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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(2-cyanophenyl)sulfanyl-N-[(1R)-1-(2-ethyl-1,3-thiazol-4-yl)ethyl]benzamide —— C21H19N3OS2
    2-(2-cyanophenyl)sulfanyl-N-[(1R)-1-(2-ethyl-1,3-thiazol-4-yl)ethyl]benzamide
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— 3-(2-bromophenyl)sulfanyl-N-[(1S)-1-(2-ethyl-1,3-thiazol-4-yl)ethyl]propanamide —— C16H19BrN2OS2
    3-(2-bromophenyl)sulfanyl-N-[(1S)-1-(2-ethyl-1,3-thiazol-4-yl)ethyl]propanamide
    —— 2-(2-cyanophenyl)sulfanyl-N-[(1S)-1-(2-ethyl-1,3-thiazol-4-yl)ethyl]benzamide —— C21H19N3OS2
    2-(2-cyanophenyl)sulfanyl-N-[(1S)-1-(2-ethyl-1,3-thiazol-4-yl)ethyl]benzamide
    —— [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone —— C17H19N3O2S
    [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(5-ethyl-1,2,4-oxadiazol-3-yl)pyrrolidin-1-yl]methanone
    —— 3-(2-bromophenyl)sulfanyl-N-[(1R)-1-(2-ethyl-1,3-thiazol-4-yl)ethyl]propanamide —— C16H19BrN2OS2
    3-(2-bromophenyl)sulfanyl-N-[(1R)-1-(2-ethyl-1,3-thiazol-4-yl)ethyl]propanamide
    —— (2R)-2-(4-methylpyrimidin-2-yl)sulfanyl-N-propylpropanamide —— C11H17N3OS
    (2R)-2-(4-methylpyrimidin-2-yl)sulfanyl-N-propylpropanamide
    —— 1-[(2R)-1-methoxypropan-2-yl]-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea —— C13H19N3OS2
    1-[(2R)-1-methoxypropan-2-yl]-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea
    —— (2S)-2-(4-methylpyrimidin-2-yl)sulfanyl-N-propylpropanamide —— C11H17N3OS
    (2S)-2-(4-methylpyrimidin-2-yl)sulfanyl-N-propylpropanamide
    —— (3S)-4-[2-(4-bromo-2,5-dimethylphenyl)sulfanylacetyl]morpholine-3-carbonitrile —— C15H17BrN2O2S
    (3S)-4-[2-(4-bromo-2,5-dimethylphenyl)sulfanylacetyl]morpholine-3-carbonitrile
    —— (3R)-4-[2-(4-bromo-2,5-dimethylphenyl)sulfanylacetyl]morpholine-3-carbonitrile —— C15H17BrN2O2S
    (3R)-4-[2-(4-bromo-2,5-dimethylphenyl)sulfanylacetyl]morpholine-3-carbonitrile
    —— [6-(2-chlorophenyl)sulfanylpyridazin-3-yl]-[(3R)-3-methylmorpholin-4-yl]methanone —— C16H16ClN3O2S
    [6-(2-chlorophenyl)sulfanylpyridazin-3-yl]-[(3R)-3-methylmorpholin-4-yl]methanone
    —— 4-[5-[5-(4-methylpyrazol-1-yl)pentylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine —— C20H32N6O2S
    4-[5-[5-(4-methylpyrazol-1-yl)pentylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine
    —— (2R)-N-benzyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methylpropanamide —— C15H19N3OS3
    (2R)-N-benzyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methylpropanamide
    —— 2-ethyl-5-[(1R)-1-[1-(2-thiophen-2-ylethyl)tetrazol-5-yl]sulfanylethyl]-1,3,4-oxadiazole —— C13H16N6OS2
    2-ethyl-5-[(1R)-1-[1-(2-thiophen-2-ylethyl)tetrazol-5-yl]sulfanylethyl]-1,3,4-oxadiazole
    —— (5S)-5-[[5-[(2-chloro-6-fluorophenyl)methyl]-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-one —— C13H11ClFN3O3S
    (5S)-5-[[5-[(2-chloro-6-fluorophenyl)methyl]-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-one
    —— (5R)-5-[[5-[(2-chloro-6-fluorophenyl)methyl]-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-one —— C13H11ClFN3O3S
    (5R)-5-[[5-[(2-chloro-6-fluorophenyl)methyl]-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-one
    —— 2-ethyl-5-[(1S)-1-[1-(2-thiophen-2-ylethyl)tetrazol-5-yl]sulfanylethyl]-1,3,4-oxadiazole —— C13H16N6OS2
    2-ethyl-5-[(1S)-1-[1-(2-thiophen-2-ylethyl)tetrazol-5-yl]sulfanylethyl]-1,3,4-oxadiazole
    —— (2S)-N-benzyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methylpropanamide —— C15H19N3OS3
    (2S)-N-benzyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methylpropanamide
    —— 4-[5-[5-(4-methylpyrazol-1-yl)pentylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine —— C20H32N6O2S
    4-[5-[5-(4-methylpyrazol-1-yl)pentylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine
    —— (2S)-N-cyclohexyl-N-ethyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C15H25N3OS3
    (2S)-N-cyclohexyl-N-ethyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— [6-(2-chlorophenyl)sulfanylpyridazin-3-yl]-[(3S)-3-methylmorpholin-4-yl]methanone —— C16H16ClN3O2S
    [6-(2-chlorophenyl)sulfanylpyridazin-3-yl]-[(3S)-3-methylmorpholin-4-yl]methanone
    —— (2R)-N-cyclohexyl-N-ethyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C15H25N3OS3
    (2R)-N-cyclohexyl-N-ethyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-2-(3,4-dimethylphenoxy)-N-(2-phenylsulfanylphenyl)propanamide —— C23H23NO2S
    (2R)-2-(3,4-dimethylphenoxy)-N-(2-phenylsulfanylphenyl)propanamide
    —— 3-{4-[(4-nitrophenyl)sulfanyl]benzyl}-1,2,3-benzotriazin-4(3H)-one —— C20H14N4O3S
    3-{4-[(4-nitrophenyl)sulfanyl]benzyl}-1,2,3-benzotriazin-4(3H)-one
    —— (2S)-2-(3,4-dimethylphenoxy)-N-(2-phenylsulfanylphenyl)propanamide —— C23H23NO2S
    (2S)-2-(3,4-dimethylphenoxy)-N-(2-phenylsulfanylphenyl)propanamide
    —— 4-[[12-(4-Methoxyphenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholin-4-ium —— C21H24N3O2S2+
    4-[[12-(4-Methoxyphenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholin-4-ium
    —— 1-[4-(4-Methoxyphenyl)sulfanyl-3-nitrophenyl]sulfonylpiperidine —— C18H20N2O5S2
    1-[4-(4-Methoxyphenyl)sulfanyl-3-nitrophenyl]sulfonylpiperidine
    —— N,N-diethyl-4-(4-methoxyphenyl)sulfanyl-3-nitrobenzenesulfonamide —— C17H20N2O5S2
    N,N-diethyl-4-(4-methoxyphenyl)sulfanyl-3-nitrobenzenesulfonamide
    —— 5-((4-Bromo-2-nitrophenyl)thio)-1-methyl-1h-tetrazole —— C8H6BrN5O2S
    5-((4-Bromo-2-nitrophenyl)thio)-1-methyl-1h-tetrazole
    —— 4-[[12-(4-Methoxyphenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholine —— C21H23N3O2S2
    4-[[12-(4-Methoxyphenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholine
    —— N-[4-(4-Bromo-2-nitro-phenylsulfanyl)-phenyl]-acetamide —— C14H11BrN2O3S
    N-[4-(4-Bromo-2-nitro-phenylsulfanyl)-phenyl]-acetamide
    —— Ethyl 4-[2-(2-nitrophenyl)sulfanylbenzoyl]piperazine-1-carboxylate —— C20H21N3O5S
    Ethyl 4-[2-(2-nitrophenyl)sulfanylbenzoyl]piperazine-1-carboxylate
    —— 4-[[4-(4-Methoxyphenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholine —— C20H23N3O2S2
    4-[[4-(4-Methoxyphenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholine
    —— (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]propanamide —— C17H22N4O2S2
    (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]propanamide
    —— (2R)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]propanamide —— C17H22N4O2S2
    (2R)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]propanamide
    —— 2-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C12H18N4O2S2
    2-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 2-[(3-Methylphenyl)methylsulfanyl]-5-piperidin-4-yl-1,3,4-oxadiazole —— C15H19N3OS
    2-[(3-Methylphenyl)methylsulfanyl]-5-piperidin-4-yl-1,3,4-oxadiazole
    —— 2-[(3-Fluorophenyl)methylsulfanyl]-5-piperidin-1-ium-4-yl-1,3,4-oxadiazole —— C14H17FN3OS+
    2-[(3-Fluorophenyl)methylsulfanyl]-5-piperidin-1-ium-4-yl-1,3,4-oxadiazole
    —— N-[5-[2-[5-(2-amino-2-oxoethyl)thiophen-2-yl]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]-N-cyclopropylpropanamide —— C16H18N4O3S3
    N-[5-[2-[5-(2-amino-2-oxoethyl)thiophen-2-yl]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]-N-cyclopropylpropanamide
    —— (2R)-N-benzyl-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-ethylpropanamide —— C21H24N4OS2
    (2R)-N-benzyl-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-ethylpropanamide
    —— (2S)-2-(2-phenylsulfanylethyl)piperidin-1-ium —— C13H20NS+
    (2S)-2-(2-phenylsulfanylethyl)piperidin-1-ium
    —— (2S)-2-[2-(4-chlorophenyl)sulfanylethyl]piperidin-1-ium —— C13H19ClNS+
    (2S)-2-[2-(4-chlorophenyl)sulfanylethyl]piperidin-1-ium
    —— 3-(5-Ethylsulfanyl-1,3,4-oxadiazol-2-yl)propylazanium —— C7H14N3OS+
    3-(5-Ethylsulfanyl-1,3,4-oxadiazol-2-yl)propylazanium
    —— 2-[(2-Methylphenyl)methylsulfanyl]-5-piperidin-1-ium-4-yl-1,3,4-oxadiazole —— C15H20N3OS+
    2-[(2-Methylphenyl)methylsulfanyl]-5-piperidin-1-ium-4-yl-1,3,4-oxadiazole
    —— 2-[(4-Fluorophenyl)methylsulfanyl]-5-piperidin-1-ium-4-yl-1,3,4-oxadiazole —— C14H17FN3OS+
    2-[(4-Fluorophenyl)methylsulfanyl]-5-piperidin-1-ium-4-yl-1,3,4-oxadiazole
    —— 3-[5-[(2-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium —— C12H15ClN3OS+
    3-[5-[(2-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium
    —— 3-[5-[(3-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine —— C12H14FN3OS
    3-[5-[(3-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine