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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 3-(4-methylphenyl)sulfanylpropanoate —— C16H21NO3S
    [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 3-(4-methylphenyl)sulfanylpropanoate
    —— [2-[(4-Chlorophenyl)methylamino]-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate —— C19H20ClNO3S
    [2-[(4-Chlorophenyl)methylamino]-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate
    —— [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate —— C18H24N2O3S
    [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate
    —— [(2S)-1-amino-1-oxopropan-2-yl] 3-(4-methylphenyl)sulfanylpropanoate —— C13H17NO3S
    [(2S)-1-amino-1-oxopropan-2-yl] 3-(4-methylphenyl)sulfanylpropanoate
    —— [2-(Ethoxycarbonylamino)-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate —— C15H19NO5S
    [2-(Ethoxycarbonylamino)-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate
    —— [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate —— C16H21NO5S2
    [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate
    —— [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate —— C20H23NO4S
    [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate
    —— [2-[[(3R)-3-methyl-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate —— C17H23NO5S2
    [2-[[(3R)-3-methyl-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-(4-methylphenyl)sulfanylpropanoate
    —— N'-amino-4-ethylsulfanylbenzenecarboximidamide —— C9H13N3S
    N'-amino-4-ethylsulfanylbenzenecarboximidamide
    —— methyl 2,4-dimethyl-5-[(2R)-2-(3-phenylsulfanylpropanoyloxy)propanoyl]-1H-pyrrole-3-carboxylate —— C20H23NO5S
    methyl 2,4-dimethyl-5-[(2R)-2-(3-phenylsulfanylpropanoyloxy)propanoyl]-1H-pyrrole-3-carboxylate
    —— 2-(2-oxoquinoxalin-1-yl)-N-(2-phenylsulfanylphenyl)acetamide —— C22H17N3O2S
    2-(2-oxoquinoxalin-1-yl)-N-(2-phenylsulfanylphenyl)acetamide
    —— [2-(4-Methylphenyl)-1,3-thiazol-4-yl]methyl 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C19H19N3O2S2
    [2-(4-Methylphenyl)-1,3-thiazol-4-yl]methyl 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— (5-Oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C15H14N4O3S2
    (5-Oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— 5-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-2-methylpyrazolo[1,5-a]quinazoline —— C19H15N3O2S
    5-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-2-methylpyrazolo[1,5-a]quinazoline
    —— 2-Methyl-5-(2-methylpyrazolo[1,5-a]quinazolin-5-yl)sulfanyl-1,3,4-thiadiazole —— C14H11N5S2
    2-Methyl-5-(2-methylpyrazolo[1,5-a]quinazolin-5-yl)sulfanyl-1,3,4-thiadiazole
    —— 6-Amino-5-[[5-(4-fluorophenyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-1-methylpyrimidine-2,4-dione —— C14H13FN6O2S
    6-Amino-5-[[5-(4-fluorophenyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-1-methylpyrimidine-2,4-dione
    —— N-(cyclopenten-1-yl)-N-ethyl-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C13H17F3N4OS
    N-(cyclopenten-1-yl)-N-ethyl-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide —— C14H24N4O2S2
    2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide
    —— N-(4-methoxyphenyl)-5-(4-methylquinolin-2-yl)sulfanyl-1,3,4-thiadiazol-2-amine —— C19H16N4OS2
    N-(4-methoxyphenyl)-5-(4-methylquinolin-2-yl)sulfanyl-1,3,4-thiadiazol-2-amine
    —— 2-(2-cyanophenyl)sulfanyl-N-[[(2R)-1-ethylpyrrolidin-2-yl]methyl]benzamide —— C21H23N3OS
    2-(2-cyanophenyl)sulfanyl-N-[[(2R)-1-ethylpyrrolidin-2-yl]methyl]benzamide
    —— N-[(2R)-2-(dimethylamino)-2-thiophen-2-ylethyl]-2-phenylsulfanylpyridine-3-carboxamide —— C20H21N3OS2
    N-[(2R)-2-(dimethylamino)-2-thiophen-2-ylethyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— 4-benzothiazol-2-ylmercapto-3-nitro-benzenesulfonic acid methylamide —— C14H11N3O4S3
    4-benzothiazol-2-ylmercapto-3-nitro-benzenesulfonic acid methylamide
    —— N-[(2S)-2-(dimethylamino)-2-thiophen-2-ylethyl]-2-phenylsulfanylpyridine-3-carboxamide —— C20H21N3OS2
