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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(2-fluorophenyl)-3-[[(E)-3-phenylsulfanylprop-2-enoyl]amino]thiourea —— C16H14FN3OS2
    1-(2-fluorophenyl)-3-[[(E)-3-phenylsulfanylprop-2-enoyl]amino]thiourea
    —— (2S)-2-methyl-N-[(2-phenylsulfanylphenyl)methyl]butanamide —— C18H21NOS
    (2S)-2-methyl-N-[(2-phenylsulfanylphenyl)methyl]butanamide
    —— (2R)-N-[(2-phenylsulfanylphenyl)methyl]-1,4-dioxane-2-carboxamide —— C18H19NO3S
    (2R)-N-[(2-phenylsulfanylphenyl)methyl]-1,4-dioxane-2-carboxamide
    —— (3S)-N'-[2-(3,4-dimethylphenyl)sulfanylacetyl]-1,1-dioxothiolane-3-carbohydrazide —— C15H20N2O4S2
    (3S)-N'-[2-(3,4-dimethylphenyl)sulfanylacetyl]-1,1-dioxothiolane-3-carbohydrazide
    —— (3S)-N'-[3-(4-fluorophenyl)sulfanylpropanoyl]-1,1-dioxothiolane-3-carbohydrazide —— C14H17FN2O4S2
    (3S)-N'-[3-(4-fluorophenyl)sulfanylpropanoyl]-1,1-dioxothiolane-3-carbohydrazide
    —— (2R)-2-methyl-N-[(2-phenylsulfanylphenyl)methyl]butanamide —— C18H21NOS
    (2R)-2-methyl-N-[(2-phenylsulfanylphenyl)methyl]butanamide
    —— (3R)-1,1-dioxo-N-[(2-phenylsulfanylphenyl)methyl]thiolane-3-carboxamide —— C18H19NO3S2
    (3R)-1,1-dioxo-N-[(2-phenylsulfanylphenyl)methyl]thiolane-3-carboxamide
    —— (3S)-1,1-dioxo-N-[(2-phenylsulfanylphenyl)methyl]thiolane-3-carboxamide —— C18H19NO3S2
    (3S)-1,1-dioxo-N-[(2-phenylsulfanylphenyl)methyl]thiolane-3-carboxamide
    —— (2S)-N-[(2-phenylsulfanylphenyl)methyl]-1,4-dioxane-2-carboxamide —— C18H19NO3S
    (2S)-N-[(2-phenylsulfanylphenyl)methyl]-1,4-dioxane-2-carboxamide
    —— (3R)-N'-[2-(3,4-dimethylphenyl)sulfanylacetyl]-1,1-dioxothiolane-3-carbohydrazide —— C15H20N2O4S2
    (3R)-N'-[2-(3,4-dimethylphenyl)sulfanylacetyl]-1,1-dioxothiolane-3-carbohydrazide
    —— (3S)-1,1-dioxo-N'-(2-phenylsulfanylacetyl)thiolane-3-carbohydrazide —— C13H16N2O4S2
    (3S)-1,1-dioxo-N'-(2-phenylsulfanylacetyl)thiolane-3-carbohydrazide
    —— (3S)-N'-[3-(4-chlorophenyl)sulfanylpropanoyl]-1,1-dioxothiolane-3-carbohydrazide —— C14H17ClN2O4S2
    (3S)-N'-[3-(4-chlorophenyl)sulfanylpropanoyl]-1,1-dioxothiolane-3-carbohydrazide
    —— 2-(difluoromethyl)-4-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylquinazoline —— C15H14F2N6OS
    2-(difluoromethyl)-4-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylquinazoline
    —— 5-[2-(difluoromethyl)quinazolin-4-yl]sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C16H15F2N5OS2
    5-[2-(difluoromethyl)quinazolin-4-yl]sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— 2-(difluoromethyl)-4-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylquinazoline —— C15H14F2N6OS
    2-(difluoromethyl)-4-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylquinazoline
    —— 5-[2-(difluoromethyl)quinazolin-4-yl]sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C16H15F2N5OS2
    5-[2-(difluoromethyl)quinazolin-4-yl]sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— 1-[(2S)-2-(dimethylamino)-2-(furan-2-yl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea —— C20H23N5O2S
