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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-N-[(4-methylphenyl)methyl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C18H23N3OS
    (2R)-N-[(4-methylphenyl)methyl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide
    —— (2R)-2-(2,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide —— C17H25NO3S2
    (2R)-2-(2,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide
    —— (2S)-N-cycloheptyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C17H27N3OS
    (2S)-N-cycloheptyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide
    —— (3R)-3-(4-propan-2-ylsulfanylphenyl)-3-pyridin-4-ylpropan-1-amine —— C17H22N2S
    (3R)-3-(4-propan-2-ylsulfanylphenyl)-3-pyridin-4-ylpropan-1-amine
    —— (3R)-3-(4-propan-2-ylsulfanylphenyl)-3-pyridin-3-ylpropan-1-amine —— C17H22N2S
    (3R)-3-(4-propan-2-ylsulfanylphenyl)-3-pyridin-3-ylpropan-1-amine
    —— (2R)-N-[(2-chlorophenyl)methyl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C17H20ClN3OS
    (2R)-N-[(2-chlorophenyl)methyl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide
    —— (2S)-N-(2-methoxyethyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C13H21N3O2S
    (2S)-N-(2-methoxyethyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide
    —— (2S)-N-tert-butyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C14H23N3OS
    (2S)-N-tert-butyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide
    —— (2R)-N-cycloheptyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C17H27N3OS
    (2R)-N-cycloheptyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide
    —— N-(butylcarbamoyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide —— C14H22N4O2S
    N-(butylcarbamoyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetamide
    —— (2R)-N-(1-cyanocyclohexyl)-2-(2,4-dimethylphenyl)sulfanyl-N-methylpropanamide —— C19H26N2OS
    (2R)-N-(1-cyanocyclohexyl)-2-(2,4-dimethylphenyl)sulfanyl-N-methylpropanamide
    —— (2R)-2-(2,4-dimethylphenyl)sulfanyl-N-[(4-fluorophenyl)methyl]propanamide —— C18H20FNOS
    (2R)-2-(2,4-dimethylphenyl)sulfanyl-N-[(4-fluorophenyl)methyl]propanamide
    —— (2S)-2-(2,5-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide —— C17H25NO3S2
    (2S)-2-(2,5-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide
    —— 2-(4-Chlorophenyl)sulfanylethyl 3-[(2-methylpropan-2-yl)oxycarbonylamino]propanoate —— C16H22ClNO4S
    2-(4-Chlorophenyl)sulfanylethyl 3-[(2-methylpropan-2-yl)oxycarbonylamino]propanoate
    —— (2R)-2-(2,4-dimethylphenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide —— C17H25NO3S2
    (2R)-2-(2,4-dimethylphenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide
    —— (2R)-2-(2,4-dimethylphenyl)sulfanyl-N-(thiophen-2-ylmethyl)propanamide —— C16H19NOS2
    (2R)-2-(2,4-dimethylphenyl)sulfanyl-N-(thiophen-2-ylmethyl)propanamide
    —— (2S)-2-(2,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide —— C17H25NO3S2
    (2S)-2-(2,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide
    —— (2S)-N-(1-cyanocyclohexyl)-2-(2,4-dimethylphenyl)sulfanyl-N-methylpropanamide —— C19H26N2OS
    (2S)-N-(1-cyanocyclohexyl)-2-(2,4-dimethylphenyl)sulfanyl-N-methylpropanamide
    —— methyl N-[(2R)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate —— C13H12BrN3O4S
    methyl N-[(2R)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate
    —— (2R)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide —— C14H14BrN3O2S
    (2R)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide
    —— methyl N-[(2S)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate —— C13H12BrN3O4S
    methyl N-[(2S)-2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate
    —— 1-[[2-(4-chlorophenyl)sulfanylacetyl]amino]-3-[(1S,2S)-2-methylcyclohexyl]thiourea —— C16H22ClN3OS2
    1-[[2-(4-chlorophenyl)sulfanylacetyl]amino]-3-[(1S,2S)-2-methylcyclohexyl]thiourea
    —— 1-[[2-(4-Chlorophenyl)sulfanylacetyl]amino]-3-(2-methylprop-2-enyl)thiourea —— C13H16ClN3OS2
    1-[[2-(4-Chlorophenyl)sulfanylacetyl]amino]-3-(2-methylprop-2-enyl)thiourea
    —— N-[6-amino-1-(2-methylpropyl)-2,4-dioxopyrimidin-5-yl]-N-butyl-2-(4-fluorophenyl)sulfanylacetamide —— C20H27FN4O3S
    N-[6-amino-1-(2-methylpropyl)-2,4-dioxopyrimidin-5-yl]-N-butyl-2-(4-fluorophenyl)sulfanylacetamide