    N-[(2S)-2-(dimethylamino)-2-thiophen-2-ylethyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— dimethyl-[(1S)-2-[(2-phenylsulfanylpyridine-3-carbonyl)amino]-1-thiophen-2-ylethyl]azanium —— C20H22N3OS2+
    dimethyl-[(1S)-2-[(2-phenylsulfanylpyridine-3-carbonyl)amino]-1-thiophen-2-ylethyl]azanium
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[3-(2-oxopyrrolidin-1-yl)propyl]acetamide —— C17H19ClN4O3S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[3-(2-oxopyrrolidin-1-yl)propyl]acetamide
    —— ethyl 2-[2-[(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl]sulfanyl-1,3-thiazol-4-yl]acetate —— C15H15N3O3S3
    ethyl 2-[2-[(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— 2-(2-Pyrimidinylmercapto)-benzthiazol 37525-42-1 C11H7N3S2
    2-(2-Pyrimidinylmercapto)-benzthiazol
    —— ethyl 2-[2-[(3R)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl]sulfanyl-1,3-thiazol-4-yl]acetate —— C15H15N3O3S3
    ethyl 2-[2-[(3R)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— dimethyl-[(1R)-2-[(2-phenylsulfanylpyridine-3-carbonyl)amino]-1-thiophen-2-ylethyl]azanium —— C20H22N3OS2+
    dimethyl-[(1R)-2-[(2-phenylsulfanylpyridine-3-carbonyl)amino]-1-thiophen-2-ylethyl]azanium
    —— [2-[benzyl(methyl)amino]-2-oxoethyl] (1'R,5'S)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate —— C22H29NO3S2
    [2-[benzyl(methyl)amino]-2-oxoethyl] (1'R,5'S)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)propanamide —— C19H27N3O2S
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)propanamide
    —— (2S)-1-(azepan-1-yl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one —— C19H25N3O2S
    (2S)-1-(azepan-1-yl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide —— C19H25N3O4S2
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide
    —— (2R)-N-tert-butyl-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C17H23N3O2S
    (2R)-N-tert-butyl-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylpropanamide —— C18H23N3O4S2
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylpropanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide —— C18H19N3O2S2
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide
    —— (2S)-N-(cyclopentylcarbamoyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C19H24N4O3S
    (2S)-N-(cyclopentylcarbamoyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide —— C19H25N3O4S2
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide —— C17H21N3O4S2
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide
    —— (2S)-N-(2-cyanoethyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide —— C17H20N4O2S
    (2S)-N-(2-cyanoethyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide
    —— (2S)-N-[(2-chlorophenyl)methyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C20H20ClN3O2S
    (2S)-N-[(2-chlorophenyl)methyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide —— C18H19N3O2S2
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylpropanamide —— C18H23N3O4S2
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylpropanamide
    —— 2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-1-methoxypropan-2-yl]acetamide —— C12H15N3O4S
    2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-1-methoxypropan-2-yl]acetamide
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)propanamide —— C17H23N3O2S
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)propanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide —— C19H25N3O4S2
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylpropanamide —— C18H23N3O4S2
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylpropanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C17H21N3O4S2
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide —— C17H21N3O4S2
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide
    —— (2R)-N-[(1S,2R)-2-methylcyclohexyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanamide —— C12H19N3OS2
    (2R)-N-[(1S,2R)-2-methylcyclohexyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanamide