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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-cyclobutyl-2-(4-ethylsulfanylphenyl)ethanamine —— C14H21NS
    (2S)-2-cyclobutyl-2-(4-ethylsulfanylphenyl)ethanamine
    —— (2S)-2-(furan-2-yl)-2-(4-methylsulfanylphenyl)ethanamine —— C13H15NOS
    (2S)-2-(furan-2-yl)-2-(4-methylsulfanylphenyl)ethanamine
    —— (2R)-2-(furan-2-yl)-2-(4-methylsulfanylphenyl)ethanamine —— C13H15NOS
    (2R)-2-(furan-2-yl)-2-(4-methylsulfanylphenyl)ethanamine
    —— (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enylpropanamide —— C14H18N4O2S
    (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enylpropanamide
    —— (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylpropyl)propanamide —— C15H22N4O2S
    (2R)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylpropyl)propanamide
    —— 2-[(5Z)-3-(3,4-dimethylphenyl)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]propanedinitrile —— C22H17N3OS2
    2-[(5Z)-3-(3,4-dimethylphenyl)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]propanedinitrile
    —— (2S)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enylpropanamide —— C14H18N4O2S
    (2S)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-prop-2-enylpropanamide
    —— 2-[(5E)-3-(4-ethylphenyl)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]propanedinitrile —— C22H17N3OS2
    2-[(5E)-3-(4-ethylphenyl)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]propanedinitrile
    —— (2S)-N-tert-butyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C15H22N4O2S
    (2S)-N-tert-butyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C15H20N4O4S2
    (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R)-N-(1-cyanocyclohexyl)-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C19H25N5O2S
    (2R)-N-(1-cyanocyclohexyl)-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-N-(1-cyanocyclohexyl)-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C19H25N5O2S
    (2S)-N-(1-cyanocyclohexyl)-N-methyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— methyl N-[(2S)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanoyl]carbamate —— C13H16N4O4S
    methyl N-[(2S)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanoyl]carbamate
    —— [(3S)-1,1-dioxothiolan-3-yl] 2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C14H17N3O5S2
    [(3S)-1,1-dioxothiolan-3-yl] 2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (2R)-N-(2-methoxyethyl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C14H20N4O3S
    (2R)-N-(2-methoxyethyl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 2-[(5Z)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-3-phenyl-1,3-thiazolidin-2-ylidene]propanedinitrile —— C20H13N3OS2
    2-[(5Z)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-3-phenyl-1,3-thiazolidin-2-ylidene]propanedinitrile
    —— (2S)-4-methyl-2-(4-methylsulfanylphenyl)pentan-1-amine —— C13H21NS
    (2S)-4-methyl-2-(4-methylsulfanylphenyl)pentan-1-amine
    —— (2S)-2-cyclobutyl-2-(4-methylsulfanylphenyl)ethanamine —— C13H19NS
    (2S)-2-cyclobutyl-2-(4-methylsulfanylphenyl)ethanamine
    —— 4-[(1-Oxidopyridin-1-ium-2-yl)sulfanylmethyl]-2-thiophen-3-yl-1,3-thiazole —— C13H10N2OS3
    4-[(1-Oxidopyridin-1-ium-2-yl)sulfanylmethyl]-2-thiophen-3-yl-1,3-thiazole
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propan-1-one —— C13H16N4O2S
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propan-1-one
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropan-1-one —— C16H18N2O3S
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropan-1-one
    —— 5-(4-Fluorophenyl)-4-methyl-3-[(1-oxidopyridin-1-ium-2-yl)sulfanylmethyl]-1,2-oxazole —— C16H13FN2O2S
    5-(4-Fluorophenyl)-4-methyl-3-[(1-oxidopyridin-1-ium-2-yl)sulfanylmethyl]-1,2-oxazole
    —— 3-[(1-Methyltetrazol-5-yl)sulfanylmethyl]-5-thiophen-2-yl-1,2-oxazole —— C10H9N5OS2
    3-[(1-Methyltetrazol-5-yl)sulfanylmethyl]-5-thiophen-2-yl-1,2-oxazole
    —— (3R)-3-amino-6-methyl-2,3-dihydrothiopyrano[2,3-c]pyrrol-4-one —— C8H10N2OS
    (3R)-3-amino-6-methyl-2,3-dihydrothiopyrano[2,3-c]pyrrol-4-one
    —— (3S)-3-amino-6-methyl-2,3-dihydrothiopyrano[2,3-c]pyrrol-4-one —— C8H10N2OS
    (3S)-3-amino-6-methyl-2,3-dihydrothiopyrano[2,3-c]pyrrol-4-one
    —— 2,3,4,5-tetrahydropyrrolo[2,1-b][1,3]thiazepine-8-carbaldehyde —— C9H11NOS
    2,3,4,5-tetrahydropyrrolo[2,1-b][1,3]thiazepine-8-carbaldehyde
    —— N-[2-(4-bromophenyl)sulfanylethyl]-2-(2-nitropyridin-3-yl)oxyacetamide —— C15H14BrN3O4S
    N-[2-(4-bromophenyl)sulfanylethyl]-2-(2-nitropyridin-3-yl)oxyacetamide
    —— 5-[[5-(4-Fluorophenyl)-4-methyl-1,2-oxazol-3-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C13H11FN4OS2
    5-[[5-(4-Fluorophenyl)-4-methyl-1,2-oxazol-3-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-(2-nitropyridin-3-yl)oxyacetamide —— C16H17N3O4S
    N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-(2-nitropyridin-3-yl)oxyacetamide
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one —— C13H16N4O2S2
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one
    —— 3-[(5-thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C10H9N5OS2
    3-[(5-thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C13H17N5O2S
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C13H17N5O2S
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— 3-[[5-(4-fluorophenyl)-4-methyl-1,2-oxazol-3-yl]methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C13H12FN5OS
    3-[[5-(4-fluorophenyl)-4-methyl-1,2-oxazol-3-yl]methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— 3-[2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1,3-oxazolidin-2-one —— C7H9N5O3S
    3-[2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1,3-oxazolidin-2-one
    —— [(2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C21H25NO4S
    [(2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [(2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C21H25NO4S
    [(2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— 3-[4-Ethyl-5-[2-[(2-fluorophenyl)methylamino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide —— C16H20FN5O2S
    3-[4-Ethyl-5-[2-[(2-fluorophenyl)methylamino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[4-Ethyl-5-[2-[(2-methylphenyl)methylamino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide —— C17H23N5O2S
    3-[4-Ethyl-5-[2-[(2-methylphenyl)methylamino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[4-Ethyl-5-[2-[2-(2-fluorophenyl)ethylamino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide —— C17H22FN5O2S
    3-[4-Ethyl-5-[2-[2-(2-fluorophenyl)ethylamino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[4-ethyl-5-[2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide —— C20H25N5O2S
    3-[4-ethyl-5-[2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-[2-[2-(3-Chlorophenyl)ethylamino]-2-oxoethyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide —— C17H22ClN5O2S
    3-[5-[2-[2-(3-Chlorophenyl)ethylamino]-2-oxoethyl]sulfanyl-4-ethyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[4-Ethyl-5-[2-[methyl-[(4-methylsulfanylphenyl)methyl]amino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide —— C18H25N5O2S2
    3-[4-Ethyl-5-[2-[methyl-[(4-methylsulfanylphenyl)methyl]amino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[4-Ethyl-5-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]-1,2,4-triazol-3-yl]propanamide —— C15H17N5O3S
    3-[4-Ethyl-5-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]-1,2,4-triazol-3-yl]propanamide
    —— 3,4-dihydro-2H-pyrrolo[2,1-b][1,3]thiazine-7-carbaldehyde —— C8H9NOS
    3,4-dihydro-2H-pyrrolo[2,1-b][1,3]thiazine-7-carbaldehyde
    —— N-[(1R)-1-cyclopropylethyl]-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H22N4OS2
    N-[(1R)-1-cyclopropylethyl]-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-6-methylheptan-2-yl]acetamide —— C20H30N4OS2
    2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-6-methylheptan-2-yl]acetamide
    —— N-[(1R)-1-cyclopropylethyl]-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H20N4OS2
    N-[(1R)-1-cyclopropylethyl]-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2-methylphenyl)methyl]acetamide —— C20H22N4OS2
    2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2-methylphenyl)methyl]acetamide
    —— 2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylbutan-2-yl)acetamide —— C17H24N4OS2
    2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylbutan-2-yl)acetamide