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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one —— C19H19N3O3S
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one
    —— 3-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-(4-fluorophenyl)-4-methyl-1,2-oxazole —— C15H15FN4OS
    3-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-(4-fluorophenyl)-4-methyl-1,2-oxazole
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C17H22N4O2S
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— 4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-2-thiophen-3-yl-1,3-thiazole —— C12H12N4S3
    4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-2-thiophen-3-yl-1,3-thiazole
    —— 2-(3-hydroxypyridin-1-ium-1-yl)-N-(2-phenylsulfanylphenyl)acetamide —— C19H17N2O2S+
    2-(3-hydroxypyridin-1-ium-1-yl)-N-(2-phenylsulfanylphenyl)acetamide
    —— 3-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-thiophen-2-yl-1,2-oxazole —— C12H12N4OS2
    3-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-thiophen-2-yl-1,2-oxazole
    —— 4-[(5-Cyclopropyl-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-2-thiophen-3-yl-1,3-thiazole —— C14H14N4S3
    4-[(5-Cyclopropyl-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-2-thiophen-3-yl-1,3-thiazole
    —— 3-[(5-Cyclopropyl-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-(4-fluorophenyl)-4-methyl-1,2-oxazole —— C17H17FN4OS
    3-[(5-Cyclopropyl-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-(4-fluorophenyl)-4-methyl-1,2-oxazole
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propan-1-one —— C21H24N4O3S
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propan-1-one
    —— 2-(2-Methylfuran-3-yl)-5-[(5-thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole —— C15H11N3O3S2
    2-(2-Methylfuran-3-yl)-5-[(5-thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 2-[[5-(4-Fluorophenyl)-4-methyl-1,2-oxazol-3-yl]methylsulfanyl]-5-(2-methylfuran-3-yl)-1,3,4-oxadiazole —— C18H14FN3O3S
    2-[[5-(4-Fluorophenyl)-4-methyl-1,2-oxazol-3-yl]methylsulfanyl]-5-(2-methylfuran-3-yl)-1,3,4-oxadiazole
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one —— C18H19N3O4S
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one
    —— (3R)-3-(oxan-4-yl)-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine —— C17H27NOS
    (3R)-3-(oxan-4-yl)-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine
    —— 3-[2-[[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-1,3-oxazolidin-2-one —— C12H11N3O5S
    3-[2-[[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-1,3-oxazolidin-2-one
    —— (3S)-3-(oxan-4-yl)-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine —— C17H27NOS
    (3S)-3-(oxan-4-yl)-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine
    —— [(2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C20H22ClNO4S
    [(2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— (3S)-4-(4-methylpiperazin-1-yl)-3-(4-methylsulfanylphenyl)butan-1-amine —— C16H27N3S
    (3S)-4-(4-methylpiperazin-1-yl)-3-(4-methylsulfanylphenyl)butan-1-amine
    —— 3-[(4-Ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-(4-fluorophenyl)-4-methyl-1,2-oxazole —— C19H17FN4OS2
    3-[(4-Ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-(4-fluorophenyl)-4-methyl-1,2-oxazole
    —— 3-[2-[[4-Benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]-1,3-oxazolidin-2-one —— C18H16N4O4S
    3-[2-[[4-Benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]-1,3-oxazolidin-2-one
    —— 4-[(4-Ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-2-thiophen-3-yl-1,3-thiazole —— C16H14N4S4
    4-[(4-Ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-2-thiophen-3-yl-1,3-thiazole
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C19H22N4O2S2
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— 3-[2-[(4-Ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1,3-oxazolidin-2-one —— C13H14N4O3S2
    3-[2-[(4-Ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1,3-oxazolidin-2-one
    —— 1-(5-Chloro-2-phenylsulfanylphenyl)-3-(3-morpholin-4-ylpropyl)thiourea —— C20H24ClN3OS2
    1-(5-Chloro-2-phenylsulfanylphenyl)-3-(3-morpholin-4-ylpropyl)thiourea
    —— 1-(5-Chloro-2-phenylsulfanylphenyl)-3-methylthiourea —— C14H13ClN2S2
    1-(5-Chloro-2-phenylsulfanylphenyl)-3-methylthiourea
