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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-N-(2-methylbutan-2-yl)-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H25N5OS
    (2S)-N-(2-methylbutan-2-yl)-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— N,N-dimethyl-5-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]pentanamide —— C18H25N3O2S
    N,N-dimethyl-5-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]pentanamide
    —— N-[[(2R)-oxolan-2-yl]methyl]-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H21N5O2S
    N-[[(2R)-oxolan-2-yl]methyl]-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2R)-N-(2-methylbutan-2-yl)-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H25N5OS
    (2R)-N-(2-methylbutan-2-yl)-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— N-[[(2S)-oxolan-2-yl]methyl]-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H21N5O2S
    N-[[(2S)-oxolan-2-yl]methyl]-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C17H23N5O2S
    1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-[[4-(2-pyridin-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— 2-[5-(4-methylpyrazol-1-yl)pentylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C20H26N4OS
    2-[5-(4-methylpyrazol-1-yl)pentylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— N,N-dimethyl-5-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]pentanamide —— C18H25N3O2S
    N,N-dimethyl-5-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]pentanamide
    —— 1-[2-(4-Chlorophenyl)sulfanylethyl]-3-(3-piperidin-1-ium-1-ylpropyl)thiourea —— C17H27ClN3S2+
    1-[2-(4-Chlorophenyl)sulfanylethyl]-3-(3-piperidin-1-ium-1-ylpropyl)thiourea
    —— 1-[(1R)-1-(4-tert-butyl-1,3-thiazol-2-yl)ethyl]-3-[2-(4-chlorophenyl)sulfanylethyl]urea —— C18H24ClN3OS2
    1-[(1R)-1-(4-tert-butyl-1,3-thiazol-2-yl)ethyl]-3-[2-(4-chlorophenyl)sulfanylethyl]urea
    —— 1-[(1S)-1-(4-tert-butyl-1,3-thiazol-2-yl)ethyl]-3-[2-(4-chlorophenyl)sulfanylethyl]urea —— C18H24ClN3OS2
    1-[(1S)-1-(4-tert-butyl-1,3-thiazol-2-yl)ethyl]-3-[2-(4-chlorophenyl)sulfanylethyl]urea
    —— N-[(4-methoxyphenyl)methyl]-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide —— C21H20N2O2S
    N-[(4-methoxyphenyl)methyl]-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide
    —— 3-[2-(4-Chlorophenyl)sulfanylethylcarbamothioylamino]propyl-dimethylazanium —— C14H23ClN3S2+
    3-[2-(4-Chlorophenyl)sulfanylethylcarbamothioylamino]propyl-dimethylazanium
    —— 1-[2-(4-Chlorophenyl)sulfanylethyl]-3-(2-methylprop-2-enyl)thiourea —— C13H17ClN2S2
    1-[2-(4-Chlorophenyl)sulfanylethyl]-3-(2-methylprop-2-enyl)thiourea
    —— 1-[(2,4-Dimethylphenyl)methyl]-1-methyl-3-(2-phenylsulfanylethyl)thiourea —— C19H24N2S2
    1-[(2,4-Dimethylphenyl)methyl]-1-methyl-3-(2-phenylsulfanylethyl)thiourea
    —— 1-[(1S)-1-(2,4-difluorophenyl)ethyl]-3-(2-phenylsulfanylethyl)thiourea —— C17H18F2N2S2
    1-[(1S)-1-(2,4-difluorophenyl)ethyl]-3-(2-phenylsulfanylethyl)thiourea
    —— 1-[(4-Fluorophenyl)methyl]-1-methyl-3-(2-phenylsulfanylethyl)thiourea —— C17H19FN2S2
    1-[(4-Fluorophenyl)methyl]-1-methyl-3-(2-phenylsulfanylethyl)thiourea
    —— 1-Methyl-1-[(4-methylphenyl)methyl]-3-(2-phenylsulfanylethyl)thiourea —— C18H22N2S2
    1-Methyl-1-[(4-methylphenyl)methyl]-3-(2-phenylsulfanylethyl)thiourea
    —— 3-[2-(4-Chlorophenyl)sulfanylethyl]-1-[(2-fluorophenyl)methyl]-1-methylthiourea —— C17H18ClFN2S2
    3-[2-(4-Chlorophenyl)sulfanylethyl]-1-[(2-fluorophenyl)methyl]-1-methylthiourea
    —— 1-[(4-Bromophenyl)methyl]-1-methyl-3-(2-phenylsulfanylethyl)thiourea —— C17H19BrN2S2
    1-[(4-Bromophenyl)methyl]-1-methyl-3-(2-phenylsulfanylethyl)thiourea
    —— 1-[(2-Chlorophenyl)methyl]-1-methyl-3-(2-phenylsulfanylethyl)thiourea —— C17H19ClN2S2
    1-[(2-Chlorophenyl)methyl]-1-methyl-3-(2-phenylsulfanylethyl)thiourea
    —— 4-Chloro-2-methyl-5-(1-methylimidazol-2-yl)sulfanylpyridazin-3-one —— C9H9ClN4OS
    4-Chloro-2-methyl-5-(1-methylimidazol-2-yl)sulfanylpyridazin-3-one
    —— 1-(6-Amino-1-butyl-2,4-dioxopyrimidin-5-yl)-1-ethyl-3-(2-phenylsulfanylethyl)thiourea —— C19H27N5O2S2
    1-(6-Amino-1-butyl-2,4-dioxopyrimidin-5-yl)-1-ethyl-3-(2-phenylsulfanylethyl)thiourea
    —— 1-[2-(4-Chlorophenyl)sulfanylethyl]-3-[[2-(3,5-dimethylpyrazol-1-yl)acetyl]amino]thiourea —— C16H20ClN5OS2
    1-[2-(4-Chlorophenyl)sulfanylethyl]-3-[[2-(3,5-dimethylpyrazol-1-yl)acetyl]amino]thiourea
    —— N-[2-[2-(4-chlorophenyl)sulfanylethylcarbamothioylamino]ethyl]acetamide —— C13H18ClN3OS2
    N-[2-[2-(4-chlorophenyl)sulfanylethylcarbamothioylamino]ethyl]acetamide
    —— 1-(3-Methylbutyl)-3-(2-phenylsulfanylethylcarbamothioylamino)thiourea —— C15H24N4S3
    1-(3-Methylbutyl)-3-(2-phenylsulfanylethylcarbamothioylamino)thiourea
    —— 1-Cyclopentyl-3-(2-phenylsulfanylethylcarbamothioylamino)thiourea —— C15H22N4S3
    1-Cyclopentyl-3-(2-phenylsulfanylethylcarbamothioylamino)thiourea
    —— 2-(2-cyanophenyl)sulfanyl-N-[(2S)-2-cyanopropyl]benzamide —— C18H15N3OS
    2-(2-cyanophenyl)sulfanyl-N-[(2S)-2-cyanopropyl]benzamide
    —— 1-[2-(4-Chlorophenyl)sulfanylethyl]-3-[[2-(2-methyl-1,3-thiazol-4-yl)acetyl]amino]thiourea —— C15H17ClN4OS3
    1-[2-(4-Chlorophenyl)sulfanylethyl]-3-[[2-(2-methyl-1,3-thiazol-4-yl)acetyl]amino]thiourea
    —— 2-(2-cyanophenyl)sulfanyl-N-[(2R)-2-cyanopropyl]benzamide —— C18H15N3OS
    2-(2-cyanophenyl)sulfanyl-N-[(2R)-2-cyanopropyl]benzamide
    —— N-[2-(4-chlorophenyl)sulfanylethyl]-4-oxopiperidine-1-carbothioamide —— C14H17ClN2OS2
    N-[2-(4-chlorophenyl)sulfanylethyl]-4-oxopiperidine-1-carbothioamide
    —— 3-[2-(4-Chlorophenyl)sulfanylethyl]-1-(2-cyanoethyl)-1-(furan-2-ylmethyl)thiourea —— C17H18ClN3OS2
    3-[2-(4-Chlorophenyl)sulfanylethyl]-1-(2-cyanoethyl)-1-(furan-2-ylmethyl)thiourea
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-cyanopropyl]acetamide —— C14H13ClN4O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-cyanopropyl]acetamide
