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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3S)-1-methyl-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]pyrrolidin-2-one —— C8H11N3OS2
    (3S)-1-methyl-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]pyrrolidin-2-one
    —— (3S)-1-methyl-3-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]pyrrolidin-2-one —— C15H18N4O2S
    (3S)-1-methyl-3-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]pyrrolidin-2-one
    —— (3R)-3-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-methylpyrrolidin-2-one —— C19H20N4O2S
    (3R)-3-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-methylpyrrolidin-2-one
    —— (3R)-1-methyl-3-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]pyrrolidin-2-one —— C9H12N2OS2
    (3R)-1-methyl-3-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]pyrrolidin-2-one
    —— (3S)-1-methyl-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]pyrrolidin-2-one —— C11H11N3O2S2
    (3S)-1-methyl-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]pyrrolidin-2-one
    —— (3S)-3-[[4-amino-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-methylpyrrolidin-2-one —— C12H15N5O2S
    (3S)-3-[[4-amino-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-methylpyrrolidin-2-one
    —— (3R)-1-methyl-3-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]pyrrolidin-2-one —— C13H16N4O2S
    (3R)-1-methyl-3-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]pyrrolidin-2-one
    —— (3S)-3-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-methylpyrrolidin-2-one —— C19H20N4O2S
    (3S)-3-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-methylpyrrolidin-2-one
    —— (3R)-1-methyl-3-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]pyrrolidin-2-one —— C16H19N3O2S
    (3R)-1-methyl-3-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]pyrrolidin-2-one
    —— (3R)-1-methyl-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]pyrrolidin-2-one —— C11H11N3O2S2
    (3R)-1-methyl-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]pyrrolidin-2-one
    —— (3R)-1-methyl-3-pyridin-2-ylsulfanylpyrrolidin-2-one —— C10H12N2OS
    (3R)-1-methyl-3-pyridin-2-ylsulfanylpyrrolidin-2-one
    —— (3S)-1-methyl-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]pyrrolidin-2-one —— C14H16N4OS2
    (3S)-1-methyl-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]pyrrolidin-2-one
    —— (3S)-1-methyl-3-(1-methylimidazol-2-yl)sulfanylpyrrolidin-2-one —— C9H13N3OS
    (3S)-1-methyl-3-(1-methylimidazol-2-yl)sulfanylpyrrolidin-2-one
    —— (3R)-1-methyl-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]pyrrolidin-2-one —— C8H11N3OS2
    (3R)-1-methyl-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]pyrrolidin-2-one
    —— (3S)-1-methyl-3-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]pyrrolidin-2-one —— C13H13N3O2S
    (3S)-1-methyl-3-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]pyrrolidin-2-one
    —— (3S)-3-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-methylpyrrolidin-2-one —— C15H18N4OS2
    (3S)-3-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-methylpyrrolidin-2-one