    —— 1-(5-Chloro-2-phenylsulfanylphenyl)-3-(2-morpholin-4-ylethyl)thiourea —— C19H22ClN3OS2
    1-(5-Chloro-2-phenylsulfanylphenyl)-3-(2-morpholin-4-ylethyl)thiourea
    —— 1-(5-chloro-2-phenylsulfanylphenyl)-3-[[(2S)-oxolan-2-yl]methyl]thiourea —— C18H19ClN2OS2
    1-(5-chloro-2-phenylsulfanylphenyl)-3-[[(2S)-oxolan-2-yl]methyl]thiourea
    —— 2-[(5-Chloro-2-phenylsulfanylphenyl)carbamothioylamino]ethyl-dimethylazanium —— C17H21ClN3S2+
    2-[(5-Chloro-2-phenylsulfanylphenyl)carbamothioylamino]ethyl-dimethylazanium
    —— 1-(5-Chloro-2-phenylsulfanylphenyl)-3-[2-(dimethylamino)ethyl]thiourea —— C17H20ClN3S2
    1-(5-Chloro-2-phenylsulfanylphenyl)-3-[2-(dimethylamino)ethyl]thiourea
    —— 1-(5-Chloro-2-phenylsulfanylphenyl)-3-(2-methoxyethyl)thiourea —— C16H17ClN2OS2
    1-(5-Chloro-2-phenylsulfanylphenyl)-3-(2-methoxyethyl)thiourea
    —— 3-Methyl-5-[(5-thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-4-amine —— C11H11N5OS2
    3-Methyl-5-[(5-thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— 3-[(5-Thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazol-4-amine —— C11H8F3N5OS2
    3-[(5-Thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazol-4-amine
    —— (3S)-4-(4-methylpiperidin-1-yl)-3-(4-methylsulfanylphenyl)butan-1-amine —— C17H28N2S
    (3S)-4-(4-methylpiperidin-1-yl)-3-(4-methylsulfanylphenyl)butan-1-amine
    —— 1-[(1R)-1-(4-ethylsulfanylphenyl)-3-methylbutyl]piperazine —— C17H28N2S
    1-[(1R)-1-(4-ethylsulfanylphenyl)-3-methylbutyl]piperazine
    —— (3R)-4-(4-methylpiperidin-1-yl)-3-(4-methylsulfanylphenyl)butan-1-amine —— C17H28N2S
    (3R)-4-(4-methylpiperidin-1-yl)-3-(4-methylsulfanylphenyl)butan-1-amine
    —— (3S)-4-(azepan-1-yl)-3-(4-methylsulfanylphenyl)butan-1-amine —— C17H28N2S
    (3S)-4-(azepan-1-yl)-3-(4-methylsulfanylphenyl)butan-1-amine
    —— 1-[(1S)-3-methyl-1-(4-methylsulfanylphenyl)butyl]-1,4-diazepane —— C17H28N2S
    1-[(1S)-3-methyl-1-(4-methylsulfanylphenyl)butyl]-1,4-diazepane
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)propan-1-one —— C18H24N4O2S
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)propan-1-one
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)propan-1-one —— C18H24N4O2S
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)propan-1-one
    —— 1-[(1S)-1-(4-ethylsulfanylphenyl)-3-methylbutyl]piperazine —— C17H28N2S
    1-[(1S)-1-(4-ethylsulfanylphenyl)-3-methylbutyl]piperazine
    —— (3R)-4-(azepan-1-yl)-3-(4-methylsulfanylphenyl)butan-1-amine —— C17H28N2S
    (3R)-4-(azepan-1-yl)-3-(4-methylsulfanylphenyl)butan-1-amine
    —— 1-[(1R)-3-methyl-1-(4-methylsulfanylphenyl)butyl]-1,4-diazepane —— C17H28N2S
    1-[(1R)-3-methyl-1-(4-methylsulfanylphenyl)butyl]-1,4-diazepane
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one —— C19H18ClN3O3S
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one
    —— 4-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanylmethyl)-2-thiophen-3-yl-1,3-thiazole —— C15H16N4S3
    4-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanylmethyl)-2-thiophen-3-yl-1,3-thiazole
    —— 2-(4-Chlorophenyl)-5-[(5-thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole —— C16H10ClN3O2S2
    2-(4-Chlorophenyl)-5-[(5-thiophen-2-yl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 3-[2-[[4-Cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]-1,3-oxazolidin-2-one —— C18H22N4O3S2
    3-[2-[[4-Cyclohexyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]-1,3-oxazolidin-2-one
    —— (3S)-3-(4-propan-2-ylsulfanylphenyl)-3-thiophen-2-ylpropan-1-amine —— C16H21NS2
    (3S)-3-(4-propan-2-ylsulfanylphenyl)-3-thiophen-2-ylpropan-1-amine
    —— (3R)-3-cyclohexyl-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine —— C18H29NS
    (3R)-3-cyclohexyl-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine
    —— (3R)-3-(4-propan-2-ylsulfanylphenyl)-3-thiophen-2-ylpropan-1-amine —— C16H21NS2
    (3R)-3-(4-propan-2-ylsulfanylphenyl)-3-thiophen-2-ylpropan-1-amine
    —— (3S)-3-cyclohexyl-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine —— C18H29NS
    (3S)-3-cyclohexyl-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine
    —— 1-[(R)-cyclopropyl-(4-propan-2-ylsulfanylphenyl)methyl]piperazine —— C17H26N2S
    1-[(R)-cyclopropyl-(4-propan-2-ylsulfanylphenyl)methyl]piperazine