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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Methoxy-7-(3-phenylsulfanyl-but-3-enyl)-oxepane 424835-14-3 C17H24O2S
    2-Methoxy-7-(3-phenylsulfanyl-but-3-enyl)-oxepane
    —— 2-(N'-Methoxycarbonylguanidino)-5-phenylthio-methoxyacetanilid 92088-58-9 C18H20N4O4S
    2-(N'-Methoxycarbonylguanidino)-5-phenylthio-methoxyacetanilid
    —— 2,2,3,3-tetrafluoropropylisothiocyanate 79668-14-7 C4H3F4NS
    2,2,3,3-tetrafluoropropylisothiocyanate
    —— Trimethylsiloxy-tert-butyldimethylsilylmethyl-phenylsulphide 129584-68-5 C16H30OSSi2
    Trimethylsiloxy-tert-butyldimethylsilylmethyl-phenylsulphide
    —— 1-(dimethylsulfamoyl)-5-(2-methyl-6-ethylphenylthio)-4-hydroxypyrazole 143535-43-7 C14H19N3O3S2
    1-(dimethylsulfamoyl)-5-(2-methyl-6-ethylphenylthio)-4-hydroxypyrazole
    —— 1-isocyanato-4-isothiocyanato-cyclohexane 108748-91-0 C8H10N2OS
    1-isocyanato-4-isothiocyanato-cyclohexane
    —— 5-methyl-4-(4-(methylthio)phenyl)-3-phenylisoxazole 181696-81-1 C17H15NOS
    5-methyl-4-(4-(methylthio)phenyl)-3-phenylisoxazole
    —— [4-[4-(methylthio)phenyl]-3-phenylisoxazol-5-yl]acetic acid 181696-89-9 C18H15NO3S
    [4-[4-(methylthio)phenyl]-3-phenylisoxazol-5-yl]acetic acid
    —— (5Z)-1-(4-methoxyphenyl)-5-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-1,3-diazinane-2,4,6-trione 5963-67-7 C23H18N2O5S
    (5Z)-1-(4-methoxyphenyl)-5-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-1,3-diazinane-2,4,6-trione
    —— thioacetimidic acid butyl ester; hydrochloride 115809-46-6 C6H13NS*ClH
    thioacetimidic acid butyl ester; hydrochloride
    —— 4-(4-(3-(4-fluorophenyl)thioureido)phenylthio)-N-methylpicolinamide 1417344-62-7 C20H17FN4OS2
    4-(4-(3-(4-fluorophenyl)thioureido)phenylthio)-N-methylpicolinamide
    —— 2-acetyl-6,7-dihydro-5-methylthiothieno<2,3-b><1,4>thiazepine 161939-40-8 C10H11NOS3
    2-acetyl-6,7-dihydro-5-methylthiothieno<2,3-b><1,4>thiazepine
    —— (2-methoxyethyl)-(2-phenylthiocyclopentyl)amine 648419-44-7 C14H21NOS
    (2-methoxyethyl)-(2-phenylthiocyclopentyl)amine
    —— N'-Methyl-N'-(2-chlor-propyl)-N-sulfinyl-hydrazin 20570-04-1 C4H9ClN2OS
    N'-Methyl-N'-(2-chlor-propyl)-N-sulfinyl-hydrazin
    —— Tert-butyl-imino-methyl-oxo-lambda6-sulfane 1356395-48-6 C5H13NOS
    Tert-butyl-imino-methyl-oxo-lambda6-sulfane
    —— 2-bromo-4-chloro-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]iminomethyl]phenol 5489-94-1 C18H15BrClN3OS
    2-bromo-4-chloro-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]iminomethyl]phenol
    —— Tetrathiodiglykol 15576-64-4 C4H10O2S4
    Tetrathiodiglykol
    —— N'-Methyl-N'-(2-chloraethyl)-N-sulfinyl-hydrazin 20570-03-0 C3H7ClN2OS
    N'-Methyl-N'-(2-chloraethyl)-N-sulfinyl-hydrazin
    —— 2-(2-bromoallyl)-3-(phenylsulfanyl)-1-tosyl-1H-pyrrole 1447766-51-9 C20H18BrNO2S2
    2-(2-bromoallyl)-3-(phenylsulfanyl)-1-tosyl-1H-pyrrole
    —— N-methyl-4,5-ethylenedithio-1,3-thiazol-2-thione 917078-03-6 C6H7NS4
    N-methyl-4,5-ethylenedithio-1,3-thiazol-2-thione
    —— 2,4-dimethoxy-5-chlorodiphenyl sulfide 75787-00-7 C14H13ClO2S
    2,4-dimethoxy-5-chlorodiphenyl sulfide
    —— Bis-(2-methyl-<1,3>dithian-2-yl)-phenyl-methanol 4883-00-5 C17H24OS4
    Bis-(2-methyl-<1,3>dithian-2-yl)-phenyl-methanol
    —— 2-[(5-phenyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinoline-3-carbaldehyde 1134633-64-9 C18H12N4OS
    2-[(5-phenyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinoline-3-carbaldehyde
    —— Benzothiazole, 2-[[4-nitro-2-(trifluoromethyl)phenyl]thio]- 91512-40-2 C14H7F3N2O2S2
    Benzothiazole, 2-[[4-nitro-2-(trifluoromethyl)phenyl]thio]-
    —— 1-Phenylsulfanyl-butane-2,3-dione 114114-06-6 C10H10O2S
    1-Phenylsulfanyl-butane-2,3-dione
    —— 4-methyl-1,2-pentadienyl phenyl sulfide 77084-82-3 C12H14S
    4-methyl-1,2-pentadienyl phenyl sulfide
    —— 2-(3-pyridylmethylene)-7-ethylbenzo[b]thiophen-3(2H)-one 1027996-95-7 C16H13NOS
    2-(3-pyridylmethylene)-7-ethylbenzo[b]thiophen-3(2H)-one
    —— 2-(4-pyridylmethylene)-7-ethylbenzo[b]thiophen-3(2H)-one 1027996-96-8 C16H13NOS
    2-(4-pyridylmethylene)-7-ethylbenzo[b]thiophen-3(2H)-one
    —— 1-methoxy-2-methyl-1-methylsulfanyl-propene 70114-70-4 C6H12OS
    1-methoxy-2-methyl-1-methylsulfanyl-propene
    —— 1-Ethylsulfanyl-3-methylsulfanyl-benzene 83500-74-7 C9H12S2
    1-Ethylsulfanyl-3-methylsulfanyl-benzene
    —— (E)-1-fluoro-1-phenyl-2-(phenylthio)propene 129762-13-6 C15H13FS
    (E)-1-fluoro-1-phenyl-2-(phenylthio)propene
    —— 2-hydroxymethyl-1,4-benzodithiane 1206598-12-0 C9H10OS2
    2-hydroxymethyl-1,4-benzodithiane
    —— 1,2,3,4,4a,10a-hexahydrothianthrene 1206598-11-9 C12H14S2
    1,2,3,4,4a,10a-hexahydrothianthrene
    —— 3-Butyl-2,3-dihydro-1,4-benzodithiine 1206598-10-8 C12H16S2
    3-Butyl-2,3-dihydro-1,4-benzodithiine
    —— N,N-Dimethyl-N'-(2-methylsulfanyl-pyrimidin-4-yl)-formamidine 141945-01-9 C8H12N4S
    N,N-Dimethyl-N'-(2-methylsulfanyl-pyrimidin-4-yl)-formamidine
    —— <3-(methylthio)phenylthio>acetic acid 3996-33-6 C9H10O2S2
    <3-(methylthio)phenylthio>acetic acid
    —— (2-Cyclohexanesulfonyl-ethyl)-trimethyl-silane 114764-26-0 C11H24O2SSi
    (2-Cyclohexanesulfonyl-ethyl)-trimethyl-silane
    —— 1-Methyl-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitro-1,2,4-triazole 5187-06-4 C6H7N7O2S
    1-Methyl-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitro-1,2,4-triazole
    —— 5-Methoxycyclohexene-1-carbonyl isothiocyanate 1134541-40-4 C9H11NO2S
    5-Methoxycyclohexene-1-carbonyl isothiocyanate
    —— Trimethyl-(1-methyl-4-phenylsulfanyl-butoxy)-silane 193539-53-6 C14H24OSSi
    Trimethyl-(1-methyl-4-phenylsulfanyl-butoxy)-silane
    —— 2,4,6-Trimethyl-6H-1,3,5-oxathiazin 339362-92-4 C6H11NOS
    2,4,6-Trimethyl-6H-1,3,5-oxathiazin
    —— 4-ethyl-3-phenylthio-4,5-dihydrofuran-2(3H)-one 96540-45-3 C12H14O2S
    4-ethyl-3-phenylthio-4,5-dihydrofuran-2(3H)-one
    —— methyl 2-(trifluoromethylsulfonyl)acetate 54049-36-4 C4H5F3O4S
    methyl 2-(trifluoromethylsulfonyl)acetate
    —— ethyl 4-methyl-2-oxo-7-phenylthio-2,3,6,7-tetrahydro-1H-1,3-diazepine-5-carboxylate 1251716-07-0 C15H18N2O3S
    ethyl 4-methyl-2-oxo-7-phenylthio-2,3,6,7-tetrahydro-1H-1,3-diazepine-5-carboxylate
    —— 4-(2'-phenyl-ethylthio)-aniline 60091-84-1 C14H15NS
    4-(2'-phenyl-ethylthio)-aniline
    —— 5-(4-Chlorophenyl)-3-{[(4-chlorophenyl)sulfanyl]methyl}isoxazole 4714-78-7 C16H11Cl2NOS
    5-(4-Chlorophenyl)-3-{[(4-chlorophenyl)sulfanyl]methyl}isoxazole
    —— 2-Bromo-1-[(4-chlorophenyl)sulfanyl]-4-nitrobenzene 58291-59-1 C12H7BrClNO2S
    2-Bromo-1-[(4-chlorophenyl)sulfanyl]-4-nitrobenzene
    —— 2-<bis(methylthio)-methyloxycarbonyl-methyl>-cyclohexanone 111017-53-9 C11H18O3S2
    2-<bis(methylthio)-methyloxycarbonyl-methyl>-cyclohexanone
    —— Ethyl 2-[(4-phenyl-1,2,3-thiadiazol-5-yl)sulfanyl]acetate 338408-09-6 C12H12N2O2S2
    Ethyl 2-[(4-phenyl-1,2,3-thiadiazol-5-yl)sulfanyl]acetate
    —— 3-[2-(tert-butyldiphenylsilyloxy)ethyl]-6,8-bis(methylsulfanyl)imidazo[2,1-f ][1,2,4]triazine 1097624-32-2 C25H30N4OS2Si
    3-[2-(tert-butyldiphenylsilyloxy)ethyl]-6,8-bis(methylsulfanyl)imidazo[2,1-f ][1,2,4]triazine