    1-[(2S)-2-(dimethylamino)-2-(furan-2-yl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea
    —— 1-[(1R)-1-(2-methylphenyl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea —— C21H22N4OS
    1-[(1R)-1-(2-methylphenyl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea
    —— 1-[(1R)-1-(3,4-difluorophenyl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea —— C20H18F2N4OS
    1-[(1R)-1-(3,4-difluorophenyl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea
    —— 1-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)-3-[[(3S)-oxolan-3-yl]methyl]urea —— C17H20N4O2S
    1-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)-3-[[(3S)-oxolan-3-yl]methyl]urea
    —— 1-[(1S)-1-(2-methylphenyl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea —— C21H22N4OS
    1-[(1S)-1-(2-methylphenyl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea
    —— 1-[(2R)-2-(dimethylamino)-2-(furan-2-yl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea —— C20H23N5O2S
    1-[(2R)-2-(dimethylamino)-2-(furan-2-yl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea
    —— 1-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)-3-[[(3R)-oxolan-3-yl]methyl]urea —— C17H20N4O2S
    1-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)-3-[[(3R)-oxolan-3-yl]methyl]urea
    —— 1-[(1S)-1-(3,4-difluorophenyl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea —— C20H18F2N4OS
    1-[(1S)-1-(3,4-difluorophenyl)ethyl]-3-(2-methyl-4-pyrimidin-2-ylsulfanylphenyl)urea
    —— 4-Acetyl-2-amino-5-cyano-6-(propylsulfanyl)-3-pyridyl cyanide —— C12H12N4OS
    4-Acetyl-2-amino-5-cyano-6-(propylsulfanyl)-3-pyridyl cyanide
    —— [2-[2-(4-bromophenyl)sulfanylethylamino]-2-oxoethyl] (E)-but-2-enoate —— C14H16BrNO3S
    [2-[2-(4-bromophenyl)sulfanylethylamino]-2-oxoethyl] (E)-but-2-enoate
    —— (E)-N-cyclopropyl-3-phenylsulfanylprop-2-enamide —— C12H13NOS
    (E)-N-cyclopropyl-3-phenylsulfanylprop-2-enamide
    —— (E)-N-[(3-chlorophenyl)methyl]-3-phenylsulfanylprop-2-enamide —— C16H14ClNOS
    (E)-N-[(3-chlorophenyl)methyl]-3-phenylsulfanylprop-2-enamide
    —— (1S,2R)-1-[5-[(4-bromophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine —— C14H18BrN3OS
    (1S,2R)-1-[5-[(4-bromophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine
    —— (1S,2S)-1-[5-[(4-bromophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine —— C14H18BrN3OS
    (1S,2S)-1-[5-[(4-bromophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine
    —— (2R)-2-[2-(4-methylphenyl)sulfanylethyl]piperidin-1-ium —— C14H22NS+
    (2R)-2-[2-(4-methylphenyl)sulfanylethyl]piperidin-1-ium
    —— (2R)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C13H14N2O2S2
    (2R)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— [(1S,2S)-1-[5-[(3-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium —— C14H19ClN3OS+
    [(1S,2S)-1-[5-[(3-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium
    —— 2-[[(2S)-1,1-dioxothiolan-2-yl]methylsulfanyl]-4,6-dimethylpyridine-3-carbonitrile —— C13H16N2O2S2
    2-[[(2S)-1,1-dioxothiolan-2-yl]methylsulfanyl]-4,6-dimethylpyridine-3-carbonitrile
    —— (2S)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)propanamide —— C16H23N3O2S2
    (2S)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)propanamide
    —— (2R)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)propanamide —— C16H23N3O2S2
    (2R)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-di(propan-2-yl)propanamide
    —— 2-{[(4-Bromophenyl)methyl]sulfanyl}-5-(pyrrolidin-2-YL)-1,3,4-oxadiazole —— C13H14BrN3OS
    2-{[(4-Bromophenyl)methyl]sulfanyl}-5-(pyrrolidin-2-YL)-1,3,4-oxadiazole
    —— 2-[[(2R)-1,1-dioxothiolan-2-yl]methylsulfanyl]-4,6-dimethylpyridine-3-carbonitrile —— C13H16N2O2S2
    2-[[(2R)-1,1-dioxothiolan-2-yl]methylsulfanyl]-4,6-dimethylpyridine-3-carbonitrile
    —— (2S)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C13H14N2O2S2
    (2S)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— (2R)-1-(4-ethylpiperazin-1-yl)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one —— C16H22N4O2S2
    (2R)-1-(4-ethylpiperazin-1-yl)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one
    —— (2S)-1-(4-ethylpiperazin-1-yl)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one —— C16H22N4O2S2
    (2S)-1-(4-ethylpiperazin-1-yl)-2-[[5-(3-methylthiophen-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one
    —— N'-[2-(2,5-difluorophenyl)sulfanylacetyl]-2-(2-oxopyridin-1-yl)acetohydrazide —— C15H13F2N3O3S
    N'-[2-(2,5-difluorophenyl)sulfanylacetyl]-2-(2-oxopyridin-1-yl)acetohydrazide
    —— 2-(2-oxopyridin-1-yl)-N'-(2-phenylsulfanylacetyl)acetohydrazide —— C15H15N3O3S
    2-(2-oxopyridin-1-yl)-N'-(2-phenylsulfanylacetyl)acetohydrazide
    —— N'-[2-(3,4-dimethylphenyl)sulfanylacetyl]-2-(2-oxopyridin-1-yl)acetohydrazide —— C17H19N3O3S
    N'-[2-(3,4-dimethylphenyl)sulfanylacetyl]-2-(2-oxopyridin-1-yl)acetohydrazide
    —— N'-[2-(4-fluorophenyl)sulfanylacetyl]-2-(2-oxopyridin-1-yl)acetohydrazide —— C15H14FN3O3S
    N'-[2-(4-fluorophenyl)sulfanylacetyl]-2-(2-oxopyridin-1-yl)acetohydrazide
    —— N'-[2-(4-bromo-2-methylphenyl)sulfanylacetyl]-2-(2-oxopyridin-1-yl)acetohydrazide —— C16H16BrN3O3S
    N'-[2-(4-bromo-2-methylphenyl)sulfanylacetyl]-2-(2-oxopyridin-1-yl)acetohydrazide
    —— (2S)-N,N,3-trimethyl-2-[1-(oxan-4-yl)tetrazol-5-yl]sulfanylbutanamide —— C13H23N5O2S
    (2S)-N,N,3-trimethyl-2-[1-(oxan-4-yl)tetrazol-5-yl]sulfanylbutanamide
    —— (2R)-N,N,3-trimethyl-2-[1-(oxan-4-yl)tetrazol-5-yl]sulfanylbutanamide —— C13H23N5O2S
    (2R)-N,N,3-trimethyl-2-[1-(oxan-4-yl)tetrazol-5-yl]sulfanylbutanamide
    —— (E)-N'-[2-[2-(4-fluorophenyl)-1,3-thiazol-4-yl]acetyl]-3-phenylsulfanylprop-2-enehydrazide —— C20H16FN3O2S2
    (E)-N'-[2-[2-(4-fluorophenyl)-1,3-thiazol-4-yl]acetyl]-3-phenylsulfanylprop-2-enehydrazide
    —— (2S)-N'-[2-[2-(4-fluorophenyl)-1,3-thiazol-4-yl]acetyl]-2-phenylsulfanylpropanehydrazide —— C20H18FN3O2S2
    (2S)-N'-[2-[2-(4-fluorophenyl)-1,3-thiazol-4-yl]acetyl]-2-phenylsulfanylpropanehydrazide