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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-chlorophenyl)sulfanyl-N-(cyclohexylideneamino)acetamide —— C14H17ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-(cyclohexylideneamino)acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-(3-methylcyclopent-2-en-1-ylidene)amino]acetamide —— C14H15ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-(3-methylcyclopent-2-en-1-ylidene)amino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-furan-2-ylmethylideneamino]acetamide —— C13H11ClN2O2S
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-furan-2-ylmethylideneamino]acetamide
    —— N-(2-adamantylideneamino)-2-(4-chlorophenyl)sulfanylacetamide —— C18H21ClN2OS
    N-(2-adamantylideneamino)-2-(4-chlorophenyl)sulfanylacetamide
    —— N-[(Z)-(1-benzyl-3,5-dimethylpyrazol-4-yl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C21H21ClN4OS
    N-[(Z)-(1-benzyl-3,5-dimethylpyrazol-4-yl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]methylideneamino]acetamide —— C20H20ClN3O2S
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]methylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-thiophen-2-ylethylideneamino]acetamide —— C14H13ClN2OS2
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-thiophen-2-ylethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-pyridin-2-ylethylideneamino]acetamide —— C15H14ClN3OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-pyridin-2-ylethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(4-methylcyclohexylidene)amino]acetamide —— C15H19ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(4-methylcyclohexylidene)amino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(1,3,5-trimethylpyrazol-4-yl)methylideneamino]acetamide —— C15H17ClN4OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(1,3,5-trimethylpyrazol-4-yl)methylideneamino]acetamide
    —— N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C15H11Cl2FN2OS
    N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— N-[(Z)-(1-butyl-5-chloro-3-methylpyrazol-4-yl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C17H20Cl2N4OS
    N-[(Z)-(1-butyl-5-chloro-3-methylpyrazol-4-yl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— 2-Cyclopropyl-5-(5-methyl-6-phenylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C18H14N4OS2
    2-Cyclopropyl-5-(5-methyl-6-phenylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole
    —— N-[(2S)-2-(dimethylamino)-3-phenylpropyl]-2-phenylsulfanylpyridine-3-carboxamide —— C23H25N3OS
    N-[(2S)-2-(dimethylamino)-3-phenylpropyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— dimethyl-[(2R)-1-phenyl-3-[(2-phenylsulfanylpyridine-3-carbonyl)amino]propan-2-yl]azanium —— C23H26N3OS+
    dimethyl-[(2R)-1-phenyl-3-[(2-phenylsulfanylpyridine-3-carbonyl)amino]propan-2-yl]azanium
    —— [2-(1-Adamantylmethylamino)-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C21H29N3O3S
    [2-(1-Adamantylmethylamino)-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[(2S)-2-thiophen-2-ylpyrrolidin-1-yl]ethanone —— C18H16FN3O2S2
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[(2S)-2-thiophen-2-ylpyrrolidin-1-yl]ethanone
    —— [2-Oxo-2-(prop-2-enylamino)ethyl] 3-(4-methylphenyl)sulfanylpropanoate —— C15H19NO3S
    [2-Oxo-2-(prop-2-enylamino)ethyl] 3-(4-methylphenyl)sulfanylpropanoate
    —— 1-[2-(4-Fluorophenyl)sulfanyl-5-nitrophenyl]sulfonylpyrrolidine —— C16H15FN2O4S2
    1-[2-(4-Fluorophenyl)sulfanyl-5-nitrophenyl]sulfonylpyrrolidine
    —— N-[2-[(S)-tert-butylsulfinyl]ethyl]-2-(3,4-difluorophenyl)sulfanylacetamide —— C14H19F2NO2S2
    N-[2-[(S)-tert-butylsulfinyl]ethyl]-2-(3,4-difluorophenyl)sulfanylacetamide
    —— N-[2-[(R)-tert-butylsulfinyl]ethyl]-2-(3,4-difluorophenyl)sulfanylacetamide —— C14H19F2NO2S2
    N-[2-[(R)-tert-butylsulfinyl]ethyl]-2-(3,4-difluorophenyl)sulfanylacetamide
    —— N-[2-[(S)-tert-butylsulfinyl]ethyl]-3-(2-chlorophenyl)sulfanylpropanamide —— C15H22ClNO2S2
    N-[2-[(S)-tert-butylsulfinyl]ethyl]-3-(2-chlorophenyl)sulfanylpropanamide
    —— 1-[(3S)-3,5-bis(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)ethanone —— C20H21N5O3S
    1-[(3S)-3,5-bis(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)ethanone
    —— N-[2-[(R)-tert-butylsulfinyl]ethyl]-3-(2-chlorophenyl)sulfanylpropanamide —— C15H22ClNO2S2
    N-[2-[(R)-tert-butylsulfinyl]ethyl]-3-(2-chlorophenyl)sulfanylpropanamide
    —— N-[(3R)-1-benzylpyrrolidin-3-yl]-2-phenylsulfanylpyridine-3-carboxamide —— C23H23N3OS
    N-[(3R)-1-benzylpyrrolidin-3-yl]-2-phenylsulfanylpyridine-3-carboxamide
    —— 5-[(4-chlorophenyl)methylsulfanyl]-N-(2,3-dimethylphenyl)-1,3,4-thiadiazol-2-amine —— C17H16ClN3S2
    5-[(4-chlorophenyl)methylsulfanyl]-N-(2,3-dimethylphenyl)-1,3,4-thiadiazol-2-amine
    —— 2-[[2-(furan-3-yl)-1,3-thiazol-4-yl]methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C19H17N3O2S2
    2-[[2-(furan-3-yl)-1,3-thiazol-4-yl]methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-(2-cyanophenyl)sulfanyl-N-[(2S)-2-(dimethylamino)-2-thiophen-2-ylethyl]benzamide —— C22H21N3OS2
    2-(2-cyanophenyl)sulfanyl-N-[(2S)-2-(dimethylamino)-2-thiophen-2-ylethyl]benzamide
    —— [(1R)-2-[[2-(2-cyanophenyl)sulfanylbenzoyl]amino]-1-thiophen-2-ylethyl]-dimethylazanium —— C22H22N3OS2+
    [(1R)-2-[[2-(2-cyanophenyl)sulfanylbenzoyl]amino]-1-thiophen-2-ylethyl]-dimethylazanium
    —— 2-[[2-(furan-3-yl)-1,3-thiazol-4-yl]methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole —— C19H17N3O2S2
    2-[[2-(furan-3-yl)-1,3-thiazol-4-yl]methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole
    —— N-(5-chloro-2-phenylsulfanylphenyl)-2-(3,5-dimethyl-1,2-oxazol-4-yl)acetamide —— C19H17ClN2O2S
    N-(5-chloro-2-phenylsulfanylphenyl)-2-(3,5-dimethyl-1,2-oxazol-4-yl)acetamide
    —— 2-[[4-Amino-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C18H18N6O2S2
    2-[[4-Amino-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— 4-[(4-benzylsulfonylpiperazin-1-ium-1-yl)methyl]-2-methylsulfanyl-1H-pyrimidin-6-one —— C17H23N4O3S2+
    4-[(4-benzylsulfonylpiperazin-1-ium-1-yl)methyl]-2-methylsulfanyl-1H-pyrimidin-6-one
    —— 1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone —— C18H16N4O3S2
    1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone
    —— (1S)-1-[4-benzyl-5-[(3,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C23H30N4S
    (1S)-1-[4-benzyl-5-[(3,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— 2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]ethanone —— C19H30N4O2S
    2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]ethanone
    —— [(1R)-1-[4-benzyl-5-[(3,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C23H31N4S+
    [(1R)-1-[4-benzyl-5-[(3,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[4-benzyl-5-[(3,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C23H31N4S+
    [(1S)-1-[4-benzyl-5-[(3,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 1-(5-Phenyl-3,4-dihydropyrazol-2-yl)-2-[[5-(propan-2-ylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C16H19N5OS2
    1-(5-Phenyl-3,4-dihydropyrazol-2-yl)-2-[[5-(propan-2-ylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— (2S)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-fluorophenyl)methyl]propanamide —— C14H17FN4OS
    (2S)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-fluorophenyl)methyl]propanamide
    —— [2-oxo-2-(1H-pyrrol-2-yl)ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C20H17NO3S
    [2-oxo-2-(1H-pyrrol-2-yl)ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— (2R)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-fluorophenyl)methyl]propanamide —— C14H17FN4OS
    (2R)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-fluorophenyl)methyl]propanamide
    —— 3-cyclohexyl-5-[[(2R)-oxan-2-yl]methylsulfanyl]-4-prop-2-enyl-1,2,4-triazole —— C17H27N3OS
    3-cyclohexyl-5-[[(2R)-oxan-2-yl]methylsulfanyl]-4-prop-2-enyl-1,2,4-triazole
    —— [1-[[[2-(2,4-Dimethylphenyl)sulfanylpyridine-3-carbonyl]amino]methyl]cyclohexyl]-dimethylazanium —— C23H32N3OS+
    [1-[[[2-(2,4-Dimethylphenyl)sulfanylpyridine-3-carbonyl]amino]methyl]cyclohexyl]-dimethylazanium
    —— N-tert-butyl-2-(1-methyltetrazol-5-yl)sulfanyl-5-nitrobenzamide —— C13H16N6O3S
    N-tert-butyl-2-(1-methyltetrazol-5-yl)sulfanyl-5-nitrobenzamide
    —— 3-cyclohexyl-5-[[(2S)-oxan-2-yl]methylsulfanyl]-4-prop-2-enyl-1,2,4-triazole —— C17H27N3OS
    3-cyclohexyl-5-[[(2S)-oxan-2-yl]methylsulfanyl]-4-prop-2-enyl-1,2,4-triazole
    —— 2-(2-methylsulfanylethylsulfanyl)-4-propyl-1H-pyrimidin-6-one —— C10H16N2OS2
    2-(2-methylsulfanylethylsulfanyl)-4-propyl-1H-pyrimidin-6-one
    —— [2-[[(1R)-1-(4-fluorophenyl)ethyl]amino]-2-oxoethyl] 2-(4-fluorophenyl)sulfanylacetate —— C18H17F2NO3S
    [2-[[(1R)-1-(4-fluorophenyl)ethyl]amino]-2-oxoethyl] 2-(4-fluorophenyl)sulfanylacetate
    —— [(2S)-3-oxobutan-2-yl] 2-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanylbenzoate —— C19H18N2O3S2
    [(2S)-3-oxobutan-2-yl] 2-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanylbenzoate
    —— (3R)-1-(2,2-dimethylpropanoyl)-N-[(2-phenylsulfanylphenyl)methyl]piperidine-3-carboxamide —— C24H30N2O2S
    (3R)-1-(2,2-dimethylpropanoyl)-N-[(2-phenylsulfanylphenyl)methyl]piperidine-3-carboxamide