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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (E)-3-(4-chlorophenylsulfanyl)hex-3-en-2-ol 1217367-27-5 C12H15ClOS
    (E)-3-(4-chlorophenylsulfanyl)hex-3-en-2-ol
    —— 2-[[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide 332386-52-4 C10H8ClN3O2S
    2-[[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2,2'-Sulfanediylbis(3-tert-butyl-5-methylphenol) 6935-22-4 C22H30O2S
    2,2'-Sulfanediylbis(3-tert-butyl-5-methylphenol)
    —— (E)-3-(p-tolylsulfanyl)hex-3-en-2-ol 1217367-28-6 C13H18OS
    (E)-3-(p-tolylsulfanyl)hex-3-en-2-ol
    —— (4-ethoxycarbonylmethylphenylthio)acetic acid 879403-05-1 C12H14O4S
    (4-ethoxycarbonylmethylphenylthio)acetic acid
    —— ethyl {[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]thio}acetate 332912-26-2 C12H11ClN2O3S
    ethyl {[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]thio}acetate
    —— 4-(6-methylsulfanylpyrimidin-4-yl)-2H-pyrazol-3-ylamine 1018473-11-4 C8H9N5S
    4-(6-methylsulfanylpyrimidin-4-yl)-2H-pyrazol-3-ylamine
    —— (1R,2S)-1-((R)-2,2-Diethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propane-1,2-diol 228243-79-6 C16H24O4S
    (1R,2S)-1-((R)-2,2-Diethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propane-1,2-diol
    —— 5-Anilino-4,6-dihydroxy-2-methylmercapto-pyrimidin 92290-01-2 C11H11N3O2S
    5-Anilino-4,6-dihydroxy-2-methylmercapto-pyrimidin
    —— 1-methyl-4-(6-methylsulfanylpyrimidin-4-yl)-1H-pyrazol-3-ylamine 1018473-12-5 C9H11N5S
    1-methyl-4-(6-methylsulfanylpyrimidin-4-yl)-1H-pyrazol-3-ylamine
    —— (1S,2S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propan-1-ol 228243-80-9 C22H38O4SSi
    (1S,2S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propan-1-ol
    —— 5-m-Toluidino-4,6-dihydroxy-2-methylmercapto-pyrimidin 88617-72-5 C12H13N3O2S
    5-m-Toluidino-4,6-dihydroxy-2-methylmercapto-pyrimidin
    —— tert-Butyl-[(S)-2-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-1-phenylsulfanylmethyl-allyloxy]-dimethyl-silane 227299-40-3 C23H38O3SSi
    tert-Butyl-[(S)-2-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-1-phenylsulfanylmethyl-allyloxy]-dimethyl-silane
    —— [3S,4S,5R,6R]-3-O-tert-butyl(dimethyl)silyl-6-tert-butyl(dimethyl)silyloxymethyl-4,5-O-(1-methylethylidene)-3,4,5-trihydroxycyclohexan-1-one 1,3-propanedithioketal 359011-65-7 C25H50O4S2Si2
    [3S,4S,5R,6R]-3-O-tert-butyl(dimethyl)silyl-6-tert-butyl(dimethyl)silyloxymethyl-4,5-O-(1-methylethylidene)-3,4,5-trihydroxycyclohexan-1-one 1,3-propanedithioketal
    —— (4-Ethyl-5-methyl-4H-[1,2,4]triazol-3-ylsulfanyl)-acetic acid 886498-62-0 C7H11N3O2S
    (4-Ethyl-5-methyl-4H-[1,2,4]triazol-3-ylsulfanyl)-acetic acid
    —— 5-Amino-2-(methylthio)pyrimidin-4(3H)-one 6627-25-4 C5H7N3OS
    5-Amino-2-(methylthio)pyrimidin-4(3H)-one
    —— 2-methyl-4-(6-methylsulfanylpyrimidin-4-yl)-2H-pyrazol-3-ylamine 1018473-08-9 C9H11N5S
    2-methyl-4-(6-methylsulfanylpyrimidin-4-yl)-2H-pyrazol-3-ylamine
    —— 3-(3-fluorobenzylthio)-5-methyl[1,2,4]triazine 1313039-64-3 C11H10FN3S
    3-(3-fluorobenzylthio)-5-methyl[1,2,4]triazine
    —— 4-Ethylenamino-2-(o-chlor-benzylmercapto)-5-hydroxymethyl-pyrimidin 92253-35-5 C14H14ClN3OS
    4-Ethylenamino-2-(o-chlor-benzylmercapto)-5-hydroxymethyl-pyrimidin
    —— mesityl(4-(trifluoromethyl)phenyl)sulfane 51431-75-5 C16H15F3S
    mesityl(4-(trifluoromethyl)phenyl)sulfane
    —— 1-Butyloxy-1-phenylmercapto-butan 92369-10-3 C14H22OS
    1-Butyloxy-1-phenylmercapto-butan
    —— ethyl 3-(3-(3-nitropyridin-2-ylamino)-1H-pyrazol-5-ylthio)benzoate 1039630-88-0 C17H15N5O4S
    ethyl 3-(3-(3-nitropyridin-2-ylamino)-1H-pyrazol-5-ylthio)benzoate
    —— 3-(2,4,6-trimethylphenyl)-sulfanyl-propionic acid methyl ester 571167-33-4 C13H18O2S
    3-(2,4,6-trimethylphenyl)-sulfanyl-propionic acid methyl ester
    —— 4-[6-(mesitylthio)-4,5-dimethyl-3-oxo-3,4-dihydropyrazin-2-ylamino]benzonitrile 467468-94-6 C22H22N4OS
    4-[6-(mesitylthio)-4,5-dimethyl-3-oxo-3,4-dihydropyrazin-2-ylamino]benzonitrile
    —— 1,2-epoxy-3-(mesitylthio)propane 173912-26-0 C12H16OS
    1,2-epoxy-3-(mesitylthio)propane
    —— 4-chloro-2-<i>p</i>-tolylsulfanyl-benzonitrile 873414-67-6 C14H10ClNS
    4-chloro-2-<i>p</i>-tolylsulfanyl-benzonitrile
    —— 7-(methylsulfonyl)-11-oxatricyclo[5.3.1.0(1,5)]undecan-8-one 1170257-98-3 C11H16O4S
    7-(methylsulfonyl)-11-oxatricyclo[5.3.1.0(1,5)]undecan-8-one
    —— S-phenyl-O-i-propyl thiolcarbonate 17659-14-2 C10H12O2S
    S-phenyl-O-i-propyl thiolcarbonate
    —— 2,2'-(naphthalene-2,3-dithio)-bis(3,5,6-trichloropyridine) 489405-71-2 C20H8Cl6N2S2
    2,2'-(naphthalene-2,3-dithio)-bis(3,5,6-trichloropyridine)
    —— (5-Brom-pentyl)-p-tolyl-sulfid 17482-11-0 C12H17BrS
    (5-Brom-pentyl)-p-tolyl-sulfid
    —— 3-Undecyl-4-thiaisochroman-1-on 6629-34-1 C19H28O2S
    3-Undecyl-4-thiaisochroman-1-on
    —— 3-methyl-4-<i>p</i>-tolylsulfanyl-furazan 2-oxide 63435-81-4 C10H10N2O2S
    3-methyl-4-<i>p</i>-tolylsulfanyl-furazan 2-oxide
    —— 7-Chloro-1,4,6-benzo<b>triazaphenothiazine 74396-46-6 C13H7ClN4S
    7-Chloro-1,4,6-benzo<b>triazaphenothiazine
    —— 7-Methoxy-1,4,6-benzo<b>triazaphenothiazine 74396-45-5 C14H10N4OS
    7-Methoxy-1,4,6-benzo<b>triazaphenothiazine
    —— (2-isopropylsulfanylpyrimidin-4-yl)methanol 1609289-39-5 C8H12N2OS
    (2-isopropylsulfanylpyrimidin-4-yl)methanol
    —— N,N-dimethylcyclohexanecarbothioamide 514223-99-5 C9H17NS
    N,N-dimethylcyclohexanecarbothioamide
    —— 3-(4-bromophenylthio)-2,6,6-trimethyl-6,7-dihydro-1H-indol-4(5H)-one 1219450-52-8 C17H18BrNOS
    3-(4-bromophenylthio)-2,6,6-trimethyl-6,7-dihydro-1H-indol-4(5H)-one
    —— cis-dichlorobis(di-n-propyl sulfoxide)platinum(II) 89301-38-2 C12H28Cl2O2PtS2
    cis-dichlorobis(di-n-propyl sulfoxide)platinum(II)
    —— (3-Chloro-4-phenylsulfanyl-but-1-ynyl)-trimethyl-silane 38943-10-1 C13H17ClSSi
    (3-Chloro-4-phenylsulfanyl-but-1-ynyl)-trimethyl-silane
    —— tert-Butyl 2-(4-amino-2-(6-methoxybenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-1-yl)ethylcarbamate 1061318-47-5 C21H25N5O5S
    tert-Butyl 2-(4-amino-2-(6-methoxybenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-1-yl)ethylcarbamate
    —— 3-methyl-4-<i>p</i>-tolylsulfanyl-furazan 63435-90-5 C10H10N2OS
    3-methyl-4-<i>p</i>-tolylsulfanyl-furazan
    —— 3-(2-Chlor-benzylmercapto)-6-methyl-pyridazin 5589-94-6 C12H11ClN2S
    3-(2-Chlor-benzylmercapto)-6-methyl-pyridazin
    —— 3-(phenylthio)-4-(trimethylsilyl)-3-sulfolene 114397-25-0 C13H18O2S2Si
    3-(phenylthio)-4-(trimethylsilyl)-3-sulfolene
    —— 3-methoxy-4-<i>p</i>-tolylsulfanyl-toluene 109592-50-9 C15H16OS
    3-methoxy-4-<i>p</i>-tolylsulfanyl-toluene
    —— di-sec-butyl sulfone 10495-46-2 C8H18O2S
    di-sec-butyl sulfone
    —— 3-hydroxy-4-(4-tolylsulfanyl)-2-pyrone 881171-79-5 C12H10O3S
    3-hydroxy-4-(4-tolylsulfanyl)-2-pyrone
    —— 1-(1'-methyl-5'-nitropyrrol-2'-yl)ethyl p-tolyl sulfide 115975-78-5 C14H16N2O2S
    1-(1'-methyl-5'-nitropyrrol-2'-yl)ethyl p-tolyl sulfide
    —— <i>N</i>-[2-(4-chloro-phenylsulfanyl)-ethyl]-aniline 6632-01-5 C14H14ClNS
    <i>N</i>-[2-(4-chloro-phenylsulfanyl)-ethyl]-aniline
    —— 2-Ethylhexyl-4-methylphenyl sulfide 123359-03-5 C15H24S
    2-Ethylhexyl-4-methylphenyl sulfide
    —— N-isopropylthiomethacrylamide 139633-11-7 C7H13NS
    N-isopropylthiomethacrylamide