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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-Ethyl-3-[(4-fluorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazole —— C14H18FN3S
    4-Ethyl-3-[(4-fluorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazole
    —— 3-Benzylsulfanyl-4-ethyl-5-propyl-1,2,4-triazole —— C14H19N3S
    3-Benzylsulfanyl-4-ethyl-5-propyl-1,2,4-triazole
    —— 2-Benzylsulfanyl-5-ethyl-1,3,4-oxadiazole —— C11H12N2OS
    2-Benzylsulfanyl-5-ethyl-1,3,4-oxadiazole
    —— 2-[(4-Ethyl-5-propyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-1,3,4-oxadiazole —— C11H17N5OS
    2-[(4-Ethyl-5-propyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-1,3,4-oxadiazole
    —— 2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-5-propyl-1,3,4-oxadiazole —— C9H13N5OS
    2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-5-propyl-1,3,4-oxadiazole
    —— 2-[(5-Benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-propyl-1,3,4-oxadiazole —— C17H21N5OS
    2-[(5-Benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-propyl-1,3,4-oxadiazole
    —— 2-Ethyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole —— C10H14N4O2S
    2-Ethyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 2-Methyl-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole —— C7H8N4O2S
    2-Methyl-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 2-Propyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole —— C11H16N4O2S
    2-Propyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 2-{[(5-ethyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-5-phenyl-1,3,4-oxadiazole —— C13H13N5OS
    2-{[(5-ethyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-5-phenyl-1,3,4-oxadiazole
    —— 2-[(5-benzyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-5-phenyl-1,3,4-oxadiazole —— C18H15N5OS
    2-[(5-benzyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-5-phenyl-1,3,4-oxadiazole
    —— 2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-1,3,4-oxadiazole —— C8H11N5OS
    2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-1,3,4-oxadiazole
    —— 2-Methyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C9H12N4O2S
    2-Methyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— (2R)-2-(4-bromophenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide —— C17H17BrFNOS
    (2R)-2-(4-bromophenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide
    —— N'-acetyl-2-(4-bromophenyl)sulfanylacetohydrazide —— C10H11BrN2O2S
    N'-acetyl-2-(4-bromophenyl)sulfanylacetohydrazide
    —— N-[3-[(2-chlorophenyl)methyl]-1,3-thiazol-2-ylidene]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H12ClN5OS2
    N-[3-[(2-chlorophenyl)methyl]-1,3-thiazol-2-ylidene]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 1-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C13H13N5OS2
    1-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— 1-(5-chlorothiophen-2-yl)-2-(4H-1,2,4-triazol-3-ylsulfanyl)ethanone —— C8H6ClN3OS2
    1-(5-chlorothiophen-2-yl)-2-(4H-1,2,4-triazol-3-ylsulfanyl)ethanone
    —— (2S)-2-(4-bromophenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide —— C17H17BrFNOS
    (2S)-2-(4-bromophenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide
    —— methyl 2,4-dimethyl-5-[(2R)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanoyl]-1H-pyrrole-3-carboxylate —— C13H16N4O3S
    methyl 2,4-dimethyl-5-[(2R)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanoyl]-1H-pyrrole-3-carboxylate
    —— 1-(5-bromothiophen-2-yl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C8H6BrN3OS2
    1-(5-bromothiophen-2-yl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— 2-(4-bromophenyl)sulfanyl-N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]acetamide —— C13H16BrNO3S2
    2-(4-bromophenyl)sulfanyl-N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]acetamide
    —— (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoate —— C16H13N4O4S-
    (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoate
    —— 2-(4-bromophenyl)sulfanyl-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide —— C13H16BrNO3S2
    2-(4-bromophenyl)sulfanyl-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide
    —— 1-(5-phenyl-3,4-dihydropyrazol-2-yl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C13H13N5OS
    1-(5-phenyl-3,4-dihydropyrazol-2-yl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C18H18N4OS2
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C16H18N3O4S-
    (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— 2-[(4-Bromophenyl)sulfanylmethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C13H9BrN2OS2
    2-[(4-Bromophenyl)sulfanylmethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoic acid —— C16H14N4O4S
    (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoic acid
    —— (E)-3-[5-(3-bromophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C16H10BrN2O4S-
    (E)-3-[5-(3-bromophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoate —— C16H11N2O4S2-
    (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoate
    —— N-[(4-chlorophenyl)methyl]-N-methyl-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H13ClN4OS
    N-[(4-chlorophenyl)methyl]-N-methyl-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (E)-3-[5-(diethylamino)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C14H17N3O4S
    (E)-3-[5-(diethylamino)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— (E)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-morpholin-4-ylfuran-2-yl)prop-2-enoic acid —— C14H15N3O5S
    (E)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-morpholin-4-ylfuran-2-yl)prop-2-enoic acid
    —— 1-[(3R)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C18H17N5O2S
    1-[(3R)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— (Z)-3-[4-bromo-5-(dimethylamino)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C12H11BrN3O4S-
    (Z)-3-[4-bromo-5-(dimethylamino)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— (Z)-3-(4-bromo-5-piperidin-1-ylfuran-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C15H15BrN3O4S-
    (Z)-3-(4-bromo-5-piperidin-1-ylfuran-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— 1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C14H20N4O2S
    1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— (Z)-3-[4-bromo-5-(dimethylamino)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C12H12BrN3O4S
    (Z)-3-[4-bromo-5-(dimethylamino)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-[5-(diethylamino)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C14H16N3O4S-
    (E)-3-[5-(diethylamino)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— (E)-3-(5-methylfuran-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C11H10N2O4S
    (E)-3-(5-methylfuran-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— (2S)-N-(1-cyanocyclohexyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide —— C12H17N5OS
    (2S)-N-(1-cyanocyclohexyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide
    —— (Z)-3-(5-bromothiophen-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C10H6BrN2O3S2-
    (Z)-3-(5-bromothiophen-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enoic acid —— C17H14N2O4S2
    (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enoic acid
    —— N-[(2R)-4-phenylbutan-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H18N4OS
    N-[(2R)-4-phenylbutan-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (Z)-3-(4-bromo-5-piperidin-1-ylfuran-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C15H16BrN3O4S
    (Z)-3-(4-bromo-5-piperidin-1-ylfuran-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-(furan-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C10H7N2O4S-
    (E)-3-(furan-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C10H15N5OS
    N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (E)-3-[5-(3-bromophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C16H11BrN2O4S
    (E)-3-[5-(3-bromophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— (2S)-N-cyclopentyl-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide —— C10H16N4OS
    (2S)-N-cyclopentyl-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide