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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-amino-3,5-dimethyl-2-methylsulfanyl-3<i>H</i>-pyrimidin-4-one 98432-28-1 C7H11N3OS
    6-amino-3,5-dimethyl-2-methylsulfanyl-3<i>H</i>-pyrimidin-4-one
    —— 5-chloro-2-(4-isopropylphenylthio)benzoic acid 91527-95-6 C16H15ClO2S
    5-chloro-2-(4-isopropylphenylthio)benzoic acid
    —— 2-[bis(propylsulfanyl)methyl]-5-(2-thienylsulfanyl)thiophene 1198175-63-1 C15H20S5
    2-[bis(propylsulfanyl)methyl]-5-(2-thienylsulfanyl)thiophene
    —— 2-[-5-(2-thienylsulfanyl)thiophene-2-yl]-1,3-dithiane 1198175-64-2 C12H12S5
    2-[-5-(2-thienylsulfanyl)thiophene-2-yl]-1,3-dithiane
    —— 2,2',5,5'-Tetrahydroxydiphenylsulfid 65201-01-6 C12H10O4S
    2,2',5,5'-Tetrahydroxydiphenylsulfid
    —— 5-Methyl-3.4.6-trithiaoctan-6-oxid 42474-29-3 C6H14OS3
    5-Methyl-3.4.6-trithiaoctan-6-oxid
    —— Tetramethyl-2,3,4,4-cyclopenten-2-thion-1 30221-54-6 C9H14S
    Tetramethyl-2,3,4,4-cyclopenten-2-thion-1
    —— 2-amino-1,5-dihydro-7-(phenylthio)-4H-pyrrolo[3,2-d]pyrimidin-4-one 266347-84-6 C12H10N4OS
    2-amino-1,5-dihydro-7-(phenylthio)-4H-pyrrolo[3,2-d]pyrimidin-4-one
    —— 1-methyl-5-(4,4-ethylenedioxyhexyl)thio-1,2,3,4-tetrazole 80086-14-2 C10H18N4O2S
    1-methyl-5-(4,4-ethylenedioxyhexyl)thio-1,2,3,4-tetrazole
    —— 3-phenylthiocyclopentanol 152584-31-1 C11H14OS
    3-phenylthiocyclopentanol
    —— D-<i>lyxo</i>-2-deoxy-hexose-diethyldithioacetal 144898-41-9 C10H22O4S2
    D-<i>lyxo</i>-2-deoxy-hexose-diethyldithioacetal
    —— (2-Isopropylidene-cyclopropylsulfanyl)-benzene 128902-37-4 C12H14S
    (2-Isopropylidene-cyclopropylsulfanyl)-benzene
    —— 2-Methanesulfonyl-2-methylsulfanyl-tetradecane 83593-83-3 C16H34O2S2
    2-Methanesulfonyl-2-methylsulfanyl-tetradecane
    —— thiophenyl 3,6-anhydro-2-deoxy-β-D-glucopyranoside 1610617-94-1 C12H14O3S
    thiophenyl 3,6-anhydro-2-deoxy-β-D-glucopyranoside
    —— 5-amino-1-butyl-2-(2,5-dimethoxy-phenylsulfanyl)-1H-imidazole-4-carboxamide 1102466-44-3 C16H22N4O3S
    5-amino-1-butyl-2-(2,5-dimethoxy-phenylsulfanyl)-1H-imidazole-4-carboxamide
    —— 6-amino-2-(benzylthio)-5-(2-phenylethynyl)pyrimidin-4(3H)-one 1160569-73-2 C19H15N3OS
    6-amino-2-(benzylthio)-5-(2-phenylethynyl)pyrimidin-4(3H)-one
    —— 2-(4-(trifluoromethyl)phenylthio)-5-amino-1-butyl-1H-imidazole-4-carboxamide 1102466-41-0 C15H17F3N4OS
    2-(4-(trifluoromethyl)phenylthio)-5-amino-1-butyl-1H-imidazole-4-carboxamide
    —— 2-methyl-2-phenyl-1,3-oxathiane 100058-46-6 C11H14OS
    2-methyl-2-phenyl-1,3-oxathiane
    —— tert-butyl(dimethyl){[4-(methylthio)benzyl]oxy}silane 1027730-39-7 C14H24OSSi
    tert-butyl(dimethyl){[4-(methylthio)benzyl]oxy}silane
    —— Formaldehyde di-(3-hydroxypropyl) thioacetal 143771-05-5 C7H16O2S2
    Formaldehyde di-(3-hydroxypropyl) thioacetal
    —— 3-mercaptopropyltrichlorosilane 88334-67-2 C3H7Cl3SSi
    3-mercaptopropyltrichlorosilane
    —— 4H-1,3,5-Dithiazine, dihydro-2,4,6-trimethyl-, hydrochloride 5340-02-3 C6H12ClNS2
    4H-1,3,5-Dithiazine, dihydro-2,4,6-trimethyl-, hydrochloride
    —— 3-(perfluorobutylthio)propanol 875628-33-4 C7H7F9OS
    3-(perfluorobutylthio)propanol
    —— 1-oxa-5-thiaspiro[5,5]undecane 180-95-0 C9H16OS
    1-oxa-5-thiaspiro[5,5]undecane
    —— 3-((5-aminopyrimidin-4-yl)thio)propan-1-ol 1422469-87-1 C7H11N3OS
    3-((5-aminopyrimidin-4-yl)thio)propan-1-ol
    —— ethyl 3-ethylthio-2-hydroxy-2-trifluoromethyl-1,4-dioxane-3-carboxylate 310460-93-6 C10H15F3O5S
    ethyl 3-ethylthio-2-hydroxy-2-trifluoromethyl-1,4-dioxane-3-carboxylate
    —— 3-Brom-6-methylthio-1,2,4,5-tetrazin 64499-97-4 C3H3BrN4S
    3-Brom-6-methylthio-1,2,4,5-tetrazin
    —— 4-cyclohexyl-N-[2-[2-(4-cyclohexylbutylamino)ethylsulfonylsulfanyl]ethyl]butan-1-amine;hydron;dichloride —— C24H50Cl2N2O2S2
    4-cyclohexyl-N-[2-[2-(4-cyclohexylbutylamino)ethylsulfonylsulfanyl]ethyl]butan-1-amine;hydron;dichloride
    —— 3-(2-Cyanphenylthio)-6-methylthio-1,2,4,5-tetrazin 121288-79-7 C10H7N5S2
    3-(2-Cyanphenylthio)-6-methylthio-1,2,4,5-tetrazin
    —— 3-[(2-cyanophenyl)thio]-1,2-benzisothiazole 190970-00-4 C14H8N2S2
    3-[(2-cyanophenyl)thio]-1,2-benzisothiazole
    —— <4-Chlor-phenylmercapto>-essigsaeure-butylamid 91802-77-6 C12H16ClNOS
    <4-Chlor-phenylmercapto>-essigsaeure-butylamid
    —— Mono-ethylmercaptodiethoxymethan 25604-63-1 C7H16O2S
    Mono-ethylmercaptodiethoxymethan
    —— 1-(2-Hydroxy-ethoxymethyl)-5-methyl-6-phenylsulfanyl-4-thioxo-3,4-dihydro-1H-pyrimidin-2-one 125057-09-2 C14H16N2O3S2
    1-(2-Hydroxy-ethoxymethyl)-5-methyl-6-phenylsulfanyl-4-thioxo-3,4-dihydro-1H-pyrimidin-2-one
    —— 1-Trimethylsiloxy-1-phenylthio-2,2-difluoroethene 169199-37-5 C11H14F2OSSi
    1-Trimethylsiloxy-1-phenylthio-2,2-difluoroethene
    —— 1-(2-Hydroxy-ethoxymethyl)-3,5-dimethyl-6-phenylsulfanyl-1H-pyrimidine-2,4-dione 132885-44-0 C15H18N2O4S
    1-(2-Hydroxy-ethoxymethyl)-3,5-dimethyl-6-phenylsulfanyl-1H-pyrimidine-2,4-dione
    —— 6-tert-Butylsulfanyl-1-(2-hydroxy-ethoxymethyl)-5-methyl-1H-pyrimidine-2,4-dione 131193-99-2 C12H20N2O4S
    6-tert-Butylsulfanyl-1-(2-hydroxy-ethoxymethyl)-5-methyl-1H-pyrimidine-2,4-dione
    —— 1-ethyl-6-(phenylthio)thymine 136160-20-8 C13H14N2O2S
    1-ethyl-6-(phenylthio)thymine
    —— 4,4,4-trifluorobutanethioamide 1184850-75-6 C4H6F3NS
    4,4,4-trifluorobutanethioamide
    —— 1-<<2-(benzyloxy)ethoxy>methyl>-6-(phenylthio)thymine 132774-36-8 C21H22N2O4S
    1-<<2-(benzyloxy)ethoxy>methyl>-6-(phenylthio)thymine
    —— 1-butyl-6-(phenylthio)thymine 136160-21-9 C15H18N2O2S
    1-butyl-6-(phenylthio)thymine
    —— 1-[(2-hydroxyethoxy)methyl]-3-benzyl-6-phenylthiothymine 132885-45-1 C21H22N2O4S
    1-[(2-hydroxyethoxy)methyl]-3-benzyl-6-phenylthiothymine
    —— 3,5-bis(methylsulfanyl)aniline 1352311-14-8 C8H11NS2
    3,5-bis(methylsulfanyl)aniline
    —— 1-Methyl-4-((E)-1-methyl-2-phenyl-vinylsulfanyl)-benzene 153215-23-7 C16H16S
    1-Methyl-4-((E)-1-methyl-2-phenyl-vinylsulfanyl)-benzene
    —— 2-Amino-4-(4-chloro-pyrazol-1-yl)-6-methylsulfanyl-pyrimidine-5-carbonitrile 357289-62-4 C9H7ClN6S
    2-Amino-4-(4-chloro-pyrazol-1-yl)-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 3-Phenyl-1,4,2-benzodithiazine 77598-01-7 C13H9NS2
    3-Phenyl-1,4,2-benzodithiazine
    —— (2'R,3'R,4R,5S)-2,2-dimethyl-5-<(tert-butyldimethylsilyloxy)methyl>-4-<3'-<(4''-methylphenyl)thio>-3'-nitrooxiran-2'-yl>-1,3-dioxolane 157661-83-1 C21H33NO6SSi
    (2'R,3'R,4R,5S)-2,2-dimethyl-5-<(tert-butyldimethylsilyloxy)methyl>-4-<3'-<(4''-methylphenyl)thio>-3'-nitrooxiran-2'-yl>-1,3-dioxolane
    —— Z-(4S,5S)-2,2-dimethyl-5-<(tert-butyldimethylsilyloxy)methyl>-4-<2'-<(4''-methylphenyl)thio>-2'-nitroethenyl>-1,3-dioxolane 157661-82-0 C21H33NO5SSi
    Z-(4S,5S)-2,2-dimethyl-5-<(tert-butyldimethylsilyloxy)methyl>-4-<2'-<(4''-methylphenyl)thio>-2'-nitroethenyl>-1,3-dioxolane
    —— Phosphorothioic acid, O-(6-((4-chlorophenyl)thio)-3-pyridazinyl) O,O-diethyl ester 53605-09-7 C14H16ClN2O3PS2
    Phosphorothioic acid, O-(6-((4-chlorophenyl)thio)-3-pyridazinyl) O,O-diethyl ester
    —— 5-allyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one 134294-97-6 C13H19NO2S
    5-allyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— 5-(2-hydroxyethylthio)-1-methyl-1H-tetrazole 136621-97-1 C4H8N4OS
    5-(2-hydroxyethylthio)-1-methyl-1H-tetrazole