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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(2,3-dihydro-1-benzothiophen-5-yl)-1,3-thiazol-4-amine —— C11H10N2S2
    2-(2,3-dihydro-1-benzothiophen-5-yl)-1,3-thiazol-4-amine
    —— [(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C20H20N2O3S
    [(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C20H20N2O3S
    [(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— 1-[(2S)-2-hydroxy-2-thiophen-3-ylpropyl]-3-[(4-methylsulfanylphenyl)methyl]urea —— C16H20N2O2S2
    1-[(2S)-2-hydroxy-2-thiophen-3-ylpropyl]-3-[(4-methylsulfanylphenyl)methyl]urea
    —— 1-[(2R)-2-hydroxy-2-thiophen-3-ylpropyl]-3-[(4-methylsulfanylphenyl)methyl]urea —— C16H20N2O2S2
    1-[(2R)-2-hydroxy-2-thiophen-3-ylpropyl]-3-[(4-methylsulfanylphenyl)methyl]urea
    —— N-[(2S)-2-(dimethylamino)-2-thiophen-2-ylethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C12H16N4OS3
    N-[(2S)-2-(dimethylamino)-2-thiophen-2-ylethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— N-[(2R)-2-(dimethylamino)-2-thiophen-2-ylethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C12H16N4OS3
    N-[(2R)-2-(dimethylamino)-2-thiophen-2-ylethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— 2-(3,4-Dimethylphenyl)-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole —— C15H15N3O2S
    2-(3,4-Dimethylphenyl)-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 1-[(6R)-6-(hydroxymethyl)-1,4-oxazepan-4-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanone —— C12H18N2O3S2
    1-[(6R)-6-(hydroxymethyl)-1,4-oxazepan-4-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanone
    —— 1-[(6S)-6-(hydroxymethyl)-1,4-oxazepan-4-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanone —— C12H18N2O3S2
    1-[(6S)-6-(hydroxymethyl)-1,4-oxazepan-4-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanone
    —— (6R)-6-[(2,3-dihydroimidazo[2,1-b][1,3]thiazol-6-ylmethylamino)methyl]-1,4-oxazepan-6-ol —— C12H20N4O2S
    (6R)-6-[(2,3-dihydroimidazo[2,1-b][1,3]thiazol-6-ylmethylamino)methyl]-1,4-oxazepan-6-ol
    —— [(2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] (2R)-2-(4-methylphenyl)sulfanylpropanoate —— C21H25NO4S
    [(2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] (2R)-2-(4-methylphenyl)sulfanylpropanoate
    —— (2S)-2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C12H14FN5OS
    (2S)-2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— 5-methyl-3-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,2-oxazole —— C11H10N4OS2
    5-methyl-3-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,2-oxazole
    —— (2R)-N-methyl-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(5-propan-2-yl-1,2,4-oxadiazol-3-yl)methyl]propanamide —— C15H21N5O3S
    (2R)-N-methyl-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(5-propan-2-yl-1,2,4-oxadiazol-3-yl)methyl]propanamide
    —— (2S)-N-methyl-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(5-propan-2-yl-1,2,4-oxadiazol-3-yl)methyl]propanamide —— C15H21N5O3S
    (2S)-N-methyl-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(5-propan-2-yl-1,2,4-oxadiazol-3-yl)methyl]propanamide
    —— (3S)-3-[[2-(1-methylimidazol-2-yl)sulfanylethylamino]methyl]piperidin-3-ol —— C12H22N4OS
    (3S)-3-[[2-(1-methylimidazol-2-yl)sulfanylethylamino]methyl]piperidin-3-ol
    —— (3R)-3-[[2-(1-methylimidazol-2-yl)sulfanylethylamino]methyl]piperidin-3-ol —— C12H22N4OS
    (3R)-3-[[2-(1-methylimidazol-2-yl)sulfanylethylamino]methyl]piperidin-3-ol
    —— (6S)-6-[(2-pyridin-2-ylsulfanylethylamino)methyl]-1,4-oxazepan-6-ol —— C13H21N3O2S
    (6S)-6-[(2-pyridin-2-ylsulfanylethylamino)methyl]-1,4-oxazepan-6-ol
    —— (6R)-6-[(2-pyridin-2-ylsulfanylethylamino)methyl]-1,4-oxazepan-6-ol —— C13H21N3O2S
    (6R)-6-[(2-pyridin-2-ylsulfanylethylamino)methyl]-1,4-oxazepan-6-ol
    —— [4-(4-Methoxyphenyl)sulfanylphenyl]urea —— C14H14N2O2S
    [4-(4-Methoxyphenyl)sulfanylphenyl]urea
    —— [(6R)-4-[(2-propylsulfanylpyrimidin-5-yl)methyl]-1,4-oxazepan-6-yl]methanol —— C14H23N3O2S
    [(6R)-4-[(2-propylsulfanylpyrimidin-5-yl)methyl]-1,4-oxazepan-6-yl]methanol
    —— [(6S)-4-[(2-propylsulfanylpyrimidin-5-yl)methyl]-1,4-oxazepan-6-yl]methanol —— C14H23N3O2S
    [(6S)-4-[(2-propylsulfanylpyrimidin-5-yl)methyl]-1,4-oxazepan-6-yl]methanol
    —— 2-(4-fluorophenyl)sulfanyl-N-[[5-(2-methyl-1,3-thiazol-4-yl)thiophen-2-yl]methyl]acetamide —— C17H15FN2OS3
    2-(4-fluorophenyl)sulfanyl-N-[[5-(2-methyl-1,3-thiazol-4-yl)thiophen-2-yl]methyl]acetamide
    —— (3S)-3-[2-[5-(4-methylphenyl)sulfanylfuran-2-yl]imidazol-1-yl]pyrrolidin-2-one —— C18H17N3O2S
    (3S)-3-[2-[5-(4-methylphenyl)sulfanylfuran-2-yl]imidazol-1-yl]pyrrolidin-2-one
    —— (3R)-3-[2-[5-(4-methylphenyl)sulfanylfuran-2-yl]imidazol-1-yl]pyrrolidin-2-one —— C18H17N3O2S
    (3R)-3-[2-[5-(4-methylphenyl)sulfanylfuran-2-yl]imidazol-1-yl]pyrrolidin-2-one
    —— (2R)-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C16H20FN3OS3
    (2R)-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C11H15F3N4O3S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— methyl N-[(2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoyl]carbamate —— C9H12N2O3S2
    methyl N-[(2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoyl]carbamate
    —— (2S)-2-pyridin-2-ylsulfanyl-1-[4-(thiophen-2-ylmethyl)-1,4-diazepan-1-yl]propan-1-one —— C18H23N3OS2
    (2S)-2-pyridin-2-ylsulfanyl-1-[4-(thiophen-2-ylmethyl)-1,4-diazepan-1-yl]propan-1-one
    —— (2R)-2-pyridin-2-ylsulfanyl-1-[4-(thiophen-2-ylmethyl)-1,4-diazepan-1-yl]propan-1-one —— C18H23N3OS2
    (2R)-2-pyridin-2-ylsulfanyl-1-[4-(thiophen-2-ylmethyl)-1,4-diazepan-1-yl]propan-1-one
    —— (4R)-N-[2-(1-methylimidazol-2-yl)sulfanylethyl]-1,9-dioxaspiro[5.5]undecan-4-amine —— C15H25N3O2S
    (4R)-N-[2-(1-methylimidazol-2-yl)sulfanylethyl]-1,9-dioxaspiro[5.5]undecan-4-amine
    —— (4S)-N-[2-(1-methylimidazol-2-yl)sulfanylethyl]-1,9-dioxaspiro[5.5]undecan-4-amine —— C15H25N3O2S
    (4S)-N-[2-(1-methylimidazol-2-yl)sulfanylethyl]-1,9-dioxaspiro[5.5]undecan-4-amine
    —— (6S)-4-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-1,4-oxazepan-6-ol —— C13H18N4O3S
    (6S)-4-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-1,4-oxazepan-6-ol
    —— (6R)-4-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-1,4-oxazepan-6-ol —— C13H18N4O3S
    (6R)-4-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-1,4-oxazepan-6-ol
    —— 5-[(2S)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]pyrrolidin-2-yl]-3-propan-2-yl-1,2,4-oxadiazole —— C17H22N6O2S
    5-[(2S)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]pyrrolidin-2-yl]-3-propan-2-yl-1,2,4-oxadiazole
    —— 5-[(2R)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]pyrrolidin-2-yl]-3-propan-2-yl-1,2,4-oxadiazole —— C17H22N6O2S
    5-[(2R)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]pyrrolidin-2-yl]-3-propan-2-yl-1,2,4-oxadiazole
    —— (3R)-3-(piperidin-1-ylmethyl)-1-[(2-propylsulfanylpyrimidin-5-yl)methyl]pyrrolidin-3-ol —— C18H30N4OS
    (3R)-3-(piperidin-1-ylmethyl)-1-[(2-propylsulfanylpyrimidin-5-yl)methyl]pyrrolidin-3-ol
    —— 4-methyl-2-methylsulfanyl-6-[4-[(1S)-1-pyrrolidin-1-ylethyl]piperidin-1-yl]pyrimidine —— C17H28N4S
    4-methyl-2-methylsulfanyl-6-[4-[(1S)-1-pyrrolidin-1-ylethyl]piperidin-1-yl]pyrimidine
    —— 4-methyl-2-methylsulfanyl-6-[4-[(1R)-1-pyrrolidin-1-ylethyl]piperidin-1-yl]pyrimidine —— C17H28N4S
    4-methyl-2-methylsulfanyl-6-[4-[(1R)-1-pyrrolidin-1-ylethyl]piperidin-1-yl]pyrimidine
    —— (3S)-3-(piperidin-1-ylmethyl)-1-[(2-propylsulfanylpyrimidin-5-yl)methyl]pyrrolidin-3-ol —— C18H30N4OS
    (3S)-3-(piperidin-1-ylmethyl)-1-[(2-propylsulfanylpyrimidin-5-yl)methyl]pyrrolidin-3-ol
    —— (3S)-1-[1-(6-methyl-2-methylsulfanylpyrimidin-4-yl)piperidin-4-yl]piperidin-3-ol —— C16H26N4OS
    (3S)-1-[1-(6-methyl-2-methylsulfanylpyrimidin-4-yl)piperidin-4-yl]piperidin-3-ol
    —— (3R)-1-[1-(6-methyl-2-methylsulfanylpyrimidin-4-yl)piperidin-4-yl]piperidin-3-ol —— C16H26N4OS
    (3R)-1-[1-(6-methyl-2-methylsulfanylpyrimidin-4-yl)piperidin-4-yl]piperidin-3-ol
    —— (6S)-6-[[2-(2H-triazol-4-ylsulfanyl)ethylamino]methyl]-1,4-oxazepan-6-ol —— C10H19N5O2S
    (6S)-6-[[2-(2H-triazol-4-ylsulfanyl)ethylamino]methyl]-1,4-oxazepan-6-ol
    —— (6R)-6-[[2-(2H-triazol-4-ylsulfanyl)ethylamino]methyl]-1,4-oxazepan-6-ol —— C10H19N5O2S
    (6R)-6-[[2-(2H-triazol-4-ylsulfanyl)ethylamino]methyl]-1,4-oxazepan-6-ol
    —— 3-(N-methyl-4-propan-2-ylsulfanylanilino)propanoic acid —— C13H19NO2S
    3-(N-methyl-4-propan-2-ylsulfanylanilino)propanoic acid
    —— (2R)-2-amino-2-(4-cyclopentylsulfanylphenyl)propan-1-ol —— C14H21NOS
    (2R)-2-amino-2-(4-cyclopentylsulfanylphenyl)propan-1-ol
    —— (2S)-2-amino-2-(4-cyclopentylsulfanylphenyl)propan-1-ol —— C14H21NOS
    (2S)-2-amino-2-(4-cyclopentylsulfanylphenyl)propan-1-ol
    —— N,2-dimethyl-4-(4-propan-2-ylsulfanylphenyl)butan-2-amine —— C15H25NS
    N,2-dimethyl-4-(4-propan-2-ylsulfanylphenyl)butan-2-amine
    —— (S)-(1-methylpiperidin-4-yl)-(4-methylsulfanylphenyl)methanamine —— C14H22N2S
    (S)-(1-methylpiperidin-4-yl)-(4-methylsulfanylphenyl)methanamine