    —— 1-(2-Phenylsulfanylethyl)-3-(prop-2-enylcarbamothioylamino)thiourea —— C13H18N4S3
    1-(2-Phenylsulfanylethyl)-3-(prop-2-enylcarbamothioylamino)thiourea
    —— 1-Benzyl-3-(2-phenylsulfanylethylcarbamothioylamino)thiourea —— C17H20N4S3
    1-Benzyl-3-(2-phenylsulfanylethylcarbamothioylamino)thiourea
    —— N-[(2S)-2-cyanopropyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C14H20N4OS
    N-[(2S)-2-cyanopropyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyanopropyl]acetamide —— C14H13ClN4O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyanopropyl]acetamide
    —— 1-(2-Phenylsulfanylethyl)-3-(propan-2-ylcarbamothioylamino)thiourea —— C13H20N4S3
    1-(2-Phenylsulfanylethyl)-3-(propan-2-ylcarbamothioylamino)thiourea
    —— N-[(2R)-2-cyanopropyl]-2-phenylsulfanylpyridine-3-carboxamide —— C16H15N3OS
    N-[(2R)-2-cyanopropyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— N-[(2R)-2-cyanopropyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C14H20N4OS
    N-[(2R)-2-cyanopropyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-[(2S)-2-cyanopropyl]-2-phenylsulfanylpyridine-3-carboxamide —— C16H15N3OS
    N-[(2S)-2-cyanopropyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— (2R)-N-[(3R)-3-cyanothiolan-3-yl]-2,3-dihydro-1-benzothiophene-2-carboxamide —— C14H14N2OS2
    (2R)-N-[(3R)-3-cyanothiolan-3-yl]-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— N-[(4S)-1-tert-butyl-4,5,6,7-tetrahydroindazol-4-yl]-2-(4-hydroxyphenyl)sulfanylacetamide —— C19H25N3O2S
    N-[(4S)-1-tert-butyl-4,5,6,7-tetrahydroindazol-4-yl]-2-(4-hydroxyphenyl)sulfanylacetamide
    —— (2S)-N-[(3S)-3-cyanothiolan-3-yl]-2,3-dihydro-1-benzothiophene-2-carboxamide —— C14H14N2OS2
    (2S)-N-[(3S)-3-cyanothiolan-3-yl]-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2R)-N-[(3S)-3-cyanothiolan-3-yl]-2,3-dihydro-1-benzothiophene-2-carboxamide —— C14H14N2OS2
    (2R)-N-[(3S)-3-cyanothiolan-3-yl]-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (E)-N',N'-dimethyl-3-phenylsulfanylprop-2-enehydrazide —— C11H14N2OS
    (E)-N',N'-dimethyl-3-phenylsulfanylprop-2-enehydrazide
    —— (2S)-N-[(3R)-3-cyanothiolan-3-yl]-2,3-dihydro-1-benzothiophene-2-carboxamide —— C14H14N2OS2
    (2S)-N-[(3R)-3-cyanothiolan-3-yl]-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— N-[(4R)-1-tert-butyl-4,5,6,7-tetrahydroindazol-4-yl]-2-(4-hydroxyphenyl)sulfanylacetamide —— C19H25N3O2S
    N-[(4R)-1-tert-butyl-4,5,6,7-tetrahydroindazol-4-yl]-2-(4-hydroxyphenyl)sulfanylacetamide
    —— (2S)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylbutan-2-yl)propanamide —— C14H26N4O2S
    (2S)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylbutan-2-yl)propanamide
    —— 2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-thiophen-2-ylethyl]acetamide —— C16H20N4OS2
    2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-thiophen-2-ylethyl]acetamide