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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-ethyl-3-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-1-(thiophen-2-ylmethyl)urea —— C18H24N2OS2
    1-ethyl-3-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-1-(thiophen-2-ylmethyl)urea
    —— 1-benzyl-1-methyl-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C20H26N2OS
    1-benzyl-1-methyl-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 1-methyl-1-[(2-methylphenyl)methyl]-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C21H28N2OS
    1-methyl-1-[(2-methylphenyl)methyl]-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 1-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-3-(pyridin-3-ylmethyl)urea —— C17H21N3OS
    1-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-3-(pyridin-3-ylmethyl)urea
    —— 3-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-1-methyl-1-[(2-methylphenyl)methyl]urea —— C20H26N2OS
    3-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-1-methyl-1-[(2-methylphenyl)methyl]urea
    —— N-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]thiomorpholine-4-carboxamide —— C16H24N2OS2
    N-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]thiomorpholine-4-carboxamide
    —— 1-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-3-propan-2-ylurea —— C14H22N2OS
    1-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-3-propan-2-ylurea
    —— 1-ethyl-3-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-1-(thiophen-2-ylmethyl)urea —— C18H24N2OS2
    1-ethyl-3-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-1-(thiophen-2-ylmethyl)urea
    —— 1-[(4-fluorophenyl)methyl]-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C19H23FN2OS
    1-[(4-fluorophenyl)methyl]-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 1-benzyl-3-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-1-methylurea —— C19H24N2OS
    1-benzyl-3-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-1-methylurea
    —— 1-(3-ethoxypropyl)-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C17H28N2O2S
    1-(3-ethoxypropyl)-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 1-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-3-(thiophen-2-ylmethyl)urea —— C16H20N2OS2
    1-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]-3-(thiophen-2-ylmethyl)urea
    —— 1-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-(2-pyridin-2-ylethyl)urea —— C18H23N3OS
    1-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-(2-pyridin-2-ylethyl)urea
    —— 1-benzyl-3-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]urea —— C18H22N2OS
    1-benzyl-3-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]urea
    —— 1-[(4-fluorophenyl)methyl]-1-methyl-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C20H25FN2OS
    1-[(4-fluorophenyl)methyl]-1-methyl-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 1-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-propan-2-ylurea —— C14H22N2OS
    1-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-propan-2-ylurea
    —— 1-cyclopentyl-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C17H26N2OS
    1-cyclopentyl-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 1-cyclopentyl-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C17H26N2OS
    1-cyclopentyl-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 1-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-(thiophen-2-ylmethyl)urea —— C16H20N2OS2
    1-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-(thiophen-2-ylmethyl)urea
    —— (1S)-1-(4-bromophenyl)-2-(1-prop-2-enyltetrazol-5-yl)sulfanylethanol —— C12H13BrN4OS
    (1S)-1-(4-bromophenyl)-2-(1-prop-2-enyltetrazol-5-yl)sulfanylethanol
    —— 1-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-(pyridin-3-ylmethyl)urea —— C17H21N3OS
    1-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-(pyridin-3-ylmethyl)urea
    —— 1-[(4-fluorophenyl)methyl]-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C19H23FN2OS
    1-[(4-fluorophenyl)methyl]-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 1-benzyl-3-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]urea —— C18H22N2OS
    1-benzyl-3-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]urea
    —— N-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]thiomorpholine-4-carboxamide —— C16H24N2OS2
    N-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]thiomorpholine-4-carboxamide
