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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N,N-dimethyl-3-((5-nitropyridin-2-yl)thio)-3-phenylpropan-1-amine 1584114-13-5 C16H19N3O2S
    N,N-dimethyl-3-((5-nitropyridin-2-yl)thio)-3-phenylpropan-1-amine
    —— N-(2,2-dimethoxy-ethyl)-2-(acetyl-methylamino)-3,3-dimethyl-thiobutyric acid amide 866784-81-8 C13H26N2O3S
    N-(2,2-dimethoxy-ethyl)-2-(acetyl-methylamino)-3,3-dimethyl-thiobutyric acid amide
    —— (E)-4-(di-sec-butylboryl)-5-(butylthio)-3-methyl-4-nonene 403519-55-1 C22H45BS
    (E)-4-(di-sec-butylboryl)-5-(butylthio)-3-methyl-4-nonene
    —— 2-Butylsulfanyl-1-tert-butylethyne 127894-33-1 C10H18S
    2-Butylsulfanyl-1-tert-butylethyne
    —— 2,3-Bis(phenylthio)-N-methylmaleinimid 74353-20-1 C17H13NO2S2
    2,3-Bis(phenylthio)-N-methylmaleinimid
    —— D-4-HYDROXYMETHYL-5-[4-(METHYLMERCAPTO)PHENYL]-2-PHENYL-2-OXAZOLINE 126429-07-0 C17H17NO2S
    D-4-HYDROXYMETHYL-5-[4-(METHYLMERCAPTO)PHENYL]-2-PHENYL-2-OXAZOLINE
    —— 1-Thiomethyl-3-methyl-allen 34262-50-5 C5H8S
    1-Thiomethyl-3-methyl-allen
    —— 2-pyridin-2-ylsulfanyl-acetamide 10002-31-0 C7H8N2OS
    2-pyridin-2-ylsulfanyl-acetamide
    —— tert-butyl 2-(trimethylsilyl)ethyl sulfoxide 156090-86-7 C9H22OSSi
    tert-butyl 2-(trimethylsilyl)ethyl sulfoxide
    —— 3,5-dichloro-2,6-difluoro-4-phenylthiopyridine 51066-41-2 C11H5Cl2F2NS
    3,5-dichloro-2,6-difluoro-4-phenylthiopyridine
    —— 5-((3,5-dichloropyridin-4-yl)thio)-N-((2,3-dihydrobenzofuran-5-yl)methyl)-4-nitrothiophene-2-carboxamide 1247820-70-7 C19H13Cl2N3O4S2
    5-((3,5-dichloropyridin-4-yl)thio)-N-((2,3-dihydrobenzofuran-5-yl)methyl)-4-nitrothiophene-2-carboxamide
    —— 1-Methylmercapto-1.2.4-pentatrien 19429-99-3 C6H8S
    1-Methylmercapto-1.2.4-pentatrien
    —— N-methoxy-N-methyl-2-(phenylthio)pent-4-enamide 754201-16-6 C13H17NO2S
    N-methoxy-N-methyl-2-(phenylthio)pent-4-enamide
    —— 2,3-Dimethyl-2,4-pentadien-diethylthioamid 52412-20-1 C11H19NS
    2,3-Dimethyl-2,4-pentadien-diethylthioamid
    —— 5-[(3,5-dichloro-4-pyridyl)sulfanyl]-N-isopropyl-4-nitro-thiophene-2-carboxamide 1247820-27-4 C13H11Cl2N3O3S2
    5-[(3,5-dichloro-4-pyridyl)sulfanyl]-N-isopropyl-4-nitro-thiophene-2-carboxamide
    —— (E)-3-dimethylamino-2-methylsulfonylpropenenitrile 858135-91-8 C6H10N2O2S
    (E)-3-dimethylamino-2-methylsulfonylpropenenitrile
    —— 2-(4-dimethylaminobutoxy)-diphenyl sulfide hydrochloride 62232-58-0 C18H23NOS*ClH