    —— (3R)-1-methyl-3-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]pyrrolidin-2-one —— C11H16N4OS
    (3R)-1-methyl-3-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]pyrrolidin-2-one
    —— (3R)-1-methyl-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]pyrrolidin-2-one —— C14H16N4OS2
    (3R)-1-methyl-3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]pyrrolidin-2-one
    —— (3R)-1-methyl-3-(1-methyltetrazol-5-yl)sulfanylpyrrolidin-2-one —— C7H11N5OS
    (3R)-1-methyl-3-(1-methyltetrazol-5-yl)sulfanylpyrrolidin-2-one
    —— (3R)-1-methyl-3-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]pyrrolidin-2-one —— C13H13N3O2S
    (3R)-1-methyl-3-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]pyrrolidin-2-one
    —— 3-[(1S)-1-ethoxyethyl]-5-[(4-methyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,2,4-oxadiazole —— C14H17N5O2S2
    3-[(1S)-1-ethoxyethyl]-5-[(4-methyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,2,4-oxadiazole
    —— 3-[(1R)-1-ethoxyethyl]-5-[[1-(2,2,2-trifluoroethyl)tetrazol-5-yl]sulfanylmethyl]-1,2,4-oxadiazole —— C10H13F3N6O2S
    3-[(1R)-1-ethoxyethyl]-5-[[1-(2,2,2-trifluoroethyl)tetrazol-5-yl]sulfanylmethyl]-1,2,4-oxadiazole
    —— (3R)-3-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-methylpyrrolidin-2-one —— C15H18N4OS2
    (3R)-3-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-methylpyrrolidin-2-one
    —— 3-[(1R)-1-ethoxyethyl]-5-[(4-methyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,2,4-oxadiazole —— C14H17N5O2S2
    3-[(1R)-1-ethoxyethyl]-5-[(4-methyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,2,4-oxadiazole
    —— 3-[(1R)-1-ethoxyethyl]-5-(1,3,4-thiadiazol-2-ylsulfanylmethyl)-1,2,4-oxadiazole —— C9H12N4O2S2
    3-[(1R)-1-ethoxyethyl]-5-(1,3,4-thiadiazol-2-ylsulfanylmethyl)-1,2,4-oxadiazole
    —— (3S)-3-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-methylpyrrolidin-2-one —— C15H18N4OS2
    (3S)-3-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-methylpyrrolidin-2-one
    —— (3S)-1-methyl-3-pyridin-2-ylsulfanylpyrrolidin-2-one —— C10H12N2OS
    (3S)-1-methyl-3-pyridin-2-ylsulfanylpyrrolidin-2-one
    —— 5-[(1-cyclopropyltetrazol-5-yl)sulfanylmethyl]-3-[(1S)-1-ethoxyethyl]-1,2,4-oxadiazole —— C11H16N6O2S
    5-[(1-cyclopropyltetrazol-5-yl)sulfanylmethyl]-3-[(1S)-1-ethoxyethyl]-1,2,4-oxadiazole
    —— 3-[(1R)-1-ethoxyethyl]-5-[(1-methylimidazol-2-yl)sulfanylmethyl]-1,2,4-oxadiazole —— C11H16N4O2S
    3-[(1R)-1-ethoxyethyl]-5-[(1-methylimidazol-2-yl)sulfanylmethyl]-1,2,4-oxadiazole
    —— (3R)-1-methyl-3-(1-methylimidazol-2-yl)sulfanylpyrrolidin-2-one —— C9H13N3OS
    (3R)-1-methyl-3-(1-methylimidazol-2-yl)sulfanylpyrrolidin-2-one
    —— 2-[(3S)-2-oxooxolan-3-yl]sulfanylpyridine-4-carbonitrile —— C10H8N2O2S
    2-[(3S)-2-oxooxolan-3-yl]sulfanylpyridine-4-carbonitrile
    —— 3-[(1S)-1-ethoxyethyl]-5-(1,3,4-thiadiazol-2-ylsulfanylmethyl)-1,2,4-oxadiazole —— C9H12N4O2S2
    3-[(1S)-1-ethoxyethyl]-5-(1,3,4-thiadiazol-2-ylsulfanylmethyl)-1,2,4-oxadiazole
    —— 3-[(1S)-1-ethoxyethyl]-5-[(1-methylimidazol-2-yl)sulfanylmethyl]-1,2,4-oxadiazole —— C11H16N4O2S
    3-[(1S)-1-ethoxyethyl]-5-[(1-methylimidazol-2-yl)sulfanylmethyl]-1,2,4-oxadiazole