    —— 2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-thiophen-2-ylethyl]acetamide —— C11H13N3OS4
    2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-thiophen-2-ylethyl]acetamide
    —— 1-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-prop-2-enylurea —— C14H20N2OS
    1-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]-3-prop-2-enylurea
    —— (2S)-2-[[5-[(1R)-2-oxocyclohexyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C14H18N2O2S3
    (2S)-2-[[5-[(1R)-2-oxocyclohexyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— 1-[2-(4-methylphenyl)sulfanylethyl]-3-[[(2S)-oxolan-2-yl]methyl]thiourea —— C15H22N2OS2
    1-[2-(4-methylphenyl)sulfanylethyl]-3-[[(2S)-oxolan-2-yl]methyl]thiourea
    —— 1-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]-3-(2-thiophen-2-ylethyl)urea —— C18H24N2OS2
    1-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]-3-(2-thiophen-2-ylethyl)urea
    —— 2-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide —— C15H21NO3S2
    2-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide
    —— (2R)-2-[[5-[(1R)-2-oxocyclohexyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C14H18N2O2S3
    (2R)-2-[[5-[(1R)-2-oxocyclohexyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— Dimethyl-[3-[2-(4-methylphenyl)sulfanylethylcarbamothioylamino]propyl]azanium —— C15H26N3S2+
    Dimethyl-[3-[2-(4-methylphenyl)sulfanylethylcarbamothioylamino]propyl]azanium
    —— 4-methyl-3-[(1R)-1-phenylethyl]sulfanyl-1,2,4-triazole —— C11H13N3S
    4-methyl-3-[(1R)-1-phenylethyl]sulfanyl-1,2,4-triazole
    —— 1-[2-(4-Methylphenyl)sulfanylethyl]-3-(2-morpholin-4-ium-4-ylethyl)thiourea —— C16H26N3OS2+
    1-[2-(4-Methylphenyl)sulfanylethyl]-3-(2-morpholin-4-ium-4-ylethyl)thiourea
    —— (2S)-2-[[5-[(1S)-2-oxocyclohexyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C14H18N2O2S3
    (2S)-2-[[5-[(1S)-2-oxocyclohexyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— 1-Methyl-3-[2-(4-methylphenyl)sulfanylethyl]thiourea —— C11H16N2S2
    1-Methyl-3-[2-(4-methylphenyl)sulfanylethyl]thiourea
    —— 2-[2-(4-Chlorophenyl)sulfanylethylcarbamothioylamino]ethyl-dimethylazanium —— C13H21ClN3S2+
    2-[2-(4-Chlorophenyl)sulfanylethylcarbamothioylamino]ethyl-dimethylazanium
    —— 2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(S)-phenyl(1,3-thiazol-2-yl)methyl]acetamide —— C20H16N4OS4
    2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(S)-phenyl(1,3-thiazol-2-yl)methyl]acetamide
    —— 5-[(1S)-1-phenylethyl]sulfanyl-2-[(1R)-1-phenylethyl]sulfanyl-1,3,4-thiadiazole —— C18H18N2S3
    5-[(1S)-1-phenylethyl]sulfanyl-2-[(1R)-1-phenylethyl]sulfanyl-1,3,4-thiadiazole
    —— 4-methyl-3-[(1S)-1-phenylethyl]sulfanyl-1,2,4-triazole —— C11H13N3S
    4-methyl-3-[(1S)-1-phenylethyl]sulfanyl-1,2,4-triazole
    —— 2,5-bis[[(1R)-1-phenylethyl]sulfanyl]-1,3,4-thiadiazole —— C18H18N2S3
    2,5-bis[[(1R)-1-phenylethyl]sulfanyl]-1,3,4-thiadiazole
    —— 2-[(1S)-1-pyridin-2-ylsulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C13H11N3OS2
    2-[(1S)-1-pyridin-2-ylsulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— (2S)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]propanamide —— C20H21N3O2S
    (2S)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]propanamide
    —— 1-(2-Methoxyethyl)-3-[2-(4-methylphenyl)sulfanylethyl]thiourea —— C13H20N2OS2
    1-(2-Methoxyethyl)-3-[2-(4-methylphenyl)sulfanylethyl]thiourea
    —— 2,5-bis[[(1S)-1-phenylethyl]sulfanyl]-1,3,4-thiadiazole —— C18H18N2S3
    2,5-bis[[(1S)-1-phenylethyl]sulfanyl]-1,3,4-thiadiazole
    —— 2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(R)-phenyl(1,3-thiazol-2-yl)methyl]acetamide —— C20H16N4OS4
    2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(R)-phenyl(1,3-thiazol-2-yl)methyl]acetamide
    —— (2R)-2-methyl-N-(2-phenylsulfanylethyl)pentanamide —— C14H21NOS
    (2R)-2-methyl-N-(2-phenylsulfanylethyl)pentanamide
    —— (2R)-N-cyclohexyl-N-methyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H21N3OS3
    (2R)-N-cyclohexyl-N-methyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— methyl N-[2-(4-chlorophenyl)sulfanylethylcarbamothioylamino]carbamate —— C11H14ClN3O2S2
    methyl N-[2-(4-chlorophenyl)sulfanylethylcarbamothioylamino]carbamate
    —— (1R)-1-(4-bromophenyl)-2-(1-prop-2-enyltetrazol-5-yl)sulfanylethanol —— C12H13BrN4OS
    (1R)-1-(4-bromophenyl)-2-(1-prop-2-enyltetrazol-5-yl)sulfanylethanol