    —— 4-[(1S)-1-aminoethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine —— C12H15N3S2
    4-[(1S)-1-aminoethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine
    —— 4-[(1R)-1-aminoethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine —— C12H15N3S2
    4-[(1R)-1-aminoethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine
    —— 3-[2-(4-Fluorophenyl)sulfanylethylsulfonyl]propanamide —— C11H14FNO3S2
    3-[2-(4-Fluorophenyl)sulfanylethylsulfonyl]propanamide
    —— 4-[(2S)-2-(methylamino)propyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine —— C14H19N3S2
    4-[(2S)-2-(methylamino)propyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine
    —— [(2S)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] (2R)-oxolane-2-carboxylate —— C20H21NO4S
    [(2S)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] (2R)-oxolane-2-carboxylate
    —— 4-[(2R)-2-(methylamino)propyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine —— C14H19N3S2
    4-[(2R)-2-(methylamino)propyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine
    —— [(2R)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] (2R)-oxolane-2-carboxylate —— C20H21NO4S
    [(2R)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] (2R)-oxolane-2-carboxylate
    —— (5Z)-3-[4-(dimethylamino)phenyl]-5-[(4-methylsulfanylphenyl)methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C19H18N2OS3
    (5Z)-3-[4-(dimethylamino)phenyl]-5-[(4-methylsulfanylphenyl)methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— 7-Methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C15H14N6O2S2
    7-Methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— 5-[[4-Methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-3-thiophen-3-yl-1,2,4-oxadiazole —— C15H13N5O2S2
    5-[[4-Methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-3-thiophen-3-yl-1,2,4-oxadiazole
    —— (2S)-N-(2-cyanoethyl)-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C15H19N5O2S
    (2S)-N-(2-cyanoethyl)-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H24N4O4S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R)-N-benzyl-N-tert-butyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C22H28N4O2S
    (2R)-N-benzyl-N-tert-butyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 2-[[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C15H11ClN2O2S2
    2-[[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C19H22N4O2S
    (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H24N4O4S2
    (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— [2-[methyl-[(4-methylsulfanylphenyl)methyl]amino]-2-oxoethyl] 2-[(3R)-1,1-dioxothiolan-3-yl]sulfanylacetate —— C17H23NO5S3
    [2-[methyl-[(4-methylsulfanylphenyl)methyl]amino]-2-oxoethyl] 2-[(3R)-1,1-dioxothiolan-3-yl]sulfanylacetate
    —— [2-[methyl-[(4-methylsulfanylphenyl)methyl]amino]-2-oxoethyl] 2-[(3S)-1,1-dioxothiolan-3-yl]sulfanylacetate —— C17H23NO5S3
    [2-[methyl-[(4-methylsulfanylphenyl)methyl]amino]-2-oxoethyl] 2-[(3S)-1,1-dioxothiolan-3-yl]sulfanylacetate
    —— (2R)-1-(azepan-1-yl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one —— C17H24N4O2S
    (2R)-1-(azepan-1-yl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one
    —— (2S)-N-[(4-fluorophenyl)methyl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C18H19FN4O2S
    (2S)-N-[(4-fluorophenyl)methyl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H24N4O4S2
    (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R)-N-[(4-fluorophenyl)methyl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C18H19FN4O2S
    (2R)-N-[(4-fluorophenyl)methyl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide —— C16H18N4O2S2
    (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide
    —— 2-[(5-cyclopropyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-ethylphenyl)ethyl]acetamide —— C19H26N4OS
    2-[(5-cyclopropyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-ethylphenyl)ethyl]acetamide
    —— N-cyclopentyl-2-[(5-cyclopropyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C18H28N4O3S2
    N-cyclopentyl-2-[(5-cyclopropyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— 4-[(5-Cyclopropyl-4-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-2-thiophen-2-yl-1,3-oxazole —— C15H16N4OS2
    4-[(5-Cyclopropyl-4-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-2-thiophen-2-yl-1,3-oxazole