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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1,3-Dimethyl-1-[(4-methylsulfanylphenyl)methyl]thiourea —— C11H16N2S2
    1,3-Dimethyl-1-[(4-methylsulfanylphenyl)methyl]thiourea
    —— 3-Ethyl-1-methyl-1-[(4-methylsulfanylphenyl)methyl]thiourea —— C12H18N2S2
    3-Ethyl-1-methyl-1-[(4-methylsulfanylphenyl)methyl]thiourea
    —— 3-Cyclohexyl-1-methyl-1-[(4-methylsulfanylphenyl)methyl]thiourea —— C16H24N2S2
    3-Cyclohexyl-1-methyl-1-[(4-methylsulfanylphenyl)methyl]thiourea
    —— 2-[[2-(3,4-dimethylphenyl)sulfanylacetyl]-[(3S)-1,1-dioxothiolan-3-yl]amino]ethyl-dimethylazanium —— C18H29N2O3S2+
    2-[[2-(3,4-dimethylphenyl)sulfanylacetyl]-[(3S)-1,1-dioxothiolan-3-yl]amino]ethyl-dimethylazanium
    —— 2-(2,5-Dimethylfuran-3-yl)-5-[(3,4-dimethylphenyl)sulfanylmethyl]-1,3,4-oxadiazole —— C17H18N2O2S
    2-(2,5-Dimethylfuran-3-yl)-5-[(3,4-dimethylphenyl)sulfanylmethyl]-1,3,4-oxadiazole
    —— 1-methyl-3-[(1S,2S)-2-methylcyclohexyl]-1-[(4-methylsulfanylphenyl)methyl]thiourea —— C17H26N2S2
    1-methyl-3-[(1S,2S)-2-methylcyclohexyl]-1-[(4-methylsulfanylphenyl)methyl]thiourea
    —— 3-(Furan-2-ylmethyl)-1-methyl-1-[(4-methylsulfanylphenyl)methyl]thiourea —— C15H18N2OS2
    3-(Furan-2-ylmethyl)-1-methyl-1-[(4-methylsulfanylphenyl)methyl]thiourea
    —— 3-(2-Methoxyethyl)-1-methyl-1-[(4-methylsulfanylphenyl)methyl]thiourea —— C13H20N2OS2
    3-(2-Methoxyethyl)-1-methyl-1-[(4-methylsulfanylphenyl)methyl]thiourea
    —— 1-methyl-1-[(4-methylsulfanylphenyl)methyl]-3-[[(2R)-oxolan-2-yl]methyl]thiourea —— C15H22N2OS2
    1-methyl-1-[(4-methylsulfanylphenyl)methyl]-3-[[(2R)-oxolan-2-yl]methyl]thiourea
    —— Methyl 6-[[methyl-[(4-methylsulfanylphenyl)methyl]carbamothioyl]amino]hexanoate —— C17H26N2O2S2
    Methyl 6-[[methyl-[(4-methylsulfanylphenyl)methyl]carbamothioyl]amino]hexanoate
    —— 3-Cyclopropyl-1-methyl-1-[(4-methylsulfanylphenyl)methyl]thiourea —— C13H18N2S2
    3-Cyclopropyl-1-methyl-1-[(4-methylsulfanylphenyl)methyl]thiourea
    —— 1-[3-(4-fluorophenyl)sulfanylpropanoylamino]-3-[(1S,2R)-2-methylcyclohexyl]thiourea —— C17H24FN3OS2
    1-[3-(4-fluorophenyl)sulfanylpropanoylamino]-3-[(1S,2R)-2-methylcyclohexyl]thiourea
    —— 1-Methyl-1-[(4-methylsulfanylphenyl)methyl]-3-(2-morpholin-4-ium-4-ylethyl)thiourea —— C16H26N3OS2+
    1-Methyl-1-[(4-methylsulfanylphenyl)methyl]-3-(2-morpholin-4-ium-4-ylethyl)thiourea
    —— 1-[3-(4-Fluorophenyl)sulfanylpropanoylamino]-3-(3-methylsulfanylpropyl)thiourea —— C14H20FN3OS3
    1-[3-(4-Fluorophenyl)sulfanylpropanoylamino]-3-(3-methylsulfanylpropyl)thiourea
    —— 2-[[3-(4-Fluorophenyl)sulfanylpropanoylamino]carbamothioylamino]ethyl-dimethylazanium —— C14H22FN4OS2+
    2-[[3-(4-Fluorophenyl)sulfanylpropanoylamino]carbamothioylamino]ethyl-dimethylazanium
    —— 1-[3-(4-fluorophenyl)sulfanylpropanoylamino]-3-[(1S,2S)-2-methylcyclohexyl]thiourea —— C17H24FN3OS2
    1-[3-(4-fluorophenyl)sulfanylpropanoylamino]-3-[(1S,2S)-2-methylcyclohexyl]thiourea
    —— 1-[[2-(2-fluorophenyl)sulfanylacetyl]amino]-3-[(1R,2R)-2-methylcyclohexyl]thiourea —— C16H22FN3OS2
