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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5-(4-fluorophenyl)thieno[2,3-d]pyrimidine —— C16H12FN5S2
    4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5-(4-fluorophenyl)thieno[2,3-d]pyrimidine
    —— 2-[4-(Azepan-1-ylsulfonyl)-2-nitrophenyl]sulfanyl-4-methyl-1,3-thiazole —— C16H19N3O4S3
    2-[4-(Azepan-1-ylsulfonyl)-2-nitrophenyl]sulfanyl-4-methyl-1,3-thiazole
    —— 4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-2,5,6-trimethylthieno[2,3-d]pyrimidine —— C13H15N5S2
    4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-2,5,6-trimethylthieno[2,3-d]pyrimidine
    —— 2-Methyl-4-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-5-phenylthieno[2,3-d]pyrimidine —— C17H12F3N5S2
    2-Methyl-4-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-5-phenylthieno[2,3-d]pyrimidine
    —— 4-[(4-Methyl-1,3-thiazol-2-yl)sulfanyl]-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine —— C14H13N3S3
    4-[(4-Methyl-1,3-thiazol-2-yl)sulfanyl]-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine
    —— 4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6-dimethyl-2-[(4-methylpiperidin-1-ium-1-yl)methyl]thieno[2,3-d]pyrimidine —— C19H27N6S2+
    4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6-dimethyl-2-[(4-methylpiperidin-1-ium-1-yl)methyl]thieno[2,3-d]pyrimidine
    —— 6,8-Dichloro-3-(2,4-dinitrophenyl)sulfanyl-[1,2,4]triazolo[4,3-a]pyridine —— C12H5Cl2N5O4S
    6,8-Dichloro-3-(2,4-dinitrophenyl)sulfanyl-[1,2,4]triazolo[4,3-a]pyridine
    —— N-[4-[5-(trifluoromethyl)pyridin-2-yl]sulfanylphenyl]acetamide —— C14H11F3N2OS
    N-[4-[5-(trifluoromethyl)pyridin-2-yl]sulfanylphenyl]acetamide
    —— 4-[4-(2,4-Dimethylphenyl)sulfanyl-3-nitrophenyl]sulfonylmorpholine —— C18H20N2O5S2
    4-[4-(2,4-Dimethylphenyl)sulfanyl-3-nitrophenyl]sulfonylmorpholine
    —— 4-(3,4-Dimethylphenyl)sulfanylthieno[2,3-d]pyrimidine —— C14H12N2S2
    4-(3,4-Dimethylphenyl)sulfanylthieno[2,3-d]pyrimidine
    —— 5-(4-Chlorophenyl)-4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]thieno[2,3-d]pyrimidine —— C16H12ClN5S2
    5-(4-Chlorophenyl)-4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]thieno[2,3-d]pyrimidine
    —— N-(cyclohexen-1-yl)-N-ethyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H24N4O2S
    N-(cyclohexen-1-yl)-N-ethyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 4-[[4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholine —— C17H22N6OS2
    4-[[4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholine
    —— (7R)-4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine —— C15H17N5S2
    (7R)-4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine
    —— 4-Methyl-2-<2,4-dinitro-phenylmercapto>-thiazol 5243-72-1 C10H7N3O4S2
    4-Methyl-2-<2,4-dinitro-phenylmercapto>-thiazol
    —— 1-[(3R)-3-ethylsulfanylazepan-1-yl]-2-phenylsulfanylethanone —— C16H23NOS2
    1-[(3R)-3-ethylsulfanylazepan-1-yl]-2-phenylsulfanylethanone
    —— N-[(2S)-3-ethyl-2-hydroxypentyl]-2-phenylsulfanylacetamide —— C15H23NO2S
    N-[(2S)-3-ethyl-2-hydroxypentyl]-2-phenylsulfanylacetamide
    —— 2-(2,4-Dimethylphenyl)sulfanyl-5-nitrobenzonitrile —— C15H12N2O2S
    2-(2,4-Dimethylphenyl)sulfanyl-5-nitrobenzonitrile
    —— 4-[[12-(4-Fluorophenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholine —— C20H20FN3OS2
    4-[[12-(4-Fluorophenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholine
    —— 3-(2-Chloro-4-nitrophenyl)sulfanyl-4-methyl-5-(trifluoromethyl)-1,2,4-triazole —— C10H6ClF3N4O2S
    3-(2-Chloro-4-nitrophenyl)sulfanyl-4-methyl-5-(trifluoromethyl)-1,2,4-triazole
    —— 4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-6,7-dimethoxy-2-phenylquinazoline —— C20H19N5O2S
    4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-6,7-dimethoxy-2-phenylquinazoline
    —— 4-[6-(4-Fluorophenyl)sulfanylpyridin-3-yl]sulfonylmorpholine —— C15H15FN2O3S2
    4-[6-(4-Fluorophenyl)sulfanylpyridin-3-yl]sulfonylmorpholine
    —— 4-(2,5-Dimethylphenyl)sulfanylthieno[2,3-d]pyrimidine —— C14H12N2S2
    4-(2,5-Dimethylphenyl)sulfanylthieno[2,3-d]pyrimidine
    —— N-[(3R)-1-benzylpyrrolidin-3-yl]-2-(2-cyanophenyl)sulfanylbenzamide —— C25H23N3OS
    N-[(3R)-1-benzylpyrrolidin-3-yl]-2-(2-cyanophenyl)sulfanylbenzamide
    —— (3-nitropyridin-2-yl) N,N-dimethylcarbamodithioate —— C8H9N3O2S2
    (3-nitropyridin-2-yl) N,N-dimethylcarbamodithioate
