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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3R)-N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-1,1-dioxothiolane-3-carboxamide —— C23H28FNO3S2
    (3R)-N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-1,1-dioxothiolane-3-carboxamide
    —— (2S)-2-(3-bromopyridin-2-yl)sulfanyl-1-(4-ethylpiperazin-1-yl)propan-1-one —— C14H20BrN3OS
    (2S)-2-(3-bromopyridin-2-yl)sulfanyl-1-(4-ethylpiperazin-1-yl)propan-1-one
    —— N-[(1R)-1-(2-chloro-4-fluorophenyl)ethyl]-2-(4-methylphenyl)sulfanylacetamide —— C17H17ClFNOS
    N-[(1R)-1-(2-chloro-4-fluorophenyl)ethyl]-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-(2-methylphenyl)sulfanyl-N-propylacetamide —— C16H23NO3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-(2-methylphenyl)sulfanyl-N-propylacetamide
    —— 2-(3-bromopyridin-2-yl)sulfanyl-N-[(2S)-6-methylheptan-2-yl]acetamide —— C15H23BrN2OS
    2-(3-bromopyridin-2-yl)sulfanyl-N-[(2S)-6-methylheptan-2-yl]acetamide
    —— N-[(1R)-1-(2-chloro-4-fluorophenyl)ethyl]-2-phenylsulfanylacetamide —— C16H15ClFNOS
    N-[(1R)-1-(2-chloro-4-fluorophenyl)ethyl]-2-phenylsulfanylacetamide
    —— 2-(3-bromopyridin-2-yl)sulfanyl-N-[(2R)-6-methylheptan-2-yl]acetamide —— C15H23BrN2OS
    2-(3-bromopyridin-2-yl)sulfanyl-N-[(2R)-6-methylheptan-2-yl]acetamide
    —— (2R)-2-(3-bromopyridin-2-yl)sulfanyl-1-(4-ethylpiperazin-1-yl)propan-1-one —— C14H20BrN3OS
    (2R)-2-(3-bromopyridin-2-yl)sulfanyl-1-(4-ethylpiperazin-1-yl)propan-1-one
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-3-phenylsulfanyl-N-propylpropanamide —— C16H23NO3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-3-phenylsulfanyl-N-propylpropanamide
    —— 3-(2-fluorophenyl)sulfanyl-N-[1-[[(3S)-oxolan-3-yl]methyl]piperidin-4-yl]propanamide —— C19H27FN2O2S
    3-(2-fluorophenyl)sulfanyl-N-[1-[[(3S)-oxolan-3-yl]methyl]piperidin-4-yl]propanamide
    —— N-[(1S)-1-(2-chloro-4-fluorophenyl)ethyl]-2-phenylsulfanylacetamide —— C16H15ClFNOS
    N-[(1S)-1-(2-chloro-4-fluorophenyl)ethyl]-2-phenylsulfanylacetamide
    —— 6,7-difluoro-4-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylquinazoline —— C14H12F2N6OS
    6,7-difluoro-4-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylquinazoline
    —— (3S)-N-[(1R)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-1,1-dioxothiolane-3-carboxamide —— C23H28FNO3S2
    (3S)-N-[(1R)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-1,1-dioxothiolane-3-carboxamide
    —— (3S)-N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-1,1-dioxothiolane-3-carboxamide —— C23H28FNO3S2
    (3S)-N-[(1S)-1-[3-fluoro-4-(4-propan-2-ylphenyl)sulfanylphenyl]ethyl]-N-methyl-1,1-dioxothiolane-3-carboxamide
    —— N-[(4-bromophenyl)methyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-methylpropanamide —— C18H22BrN3OS
    N-[(4-bromophenyl)methyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-methylpropanamide
    —— 6,7-difluoro-4-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylquinazoline —— C14H12F2N6OS
    6,7-difluoro-4-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylquinazoline
    —— 2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C13H16N4O2S
    2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— 2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C13H16N4O2S
    2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— (2R)-N-cyclohexyl-2-[[5-(dimethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,3-dimethylbutanamide —— C16H28N4OS2
    (2R)-N-cyclohexyl-2-[[5-(dimethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,3-dimethylbutanamide
    —— (2S)-N-cyclohexyl-2-[[5-(dimethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,3-dimethylbutanamide —— C16H28N4OS2
    (2S)-N-cyclohexyl-2-[[5-(dimethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,3-dimethylbutanamide
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N'-[2-(4-methylphenyl)sulfanylacetyl]propanehydrazide —— C19H24N4O2S2
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N'-[2-(4-methylphenyl)sulfanylacetyl]propanehydrazide
    —— N'-[2-(4-methylphenyl)sulfanylacetyl]-2-[2-(2-oxopyrrolidin-1-yl)-1,3-thiazol-4-yl]acetohydrazide —— C18H20N4O3S2
    N'-[2-(4-methylphenyl)sulfanylacetyl]-2-[2-(2-oxopyrrolidin-1-yl)-1,3-thiazol-4-yl]acetohydrazide
    —— 2-[(2-chlorophenyl)methylsulfanyl]-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide —— C17H16ClFN2O2S2
    2-[(2-chlorophenyl)methylsulfanyl]-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide
    —— N'-[2-(2-fluorophenyl)sulfanylacetyl]-1-methylpyrazole-4-carbohydrazide —— C13H13FN4O2S
    N'-[2-(2-fluorophenyl)sulfanylacetyl]-1-methylpyrazole-4-carbohydrazide
    —— 1-benzyl-N'-[2-(2-fluorophenyl)sulfanylacetyl]pyrazole-4-carbohydrazide —— C19H17FN4O2S
    1-benzyl-N'-[2-(2-fluorophenyl)sulfanylacetyl]pyrazole-4-carbohydrazide
    —— N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-pyridin-3-ylpropanehydrazide —— C16H16FN3O2S
    N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-pyridin-3-ylpropanehydrazide