    2-(4-dimethylaminobutoxy)-diphenyl sulfide hydrochloride
    —— 1-pentyl-3-[(Z)-12-(1H-1,2,4-triazol-5-ylsulfanyl)dodec-5-enyl]urea 1402547-56-1 C20H37N5OS
    1-pentyl-3-[(Z)-12-(1H-1,2,4-triazol-5-ylsulfanyl)dodec-5-enyl]urea
    —— Pyrrolidine, 1-[[[5-(2-thienyl)-1,3,4-oxadiazol-2-yl]thio]acetyl]- 459846-08-3 C12H13N3O2S2
    Pyrrolidine, 1-[[[5-(2-thienyl)-1,3,4-oxadiazol-2-yl]thio]acetyl]-
    —— 4-Chloro-2-isothiocyanato-2-methyl-pentane 691359-03-2 C7H12ClNS
    4-Chloro-2-isothiocyanato-2-methyl-pentane
    —— Bis-<7-nitro-benz<2,1,3-thiadizolyl-(4)>-sulfid 7668-44-2 C12H4N6O4S3
    Bis-<7-nitro-benz<2,1,3-thiadizolyl-(4)>-sulfid
    —— 4-isothiocyanato-4-methyl-2-pentanol 691359-06-5 C7H13NOS
    4-isothiocyanato-4-methyl-2-pentanol
    —— 6-(ethylthio)-2,3-difluoropyridine 1257071-62-7 C7H7F2NS
    6-(ethylthio)-2,3-difluoropyridine
    —— 2-ethyl-3-hydroxy-6-(phenylthio)-4(1H)-pyridinone 221695-79-0 C13H13NO2S
    2-ethyl-3-hydroxy-6-(phenylthio)-4(1H)-pyridinone
    —— 6,6-dimethyl-2,4-bis(phenylthio)hepta-2,4-dienal 210416-91-4 C21H22OS2
    6,6-dimethyl-2,4-bis(phenylthio)hepta-2,4-dienal
    —— (1Z,4Z,6Z)-2,6-dicyano-1-ethoxy-8,8-dimethyl-4-(phenylthio)nona-1,4,6-trien-3-ol 403719-73-3 C21H24N2O2S
    (1Z,4Z,6Z)-2,6-dicyano-1-ethoxy-8,8-dimethyl-4-(phenylthio)nona-1,4,6-trien-3-ol
    —— (2Z,4Z)-4-cyano-6,6-dimethyl-2-(phenylthio)hepta-2,4-dienal 403719-65-3 C16H17NOS
    (2Z,4Z)-4-cyano-6,6-dimethyl-2-(phenylthio)hepta-2,4-dienal
    —— (1Z,4E)-2-cyano-1-ethoxy-6,6-dimethyl-4-(phenylthio)hepta-1,4-dien-3-ol 403719-53-9 C18H23NO2S
    (1Z,4E)-2-cyano-1-ethoxy-6,6-dimethyl-4-(phenylthio)hepta-1,4-dien-3-ol
    —— Ethyl 6-chloro-4-(2-methylsulfanylanilino)pyridazine-3-carboxylate 1609393-86-3 C14H14ClN3O2S
    Ethyl 6-chloro-4-(2-methylsulfanylanilino)pyridazine-3-carboxylate
    —— 4,4-Dichloro-1-isothiocyanato-1-tert-butyl-2-aza-1,3-butadiene 92277-53-7 C8H10Cl2N2S
    4,4-Dichloro-1-isothiocyanato-1-tert-butyl-2-aza-1,3-butadiene
    —— S-Cyclohexyl-S-methyl dithiocarbonate 41320-28-9 C8H14OS2
    S-Cyclohexyl-S-methyl dithiocarbonate
    —— 5-methoxy-2,2-dimethyl-6-phenyl-6-(phenylthio)-3-hexanone 121862-20-2 C21H26O2S
    5-methoxy-2,2-dimethyl-6-phenyl-6-(phenylthio)-3-hexanone
    —— 3-oxo-2-(pyridin-2-ylsulfanyl-acetyl)-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyridinylium betaine 66102-82-7 C14H10N2O2S2
    3-oxo-2-(pyridin-2-ylsulfanyl-acetyl)-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyridinylium betaine