    1-[[2-(2-fluorophenyl)sulfanylacetyl]amino]-3-[(1R,2R)-2-methylcyclohexyl]thiourea
    —— 2-(2,4-dimethylphenyl)sulfanyl-1-[4-[(3R)-1,1-dioxothiolan-3-yl]piperazin-1-yl]ethanone —— C18H26N2O3S2
    2-(2,4-dimethylphenyl)sulfanyl-1-[4-[(3R)-1,1-dioxothiolan-3-yl]piperazin-1-yl]ethanone
    —— 1-(3-Chloro-4-methylphenyl)-3-[[2-(2-fluorophenyl)sulfanylacetyl]amino]thiourea —— C16H15ClFN3OS2
    1-(3-Chloro-4-methylphenyl)-3-[[2-(2-fluorophenyl)sulfanylacetyl]amino]thiourea
    —— (2S)-2-(2-chlorophenyl)sulfanyl-1-(2,2-dimethylmorpholin-4-yl)propan-1-one —— C15H20ClNO2S
    (2S)-2-(2-chlorophenyl)sulfanyl-1-(2,2-dimethylmorpholin-4-yl)propan-1-one
    —— (2R)-2-(2-chlorophenyl)sulfanyl-1-(2,2-dimethylmorpholin-4-yl)propan-1-one —— C15H20ClNO2S
    (2R)-2-(2-chlorophenyl)sulfanyl-1-(2,2-dimethylmorpholin-4-yl)propan-1-one
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[2-(2-methylphenyl)ethyl]acetamide —— C19H23NOS
    2-(2,4-dimethylphenyl)sulfanyl-N-[2-(2-methylphenyl)ethyl]acetamide
    —— 2-(2,4-Dimethylphenyl)sulfanyl-1-[4-[(5-methyl-1,2-oxazol-3-yl)methyl]piperazin-1-yl]ethanone —— C19H25N3O2S
    2-(2,4-Dimethylphenyl)sulfanyl-1-[4-[(5-methyl-1,2-oxazol-3-yl)methyl]piperazin-1-yl]ethanone
    —— 1-[[2-(2-fluorophenyl)sulfanylacetyl]amino]-3-[(1S,2R)-2-methylcyclohexyl]thiourea —— C16H22FN3OS2
    1-[[2-(2-fluorophenyl)sulfanylacetyl]amino]-3-[(1S,2R)-2-methylcyclohexyl]thiourea
    —— 1-[2-(Dimethylamino)ethyl]-3-[[2-(4-methylphenyl)sulfanylacetyl]amino]thiourea —— C14H22N4OS2
    1-[2-(Dimethylamino)ethyl]-3-[[2-(4-methylphenyl)sulfanylacetyl]amino]thiourea
    —— 1-[[2-(4-Methylphenyl)sulfanylacetyl]amino]-3-(2-methylprop-2-enyl)thiourea —— C14H19N3OS2
    1-[[2-(4-Methylphenyl)sulfanylacetyl]amino]-3-(2-methylprop-2-enyl)thiourea
    —— 1-[3-(4-fluorophenyl)sulfanylpropanoylamino]-3-[(1R,2R)-2-methylcyclohexyl]thiourea —— C17H24FN3OS2
    1-[3-(4-fluorophenyl)sulfanylpropanoylamino]-3-[(1R,2R)-2-methylcyclohexyl]thiourea
    —— N-[(3S,4S)-4-chloro-1,1-dioxothiolan-3-yl]-2-(2,4-dimethylphenyl)sulfanylacetamide —— C14H18ClNO3S2
    N-[(3S,4S)-4-chloro-1,1-dioxothiolan-3-yl]-2-(2,4-dimethylphenyl)sulfanylacetamide
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[(1-morpholin-4-ylcyclohexyl)methyl]acetamide —— C21H32N2O2S
    2-(2,4-dimethylphenyl)sulfanyl-N-[(1-morpholin-4-ylcyclohexyl)methyl]acetamide
    —— 1-(4-Chlorophenyl)-3-[[2-(4-methylphenyl)sulfanylacetyl]amino]thiourea —— C16H16ClN3OS2
    1-(4-Chlorophenyl)-3-[[2-(4-methylphenyl)sulfanylacetyl]amino]thiourea
    —— 1-(3-Chloro-4-methylphenyl)-3-[[2-(4-methylphenyl)sulfanylacetyl]amino]thiourea —— C17H18ClN3OS2
    1-(3-Chloro-4-methylphenyl)-3-[[2-(4-methylphenyl)sulfanylacetyl]amino]thiourea
    —— 1-[3-(4-Fluorophenyl)sulfanylpropanoylamino]-3-methylthiourea —— C11H14FN3OS2
    1-[3-(4-Fluorophenyl)sulfanylpropanoylamino]-3-methylthiourea
    —— 1-[[2-(2-Fluorophenyl)sulfanylacetyl]amino]-3-(2-methylprop-2-enyl)thiourea —— C13H16FN3OS2
    1-[[2-(2-Fluorophenyl)sulfanylacetyl]amino]-3-(2-methylprop-2-enyl)thiourea
    —— 1-[[2-(2-Fluorophenyl)sulfanylacetyl]amino]-3-(furan-2-ylmethyl)thiourea —— C14H14FN3O2S2
    1-[[2-(2-Fluorophenyl)sulfanylacetyl]amino]-3-(furan-2-ylmethyl)thiourea
    —— 2-[[[2-(2-Fluorophenyl)sulfanylacetyl]amino]carbamothioylamino]ethyl-dimethylazanium —— C13H20FN4OS2+
    2-[[[2-(2-Fluorophenyl)sulfanylacetyl]amino]carbamothioylamino]ethyl-dimethylazanium
    —— 1-[3-(4-fluorophenyl)sulfanylpropanoylamino]-3-[(1R,2S)-2-methylcyclohexyl]thiourea —— C17H24FN3OS2
    1-[3-(4-fluorophenyl)sulfanylpropanoylamino]-3-[(1R,2S)-2-methylcyclohexyl]thiourea
    —— 1-[2-(Dimethylamino)ethyl]-3-[[2-(2-fluorophenyl)sulfanylacetyl]amino]thiourea —— C13H19FN4OS2
    1-[2-(Dimethylamino)ethyl]-3-[[2-(2-fluorophenyl)sulfanylacetyl]amino]thiourea
    —— 2-(2,5-Dimethylfuran-3-yl)-5-[(2,4-dimethylphenyl)sulfanylmethyl]-1,3,4-oxadiazole —— C17H18N2O2S
    2-(2,5-Dimethylfuran-3-yl)-5-[(2,4-dimethylphenyl)sulfanylmethyl]-1,3,4-oxadiazole
    —— [2-oxo-2-(2-phenylsulfanylanilino)ethyl] 2-oxo-1H-pyridine-3-carboxylate —— C20H16N2O4S
    [2-oxo-2-(2-phenylsulfanylanilino)ethyl] 2-oxo-1H-pyridine-3-carboxylate
    —— Methyl 3-[2-[4-(3,4-dimethylphenyl)sulfanylanilino]-2-oxoethyl]sulfanylpropanoate —— C20H23NO3S2
    Methyl 3-[2-[4-(3,4-dimethylphenyl)sulfanylanilino]-2-oxoethyl]sulfanylpropanoate
    —— N-cyclopentyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C15H21N3O4S2
    N-cyclopentyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— (2S)-N,N-dimethyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanamide —— C9H13N3O2S
    (2S)-N,N-dimethyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanamide
    —— Methyl 3-[2-oxo-2-(2-phenylsulfanylanilino)ethyl]sulfanylpropanoate —— C18H19NO3S2
    Methyl 3-[2-oxo-2-(2-phenylsulfanylanilino)ethyl]sulfanylpropanoate
    —— (2R)-N-ethyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanamide —— C9H13N3O2S
    (2R)-N-ethyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanamide
    —— (E,3R)-5-methyl-1-methylsulfonylhex-1-en-3-amine —— C8H17NO2S
    (E,3R)-5-methyl-1-methylsulfonylhex-1-en-3-amine
    —— (2R)-2-[[5-[cyclopropyl(propanoyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide —— C19H23FN4O2S2
    (2R)-2-[[5-[cyclopropyl(propanoyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide
    —— N-cyclopropyl-N-[5-[2-(2-methylpropylamino)-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]propanamide —— C14H22N4O2S2
    N-cyclopropyl-N-[5-[2-(2-methylpropylamino)-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]propanamide
    —— N-cyclopropyl-N-[5-[2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]propanamide —— C17H26N4O2S2
    N-cyclopropyl-N-[5-[2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]propanamide
    —— N-[5-[2-(2-acetylhydrazinyl)-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]-N-cyclopropylpropanamide —— C12H17N5O3S2
    N-[5-[2-(2-acetylhydrazinyl)-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]-N-cyclopropylpropanamide
    —— N-cyclopropyl-N-[5-[2-oxo-2-(1,2,5-trimethylpyrrol-3-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]propanamide —— C17H22N4O2S2
    N-cyclopropyl-N-[5-[2-oxo-2-(1,2,5-trimethylpyrrol-3-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]propanamide