    —— N-[(2R)-3-ethyl-2-hydroxypentyl]-2-phenylsulfanylacetamide —— C15H23NO2S
    N-[(2R)-3-ethyl-2-hydroxypentyl]-2-phenylsulfanylacetamide
    —— 2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-nitrobenzonitrile —— C15H10N4O2S2
    2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-nitrobenzonitrile
    —— 3-(4-methoxyphenyl)-5-(2-nitrophenyl)sulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazole —— C20H20N4O4S
    3-(4-methoxyphenyl)-5-(2-nitrophenyl)sulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazole
    —— 5,6-Dimethyl-4-(2-nitrophenyl)sulfanylthieno[2,3-d]pyrimidine —— C14H11N3O2S2
    5,6-Dimethyl-4-(2-nitrophenyl)sulfanylthieno[2,3-d]pyrimidine
    —— [5,6-Dimethyl-4-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulfanyl)thieno[2,3-d]pyrimidin-2-yl]methyl-diethylazanium —— C19H23N6S2+
    [5,6-Dimethyl-4-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulfanyl)thieno[2,3-d]pyrimidin-2-yl]methyl-diethylazanium
    —— 12-(2,4-Dinitrophenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C15H10N4O4S2
    12-(2,4-Dinitrophenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 4-(2-Nitrophenyl)sulfanylthieno[2,3-d]pyrimidine —— C12H7N3O2S2
    4-(2-Nitrophenyl)sulfanylthieno[2,3-d]pyrimidine
    —— 3-(2-Methoxyethyl)-2-(2-nitrophenyl)sulfanylquinazolin-4-one —— C17H15N3O4S
    3-(2-Methoxyethyl)-2-(2-nitrophenyl)sulfanylquinazolin-4-one
    —— 2-[(10-Methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-3-prop-2-enylquinazolin-4-one —— C21H18N4OS2
    2-[(10-Methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-3-prop-2-enylquinazolin-4-one
    —— 2-(2,4-Dinitrophenyl)sulfanyl-3-(2-methylpropyl)quinazolin-4-one —— C18H16N4O5S
    2-(2,4-Dinitrophenyl)sulfanyl-3-(2-methylpropyl)quinazolin-4-one
    —— N-[4-[2-nitro-4-(propan-2-ylsulfamoyl)phenyl]sulfanylphenyl]acetamide —— C17H19N3O5S2
    N-[4-[2-nitro-4-(propan-2-ylsulfamoyl)phenyl]sulfanylphenyl]acetamide
    —— (2R)-N-[1-(3-bromophenyl)cyclobutyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C16H19BrN4OS
    (2R)-N-[1-(3-bromophenyl)cyclobutyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 4-(4-Fluorophenyl)sulfanyl-3-nitrobenzenesulfonamide —— C12H9FN2O4S2
    4-(4-Fluorophenyl)sulfanyl-3-nitrobenzenesulfonamide
    —— 2-[[4-(4-Fluorophenyl)sulfanyl-3-nitrophenyl]sulfonylamino]ethyl-dimethylazanium —— C16H19FN3O4S2+
    2-[[4-(4-Fluorophenyl)sulfanyl-3-nitrophenyl]sulfonylamino]ethyl-dimethylazanium
    —— 2-(2-Nitrophenyl)sulfanyl-3-propylquinazolin-4-one —— C17H15N3O3S
    2-(2-Nitrophenyl)sulfanyl-3-propylquinazolin-4-one
    —— 4-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-3-nitrobenzenesulfonamide —— C14H12N2O6S2
    4-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-3-nitrobenzenesulfonamide
    —— N-[4-(5-morpholin-4-ylsulfonylpyridin-2-yl)sulfanylphenyl]acetamide —— C17H19N3O4S2
    N-[4-(5-morpholin-4-ylsulfonylpyridin-2-yl)sulfanylphenyl]acetamide
    —— 2-(3,4-Dimethylphenyl)sulfanyl-3-nitropyridine —— C13H12N2O2S
    2-(3,4-Dimethylphenyl)sulfanyl-3-nitropyridine
    —— [(2R)-1-[[2-(2-cyanophenyl)sulfanylbenzoyl]amino]-3-phenylpropan-2-yl]-dimethylazanium —— C25H26N3OS+
    [(2R)-1-[[2-(2-cyanophenyl)sulfanylbenzoyl]amino]-3-phenylpropan-2-yl]-dimethylazanium
    —— 4-Chloro-5-(4-fluorophenyl)sulfanyl-2-phenylpyridazin-3-one —— C16H10ClFN2OS
    4-Chloro-5-(4-fluorophenyl)sulfanyl-2-phenylpyridazin-3-one
    —— 5-Nitro-2-(5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-ylsulfanyl)benzonitrile —— C17H12N4O2S2
    5-Nitro-2-(5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-ylsulfanyl)benzonitrile
    —— 12-(2-Nitrophenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C15H11N3O2S2
    12-(2-Nitrophenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— N-[[5,6-dimethyl-4-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulfanyl)thieno[2,3-d]pyrimidin-2-yl]methyl]-N-ethylethanamine —— C19H22N6S2
    N-[[5,6-dimethyl-4-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulfanyl)thieno[2,3-d]pyrimidin-2-yl]methyl]-N-ethylethanamine
    —— 5-Methyl-1-(2-nitrophenyl)sulfanyl-[1,2,4]triazolo[4,3-a]quinoline —— C17H12N4O2S
    5-Methyl-1-(2-nitrophenyl)sulfanyl-[1,2,4]triazolo[4,3-a]quinoline
    —— (5-chloro-6-oxo-1-phenylpyridazin-4-yl) N,N-dimethylcarbamodithioate —— C13H12ClN3OS2
    (5-chloro-6-oxo-1-phenylpyridazin-4-yl) N,N-dimethylcarbamodithioate