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N'-[2-(2-fluorophenyl)sulfanylacetyl]propanehydrazide —— C18H21FN4O2S2
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N'-[2-(2-fluorophenyl)sulfanylacetyl]propanehydrazide
    —— Ethyl 2,5-dimethyl-1-[2-[2-[2-(4-methylphenyl)sulfanylacetyl]hydrazinyl]-2-oxoethyl]pyrrole-3-carboxylate —— C20H25N3O4S
    Ethyl 2,5-dimethyl-1-[2-[2-[2-(4-methylphenyl)sulfanylacetyl]hydrazinyl]-2-oxoethyl]pyrrole-3-carboxylate
    —— 2-[(1S)-cyclopent-2-en-1-yl]-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide —— C15H17FN2O2S
    2-[(1S)-cyclopent-2-en-1-yl]-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide
    —— 2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methyl-N-[(1S)-1-phenylethyl]acetamide —— C21H24N4OS2
    2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methyl-N-[(1S)-1-phenylethyl]acetamide
    —— N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-methyl-5-propan-2-yl-1,2-oxazole-4-carbohydrazide —— C16H18FN3O3S
    N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-methyl-5-propan-2-yl-1,2-oxazole-4-carbohydrazide
    —— 2-[(1R)-cyclopent-2-en-1-yl]-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide —— C15H17FN2O2S
    2-[(1R)-cyclopent-2-en-1-yl]-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide
    —— N-methyl-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C20H22N4OS2
    N-methyl-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— 3-benzylsulfanyl-4-[(Z)-[5-(2-fluorophenyl)furan-2-yl]methylideneamino]-1H-1,2,4-triazole-5-thione —— C20H15FN4OS2
    3-benzylsulfanyl-4-[(Z)-[5-(2-fluorophenyl)furan-2-yl]methylideneamino]-1H-1,2,4-triazole-5-thione
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-methyl-N-(1,3-thiazol-2-yl)propanamide —— C13H13ClN2OS2
    (2S)-2-(4-chlorophenyl)sulfanyl-N-methyl-N-(1,3-thiazol-2-yl)propanamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-methyl-N-(1,3-thiazol-2-yl)propanamide —— C13H13ClN2OS2
    (2R)-2-(4-chlorophenyl)sulfanyl-N-methyl-N-(1,3-thiazol-2-yl)propanamide
    —— N-[(Z)-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C19H19FN4O2S
    N-[(Z)-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-[(Z)-[2,5-dimethyl-1-(2-propan-2-ylpyrazol-3-yl)pyrrol-3-yl]methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C21H24FN5OS
    N-[(Z)-[2,5-dimethyl-1-(2-propan-2-ylpyrazol-3-yl)pyrrol-3-yl]methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-[(Z)-[2,5-dimethyl-1-(2-propan-2-ylpyrazol-3-yl)pyrrol-3-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide —— C22H27N5OS
    N-[(Z)-[2,5-dimethyl-1-(2-propan-2-ylpyrazol-3-yl)pyrrol-3-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(Z)-[1-[(3S)-1,1-dioxothiolan-3-yl]-3,5-dimethylpyrazol-4-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide —— C19H24N4O3S2
    N-[(Z)-[1-[(3S)-1,1-dioxothiolan-3-yl]-3,5-dimethylpyrazol-4-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(Z)-[1-[(3R)-1,1-dioxothiolan-3-yl]-3,5-dimethylpyrazol-4-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide —— C19H24N4O3S2
    N-[(Z)-[1-[(3R)-1,1-dioxothiolan-3-yl]-3,5-dimethylpyrazol-4-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(Z)-[5-(2-fluorophenyl)furan-2-yl]methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C19H14F2N2O2S
    N-[(Z)-[5-(2-fluorophenyl)furan-2-yl]methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-[(1R)-1-(2-bromophenyl)ethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C18H22BrN3OS
    N-[(1R)-1-(2-bromophenyl)ethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-[(1S)-1-(2-bromophenyl)ethyl]-2-(2,5-difluorophenyl)sulfanylacetamide —— C16H14BrF2NOS
    N-[(1S)-1-(2-bromophenyl)ethyl]-2-(2,5-difluorophenyl)sulfanylacetamide
    —— (2R)-1-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-2-(4-methylphenyl)sulfanylpropan-1-one —— C19H25N3O4S2
    (2R)-1-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-2-(4-methylphenyl)sulfanylpropan-1-one
    —— 1-[4-[(3,5-Dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-2-(3,4-dimethylphenyl)sulfanylethanone —— C19H25N3O4S2
    1-[4-[(3,5-Dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-2-(3,4-dimethylphenyl)sulfanylethanone
    —— (2R)-1-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-2-phenylsulfanylpropan-1-one —— C18H23N3O4S2
    (2R)-1-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-2-phenylsulfanylpropan-1-one
    —— (E)-1-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-3-phenylsulfanylprop-2-en-1-one —— C18H21N3O4S2
    (E)-1-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-3-phenylsulfanylprop-2-en-1-one
    —— 1-[4-[(3,5-Dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-3-phenylsulfanylpropan-1-one —— C18H23N3O4S2
    1-[4-[(3,5-Dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-3-phenylsulfanylpropan-1-one
    —— 1-[3-(4,6-Dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoylamino]-3-(3-methylbutyl)thiourea —— C16H27N5OS2
    1-[3-(4,6-Dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoylamino]-3-(3-methylbutyl)thiourea