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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-[[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine —— C15H15ClN4S3
    5-[[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine
    —— methyl 2,4-dimethyl-5-[(2R)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C16H22N4O3S2
    methyl 2,4-dimethyl-5-[(2R)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— N-(1-cyanocyclohexyl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H21N5OS2
    N-(1-cyanocyclohexyl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 1-(1-Ethyl-2,5-dimethylpyrrol-3-yl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C15H22N4OS2
    1-(1-Ethyl-2,5-dimethylpyrrol-3-yl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C16H21FN4OS2
    (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— N-[(1S,2S)-2-methylcyclohexyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H24N4OS2
    N-[(1S,2S)-2-methylcyclohexyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-N-(1-adamantyl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C18H28N4OS2
    (2R)-N-(1-adamantyl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— ethyl 2,4-dimethyl-5-[(2S)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C17H24N4O3S2
    ethyl 2,4-dimethyl-5-[(2S)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— (2S)-N-(1-adamantyl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C18H28N4OS2
    (2S)-N-(1-adamantyl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine —— C14H15N5OS2
    5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine
    —— 5-[[2-(4-methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine —— C16H18N4S3
    5-[[2-(4-methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine
    —— 5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine —— C12H13N5O2S2
    5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H30N4OS2
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1R,2R)-2-methylcyclohexyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H24N4OS2
    N-[(1R,2R)-2-methylcyclohexyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1R,2S)-2-methylcyclohexyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H24N4OS2
    N-[(1R,2S)-2-methylcyclohexyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 1-(5-Chlorothiophen-2-yl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C11H12ClN3OS3
    1-(5-Chlorothiophen-2-yl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— N-[2-(4-fluorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H19FN4OS2
    N-[2-(4-fluorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— ethyl 2,5-dimethyl-4-[2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-1H-pyrrole-3-carboxylate —— C16H22N4O3S2
    ethyl 2,5-dimethyl-4-[2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-1H-pyrrole-3-carboxylate
    —— 1-(5-Bromothiophen-2-yl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C11H12BrN3OS3
    1-(5-Bromothiophen-2-yl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 5-[(4-chlorophenyl)methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine —— C12H14ClN3S2
    5-[(4-chlorophenyl)methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine
    —— (2R)-1-(4-chloro-3-methylphenyl)sulfanyl-3-methylbutan-2-amine —— C12H18ClNS
    (2R)-1-(4-chloro-3-methylphenyl)sulfanyl-3-methylbutan-2-amine
    —— (2S)-1-(4-chloro-3-methylphenyl)sulfanyl-3-methylbutan-2-amine —— C12H18ClNS
    (2S)-1-(4-chloro-3-methylphenyl)sulfanyl-3-methylbutan-2-amine
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C18H25N5O2S2
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— (2R)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile —— C18H23N5OS
    (2R)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C20H29N5O2S
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C20H29N5O2S
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— N-(1-adamantylmethyl)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C21H33N5O2S
    N-(1-adamantylmethyl)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2S)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C19H26FN5O2S
    (2S)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-1-[1-[(2S)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone —— C20H31N5O3S
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-1-[1-[(2S)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— N-[3-(3,5-dimethylpyrazol-1-yl)propyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H29N7O2S
    N-[3-(3,5-dimethylpyrazol-1-yl)propyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[2-(4-chlorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H24ClN5O2S
    N-[2-(4-chlorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C19H26FN5O2S
    (2R)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— N-[(3-chlorophenyl)methyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H22ClN5O2S
    N-[(3-chlorophenyl)methyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone —— C20H31N5O3S
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— (3S)-3-[(2,3-dihydroimidazo[2,1-b][1,3]thiazol-6-ylmethylamino)methyl]pyrrolidin-3-ol —— C11H18N4OS
    (3S)-3-[(2,3-dihydroimidazo[2,1-b][1,3]thiazol-6-ylmethylamino)methyl]pyrrolidin-3-ol
    —— (3R)-3-[(2,3-dihydroimidazo[2,1-b][1,3]thiazol-6-ylmethylamino)methyl]pyrrolidin-3-ol —— C11H18N4OS
    (3R)-3-[(2,3-dihydroimidazo[2,1-b][1,3]thiazol-6-ylmethylamino)methyl]pyrrolidin-3-ol
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C16H23N5O2S2
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— 4-[4-ethyl-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]morpholine —— C18H22N6O2S
    4-[4-ethyl-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]morpholine
    —— N-(cyclohexen-1-yl)-N-cyclopropyl-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C19H29N5O2S
    N-(cyclohexen-1-yl)-N-cyclopropyl-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1R)-1-(2,4-difluorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H23F2N5O2S
    N-[(1R)-1-(2,4-difluorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H24ClN5O2S
    N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[2-(cyclohexen-1-yl)ethylcarbamoyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C19H30N6O3S
    N-[2-(cyclohexen-1-yl)ethylcarbamoyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H23F2N5O2S
    N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H24ClN5O2S
    N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 4-[4-Ethyl-5-[(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,2,4-triazol-3-yl]morpholine —— C15H18N6O2S2
    4-[4-Ethyl-5-[(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,2,4-triazol-3-yl]morpholine
    —— (2R)-N-(1-cyanocyclohexyl)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C18H28N6O2S
    (2R)-N-(1-cyanocyclohexyl)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H24ClN5O2S
    N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 4-[(3R)-3-(1H-imidazol-2-yl)piperidin-1-yl]-6-thiophen-2-ylsulfanylpyrimidin-2-amine —— C16H18N6S2
    4-[(3R)-3-(1H-imidazol-2-yl)piperidin-1-yl]-6-thiophen-2-ylsulfanylpyrimidin-2-amine
    —— 1-Methylsulfanyl-4-(2,2,2-trimethoxyethyl)benzene —— C12H18O3S
    1-Methylsulfanyl-4-(2,2,2-trimethoxyethyl)benzene
    —— 4-[(3S)-3-(1H-imidazol-2-yl)piperidin-1-yl]-6-thiophen-2-ylsulfanylpyrimidin-2-amine —— C16H18N6S2
    4-[(3S)-3-(1H-imidazol-2-yl)piperidin-1-yl]-6-thiophen-2-ylsulfanylpyrimidin-2-amine