
    —— N-[(1R)-1-(4-bromophenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H19BrN4O2S
    N-[(1R)-1-(4-bromophenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (1S)-2-morpholin-4-yl-1-(4-propan-2-ylsulfanylphenyl)ethanamine —— C15H24N2OS
    (1S)-2-morpholin-4-yl-1-(4-propan-2-ylsulfanylphenyl)ethanamine
    —— (2R)-1-amino-3-[4-(4-methylsulfanylphenyl)-1,3-thiazol-2-yl]propan-2-ol —— C13H16N2OS2
    (2R)-1-amino-3-[4-(4-methylsulfanylphenyl)-1,3-thiazol-2-yl]propan-2-ol
    —— (2S)-2-morpholin-4-yl-2-(4-propan-2-ylsulfanylphenyl)ethanamine —— C15H24N2OS
    (2S)-2-morpholin-4-yl-2-(4-propan-2-ylsulfanylphenyl)ethanamine
    —— (2R)-2-morpholin-4-yl-2-(4-propan-2-ylsulfanylphenyl)ethanamine —— C15H24N2OS
    (2R)-2-morpholin-4-yl-2-(4-propan-2-ylsulfanylphenyl)ethanamine
    —— (2S)-1-amino-3-[4-(4-methylsulfanylphenyl)-1,3-thiazol-2-yl]propan-2-ol —— C13H16N2OS2
    (2S)-1-amino-3-[4-(4-methylsulfanylphenyl)-1,3-thiazol-2-yl]propan-2-ol
    —— (1R)-2-morpholin-4-yl-1-(4-propan-2-ylsulfanylphenyl)ethanamine —— C15H24N2OS
    (1R)-2-morpholin-4-yl-1-(4-propan-2-ylsulfanylphenyl)ethanamine
    —— (2S)-1-(5-bromothiophen-2-yl)sulfanyl-3-methylbutan-2-amine —— C9H14BrNS2
    (2S)-1-(5-bromothiophen-2-yl)sulfanyl-3-methylbutan-2-amine
    —— (2R)-1-(5-bromothiophen-2-yl)sulfanyl-3-methylbutan-2-amine —— C9H14BrNS2
    (2R)-1-(5-bromothiophen-2-yl)sulfanyl-3-methylbutan-2-amine
    —— 2-[(3R)-3-[(3-methylsulfanylanilino)methyl]pyrrolidin-1-yl]ethanol —— C14H22N2OS
    2-[(3R)-3-[(3-methylsulfanylanilino)methyl]pyrrolidin-1-yl]ethanol
    —— 2-[(3S)-3-[(3-methylsulfanylanilino)methyl]pyrrolidin-1-yl]ethanol —— C14H22N2OS
    2-[(3S)-3-[(3-methylsulfanylanilino)methyl]pyrrolidin-1-yl]ethanol
    —— 2-(2-fluorophenyl)sulfanylethyl (3R)-3-(carbamoylamino)-3-(4-chlorophenyl)propanoate —— C18H18ClFN2O3S
    2-(2-fluorophenyl)sulfanylethyl (3R)-3-(carbamoylamino)-3-(4-chlorophenyl)propanoate
    —— (2R)-3-(4-methylphenyl)-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C21H21N3OS2
    (2R)-3-(4-methylphenyl)-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— (2S)-3-(4-methylphenyl)-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C21H21N3OS2
    (2S)-3-(4-methylphenyl)-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— (2S)-3-(4-methylphenyl)-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C21H21N3OS2
    (2S)-3-(4-methylphenyl)-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— 2-(2-fluorophenyl)sulfanylethyl (3S)-3-(carbamoylamino)-3-(4-chlorophenyl)propanoate —— C18H18ClFN2O3S
    2-(2-fluorophenyl)sulfanylethyl (3S)-3-(carbamoylamino)-3-(4-chlorophenyl)propanoate
    —— N-methyl-N-(4-methylcyclohexyl)-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H29N3O2S2
    N-methyl-N-(4-methylcyclohexyl)-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 5-[(3S)-3-[(3-methylsulfanylanilino)methyl]pyrrolidin-1-yl]pentan-1-ol —— C17H28N2OS
    5-[(3S)-3-[(3-methylsulfanylanilino)methyl]pyrrolidin-1-yl]pentan-1-ol
    —— 5-[(3R)-3-[(3-methylsulfanylanilino)methyl]pyrrolidin-1-yl]pentan-1-ol —— C17H28N2OS
    5-[(3R)-3-[(3-methylsulfanylanilino)methyl]pyrrolidin-1-yl]pentan-1-ol
    —— 2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide —— C15H21N5OS
    2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide
    —— 3-methylsulfanyl-N-[[(3S)-1-(3-propan-2-yloxypropyl)pyrrolidin-3-yl]methyl]aniline —— C18H30N2OS
    3-methylsulfanyl-N-[[(3S)-1-(3-propan-2-yloxypropyl)pyrrolidin-3-yl]methyl]aniline
    —— 3-methylsulfanyl-N-[[(3R)-1-(3-propan-2-yloxypropyl)pyrrolidin-3-yl]methyl]aniline —— C18H30N2OS
    3-methylsulfanyl-N-[[(3R)-1-(3-propan-2-yloxypropyl)pyrrolidin-3-yl]methyl]aniline
    —— N-[[(3R)-1-(3-ethoxypropyl)pyrrolidin-3-yl]methyl]-3-methylsulfanylaniline —— C17H28N2OS
    N-[[(3R)-1-(3-ethoxypropyl)pyrrolidin-3-yl]methyl]-3-methylsulfanylaniline
    —— 2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-3-methyl-1-phenylbutyl]acetamide —— C15H21N5OS
    2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-3-methyl-1-phenylbutyl]acetamide
    —— N-[[(3S)-1-(3-methoxypropyl)pyrrolidin-3-yl]methyl]-3-methylsulfanylaniline —— C16H26N2OS
    N-[[(3S)-1-(3-methoxypropyl)pyrrolidin-3-yl]methyl]-3-methylsulfanylaniline
    —— N-[[(3S)-1-[3-(dimethylamino)propyl]pyrrolidin-3-yl]methyl]-3-methylsulfanylaniline —— C17H29N3S
    N-[[(3S)-1-[3-(dimethylamino)propyl]pyrrolidin-3-yl]methyl]-3-methylsulfanylaniline
    —— (1'S,2R,5'R,6'R)-2'-amino-6'-(4-methylsulfanylphenyl)spiro[1,3-oxathiolane-2,4'-3-azoniabicyclo[3.1.0]hex-2-ene]-1',5'-dicarbonitrile —— C16H15N4OS2+
    (1'S,2R,5'R,6'R)-2'-amino-6'-(4-methylsulfanylphenyl)spiro[1,3-oxathiolane-2,4'-3-azoniabicyclo[3.1.0]hex-2-ene]-1',5'-dicarbonitrile
    —— (1'S,2R,5'R,6'R)-2'-amino-6'-(4-methylsulfanylphenyl)spiro[1,3-oxathiolane-2,4'-3-azabicyclo[3.1.0]hex-2-ene]-1',5'-dicarbonitrile —— C16H14N4OS2
    (1'S,2R,5'R,6'R)-2'-amino-6'-(4-methylsulfanylphenyl)spiro[1,3-oxathiolane-2,4'-3-azabicyclo[3.1.0]hex-2-ene]-1',5'-dicarbonitrile