    —— 3-<2-(4-Methylphenyl)ethylidenyl>-2-pentyl-2,3-dihydrobenzo<b>thiophen-2-ol 146916-45-2 C22H26OS
    3-<2-(4-Methylphenyl)ethylidenyl>-2-pentyl-2,3-dihydrobenzo<b>thiophen-2-ol
    —— bis-γ,γ-dimethylallenyl thiosulfonate 166986-76-1 C10H14O2S2
    bis-γ,γ-dimethylallenyl thiosulfonate
    —— 5-methylsulfanyl-2,3-diphenyl-[1,3,4]oxadiazolium; iodide 52816-39-4 C15H13N2OS*I
    5-methylsulfanyl-2,3-diphenyl-[1,3,4]oxadiazolium; iodide
    —— methyl N'-cyano-N-<1,2-dihydro-1,2-dimethyl-5-methylthio-3H-1,2,4-triazol-3-ylidene>carbamimidothioate 282093-33-8 C8H12N6S2
    methyl N'-cyano-N-<1,2-dihydro-1,2-dimethyl-5-methylthio-3H-1,2,4-triazol-3-ylidene>carbamimidothioate
    —— 2,3,6-Trichloro-5-methylthiopyridine 129836-61-9 C6H4Cl3NS
    2,3,6-Trichloro-5-methylthiopyridine
    —— 7,12-Dithia-pleiadene 7-oxide 124480-08-6 C16H10OS2
    7,12-Dithia-pleiadene 7-oxide
    —— 7,12-Dithia-pleiadene 124508-05-0 C16H10S2
    7,12-Dithia-pleiadene
    —— 1,4-Bis-<(1,2,3,4-thiatriazol-5-yl)-mercaptomethyl>-cyclohexan 3289-20-1 C10H14N6S4
    1,4-Bis-<(1,2,3,4-thiatriazol-5-yl)-mercaptomethyl>-cyclohexan
    —— 4-chloro-3-(pyridin-4-ylthio)-benzaldehyde dimethyl acetal 203179-01-5 C14H14ClNO2S
    4-chloro-3-(pyridin-4-ylthio)-benzaldehyde dimethyl acetal
    —— (SS,2S)-2-cyclohexylsulfinyl-N,N-dimethylpent-4-enethioamide 385837-48-9 C13H23NOS2
    (SS,2S)-2-cyclohexylsulfinyl-N,N-dimethylpent-4-enethioamide
    —— N-[4-chloro-3-(m-tolylsulfanyl)phenyl]-4-methoxy-pyrimidin-2-amine 1333950-22-3 C18H16ClN3OS
    N-[4-chloro-3-(m-tolylsulfanyl)phenyl]-4-methoxy-pyrimidin-2-amine
    —— (R)-5-((R)-hydroxy-(phenyl)methyl)-3-phenylthiofuran-2(5H)-one 1223157-56-9 C17H14O3S
    (R)-5-((R)-hydroxy-(phenyl)methyl)-3-phenylthiofuran-2(5H)-one
    —— [(2S,3S)-2-(4-Methoxy-pyrimidin-2-yloxymethyl)-5-phenylsulfanyl-tetrahydro-furan-3-ylmethyl]-phosphonic acid diethyl ester 220222-91-3 C21H29N2O6PS
    [(2S,3S)-2-(4-Methoxy-pyrimidin-2-yloxymethyl)-5-phenylsulfanyl-tetrahydro-furan-3-ylmethyl]-phosphonic acid diethyl ester
    —— 2-methanesulfonyl-2-methyl-propan-1-ol 25841-38-7 C5H12O3S
    2-methanesulfonyl-2-methyl-propan-1-ol
    —— N-ethyl-2-(methylthio)aniline 80922-03-8 C9H13NS
    N-ethyl-2-(methylthio)aniline
    —— 4-allylthiopyrimidin-2(1H)-one 105173-88-4 C7H8N2OS
    4-allylthiopyrimidin-2(1H)-one
    —— 4-benzylthiouracil 78932-26-0 C11H10N2OS
    4-benzylthiouracil