    —— 2-(4-cyanopyridin-2-yl)sulfanyl-N-[(R)-cyclopropyl-(4-methylphenyl)methyl]acetamide —— C19H19N3OS
    2-(4-cyanopyridin-2-yl)sulfanyl-N-[(R)-cyclopropyl-(4-methylphenyl)methyl]acetamide
    —— 2-(4-cyanopyridin-2-yl)sulfanyl-N-[(1R)-1-(furan-2-yl)ethyl]acetamide —— C14H13N3O2S
    2-(4-cyanopyridin-2-yl)sulfanyl-N-[(1R)-1-(furan-2-yl)ethyl]acetamide
    —— 3-[(1S)-1-ethoxyethyl]-5-[[1-(2,2,2-trifluoroethyl)tetrazol-5-yl]sulfanylmethyl]-1,2,4-oxadiazole —— C10H13F3N6O2S
    3-[(1S)-1-ethoxyethyl]-5-[[1-(2,2,2-trifluoroethyl)tetrazol-5-yl]sulfanylmethyl]-1,2,4-oxadiazole
    —— 5-[(1-cyclopropyltetrazol-5-yl)sulfanylmethyl]-3-[(1R)-1-ethoxyethyl]-1,2,4-oxadiazole —— C11H16N6O2S
    5-[(1-cyclopropyltetrazol-5-yl)sulfanylmethyl]-3-[(1R)-1-ethoxyethyl]-1,2,4-oxadiazole
    —— 5-[(1-cyclopentyltetrazol-5-yl)sulfanylmethyl]-3-[(1R)-1-ethoxyethyl]-1,2,4-oxadiazole —— C13H20N6O2S
    5-[(1-cyclopentyltetrazol-5-yl)sulfanylmethyl]-3-[(1R)-1-ethoxyethyl]-1,2,4-oxadiazole
    —— 2-(4-cyanopyridin-2-yl)sulfanyl-N-(2-phenylethyl)acetamide —— C16H15N3OS
    2-(4-cyanopyridin-2-yl)sulfanyl-N-(2-phenylethyl)acetamide
    —— 5-[(1-cyclopentyltetrazol-5-yl)sulfanylmethyl]-3-[(1S)-1-ethoxyethyl]-1,2,4-oxadiazole —— C13H20N6O2S
    5-[(1-cyclopentyltetrazol-5-yl)sulfanylmethyl]-3-[(1S)-1-ethoxyethyl]-1,2,4-oxadiazole
    —— 2-[(3R)-2-oxooxolan-3-yl]sulfanylpyridine-4-carbonitrile —— C10H8N2O2S
    2-[(3R)-2-oxooxolan-3-yl]sulfanylpyridine-4-carbonitrile
    —— (2R)-N-cyclohexyl-N,3-dimethyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]butanamide —— C15H25N3OS2
    (2R)-N-cyclohexyl-N,3-dimethyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]butanamide
    —— 2-(4-cyanopyridin-2-yl)sulfanyl-N-[(S)-cyclopropyl-(4-methylphenyl)methyl]acetamide —— C19H19N3OS
    2-(4-cyanopyridin-2-yl)sulfanyl-N-[(S)-cyclopropyl-(4-methylphenyl)methyl]acetamide
    —— 2-(4-cyanopyridin-2-yl)sulfanyl-N-[(1S)-1-(furan-2-yl)ethyl]acetamide —— C14H13N3O2S
    2-(4-cyanopyridin-2-yl)sulfanyl-N-[(1S)-1-(furan-2-yl)ethyl]acetamide
    —— (2S)-N-cyclohexyl-N,3-dimethyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]butanamide —— C15H25N3OS2
    (2S)-N-cyclohexyl-N,3-dimethyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]butanamide
    —— 3-Cyclopropyl-5-[(2-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-amine —— C13H16N4S
    3-Cyclopropyl-5-[(2-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— (3S)-N'-[3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoyl]-1,1-dioxothiolane-3-carbohydrazide —— C15H22N4O4S2
    (3S)-N'-[3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoyl]-1,1-dioxothiolane-3-carbohydrazide
    —— 3-Cyclopropyl-5-[(2,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-4-amine —— C14H18N4S
    3-Cyclopropyl-5-[(2,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— 3-Cyclopropyl-5-[[2-(4-methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-1,2,4-triazol-4-amine —— C16H17N5S2
    3-Cyclopropyl-5-[[2-(4-methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-1,2,4-triazol-4-amine
    —— 4-[(4-amino-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine —— C16H18N6S2
    4-[(4-amino-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine