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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(2-bromophenyl)-5-(1H-1,2,4-triazol-5-ylsulfanylmethyl)-1,3,4-oxadiazole —— C11H8BrN5OS
    2-(2-bromophenyl)-5-(1H-1,2,4-triazol-5-ylsulfanylmethyl)-1,3,4-oxadiazole
    —— (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C16H11ClN2O4S
    (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— N-[(1R)-1-thiophen-2-ylethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C10H12N4OS2
    N-[(1R)-1-thiophen-2-ylethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (E)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoic acid —— C12H12N2O4S
    (E)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoic acid
    —— (E)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-thiophen-2-ylprop-2-enoic acid —— C10H8N2O3S2
    (E)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-thiophen-2-ylprop-2-enoic acid
    —— 1-[(3S)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C15H13N5OS3
    1-[(3S)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C16H11ClN2O4S
    (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-[5-(dimethylamino)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C12H13N3O4S
    (E)-3-[5-(dimethylamino)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-[5-(5-chloro-2-methylphenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C17H12ClN2O4S-
    (E)-3-[5-(5-chloro-2-methylphenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— N-(4-fluorobenzyl)-2-(1H-1,2,4-triazol-3-ylsulfanyl)acetamide —— C11H11FN4OS
    N-(4-fluorobenzyl)-2-(1H-1,2,4-triazol-3-ylsulfanyl)acetamide
    —— (E)-3-[5-(4-bromophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C16H10BrN2O4S-
    (E)-3-[5-(4-bromophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— (Z)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoic acid —— C17H16N4O4S
    (Z)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoic acid
    —— N-[(2R)-2-phenylpropyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C13H16N4OS
    N-[(2R)-2-phenylpropyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C15H13N5OS3
    1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— (E)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-piperidin-1-ylfuran-2-yl)prop-2-enoate —— C15H16N3O4S-
    (E)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-piperidin-1-ylfuran-2-yl)prop-2-enoate
    —— (E)-3-[5-(4-bromophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C16H11BrN2O4S
    (E)-3-[5-(4-bromophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C16H10ClN2O4S-
    (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate —— C16H10ClN2O4S-
    (E)-3-[5-(4-chlorophenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoate
    —— N-(1-adamantyl)-N-[(4-fluorophenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C21H25FN4OS
    N-(1-adamantyl)-N-[(4-fluorophenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[2-(cyclohexen-1-yl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H18N4OS
    N-[2-(cyclohexen-1-yl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (E)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoate —— C12H11N2O4S-
    (E)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoate
    —— (Z)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoate —— C12H11N2O3S2-
    (Z)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoate
    —— (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C17H21N3O4S
    (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— 1-(1-ethyl-2,5-dimethyl-1H-pyrrol-3-yl)-2-(4H-1,2,4-triazol-3-ylsulfanyl)ethanone —— C12H16N4OS
    1-(1-ethyl-2,5-dimethyl-1H-pyrrol-3-yl)-2-(4H-1,2,4-triazol-3-ylsulfanyl)ethanone
    —— (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoate —— C16H10ClN2O3S2-
    (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoate
    —— 2-(4-chlorophenyl)-5-[(4H-1,2,4-triazol-3-ylsulfanyl)methyl]-1,3,4-oxadiazole —— C11H8ClN5OS
    2-(4-chlorophenyl)-5-[(4H-1,2,4-triazol-3-ylsulfanyl)methyl]-1,3,4-oxadiazole
    —— N-(1-adamantylmethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C15H22N4OS
    N-(1-adamantylmethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(1S)-1-(2-bromophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H13BrN4OS
    N-[(1S)-1-(2-bromophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(1R)-1-(4-bromophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H13BrN4OS
    N-[(1R)-1-(4-bromophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(1S)-1-(4-bromophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H13BrN4OS
    N-[(1S)-1-(4-bromophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(1S)-1-(4-ethylphenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H18N4OS
    N-[(1S)-1-(4-ethylphenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(1R)-1-(2-bromophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H13BrN4OS
    N-[(1R)-1-(2-bromophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(1R)-1-(4-ethylphenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H18N4OS
    N-[(1R)-1-(4-ethylphenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-[5-(dimethylamino)furan-2-yl]prop-2-enoic acid —— C17H14ClN3O4S
    (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-[5-(dimethylamino)furan-2-yl]prop-2-enoic acid
    —— (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(furan-2-yl)prop-2-enoate —— C15H8ClN2O4S-
    (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(furan-2-yl)prop-2-enoate
    —— (E)-2-(1,3-benzoxazol-2-ylsulfanyl)-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enoate —— C21H14NO4S2-
    (E)-2-(1,3-benzoxazol-2-ylsulfanyl)-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enoate
    —— (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoate —— C16H10ClN2O4S-
    (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoate
    —— (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoic acid —— C16H11ClN2O3S2
    (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoic acid
    —— (E)-2-(1,3-benzoxazol-2-ylsulfanyl)-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enoic acid —— C21H15NO4S2
    (E)-2-(1,3-benzoxazol-2-ylsulfanyl)-3-[5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enoic acid
    —— (E)-2-(1,3-benzoxazol-2-ylsulfanyl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoic acid —— C20H13NO4S2
    (E)-2-(1,3-benzoxazol-2-ylsulfanyl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoic acid
    —— [(2S)-1-amino-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C12H14BrNO3S
    [(2S)-1-amino-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— [(2R)-1-amino-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C12H14BrNO3S
    [(2R)-1-amino-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— [2-(Ethoxycarbonylamino)-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C14H16BrNO5S
    [2-(Ethoxycarbonylamino)-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— 4-[(1R)-1-(methylamino)ethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine —— C13H17N3S2
    4-[(1R)-1-(methylamino)ethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine
    —— 4-[(1S)-1-(methylamino)ethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine —— C13H17N3S2
    4-[(1S)-1-(methylamino)ethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine
    —— 4-[(1S)-1-(ethylamino)ethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine —— C14H19N3S2
    4-[(1S)-1-(ethylamino)ethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine
    —— 4-[(1R)-1-(ethylamino)ethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine —— C14H19N3S2
    4-[(1R)-1-(ethylamino)ethyl]-N-(3-methylsulfanylphenyl)-1,3-thiazol-2-amine
    —— 2-(2-chlorophenyl)sulfanyl-N-(2,3-dihydro-1,4-benzodioxin-6-yl)pyridine-3-carboxamide —— C20H15ClN2O3S
    2-(2-chlorophenyl)sulfanyl-N-(2,3-dihydro-1,4-benzodioxin-6-yl)pyridine-3-carboxamide
    —— N-cyclopentyl-2-[2-[(4-fluorophenyl)sulfanylmethyl]-5-methoxy-4-oxopyridin-1-yl]acetamide —— C20H23FN2O3S
    N-cyclopentyl-2-[2-[(4-fluorophenyl)sulfanylmethyl]-5-methoxy-4-oxopyridin-1-yl]acetamide
    —— N-(1,3-benzodioxol-5-yl)-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide —— C20H16N2O3S
    N-(1,3-benzodioxol-5-yl)-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide