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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-(2-(2-(2-tert-butoxyethoxy)ethoxy)ethylsulfonyl)-2-methylbutan-2-amine 1373434-13-9 C15H33NO5S
    4-(2-(2-(2-tert-butoxyethoxy)ethoxy)ethylsulfonyl)-2-methylbutan-2-amine
    —— 2-(3-(dichloroamino)-3-methylbutylsulfonyl)ethanol 1373433-51-2 C7H15Cl2NO3S
    2-(3-(dichloroamino)-3-methylbutylsulfonyl)ethanol
    —— 2-(2-(2-(3-amino-3-methylbutylsulfonyl)ethoxy)ethoxy)ethanol 1373433-68-1 C11H25NO5S
    2-(2-(2-(3-amino-3-methylbutylsulfonyl)ethoxy)ethoxy)ethanol
    —— N-[4-[[4-[2-(dimethylamino)ethylamino]-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-61-8 C21H26N8OS2
    N-[4-[[4-[2-(dimethylamino)ethylamino]-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— 2-(phenylthio)-6-methylcyclohexanone 57768-34-0 C13H16OS
    2-(phenylthio)-6-methylcyclohexanone
    —— (Z)-1-(phenylthio)buta-1,3-diene 20664-21-5 C10H10S
    (Z)-1-(phenylthio)buta-1,3-diene
    —— 2-Methyl-2-phenylthio-cyclohexanon 54376-46-4 C13H16OS
    2-Methyl-2-phenylthio-cyclohexanon
    —— 1-(3-ethylsulfanyl-propylsulfanyl)-butane 90725-22-7 C9H20S2
    1-(3-ethylsulfanyl-propylsulfanyl)-butane
    —— 4,4'-Dimethyl-6,6'-dichlor-thioindigo 52700-64-8 C18H10Cl2O2S2
    4,4'-Dimethyl-6,6'-dichlor-thioindigo
    —— trans-1-Methoxy-3-methylmercapto-prop-1-en 13168-93-9 C5H10OS
    trans-1-Methoxy-3-methylmercapto-prop-1-en
    —— cis-1-Methoxy-3-methylmercapto-prop-1-en 13168-94-0 C5H10OS
    cis-1-Methoxy-3-methylmercapto-prop-1-en
    —— (2-chlorobut-3-en-1-yl)(phenyl)sulfane 16728-08-8 C10H11ClS
    (2-chlorobut-3-en-1-yl)(phenyl)sulfane
    —— 5.5'-Dichlor-7.7'-dimethylthioindigo 5462-29-3 C18H10Cl2O2S2
    5.5'-Dichlor-7.7'-dimethylthioindigo
    —— 3-[2-(4-hydroxyphenyl)ethyl]-6-(4-methylphenyl)-7H-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazine 1346462-15-4 C19H18N4OS
    3-[2-(4-hydroxyphenyl)ethyl]-6-(4-methylphenyl)-7H-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazine
    —— 4-Methylbenzo<b>thiophen-3(2H)-on 68670-96-2 C9H8OS
    4-Methylbenzo<b>thiophen-3(2H)-on
    —— tert-butyl [1-amino-4-(methylsulfonyl)butan-2-yl]carbamate 1429913-66-5 C10H22N2O4S
    tert-butyl [1-amino-4-(methylsulfonyl)butan-2-yl]carbamate
    —— ethyl 2-(5-chloro-2-(2-methoxy-2-oxoethyl)phenyl)-2-(phenylthio)acetate 1011458-53-9 C19H19ClO4S
    ethyl 2-(5-chloro-2-(2-methoxy-2-oxoethyl)phenyl)-2-(phenylthio)acetate
    —— α-Phenylmercapto-α-hydroxy-essigsaeure 72761-70-7 C8H8O3S
    α-Phenylmercapto-α-hydroxy-essigsaeure
    —— phenylsulfanylcarbene 52565-42-1 C7H6S
    phenylsulfanylcarbene
    —— (1,1-dimethyl-allyl)-methyl-disulfane 34776-59-5 C6H12S2
    (1,1-dimethyl-allyl)-methyl-disulfane
    —— 1-Methylthio-3,3,6-trimethylhept-5-en-1-in 63303-57-1 C11H18S
    1-Methylthio-3,3,6-trimethylhept-5-en-1-in
    —— 3-[2-cyclohexylethyl]-6-(4-methylphenyl)-7H-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazine 1346462-19-8 C19H24N4S
    3-[2-cyclohexylethyl]-6-(4-methylphenyl)-7H-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazine
    —— 3-(2-furyl)-6-(4-methylphenyl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadizine 183536-46-1 C15H12N4OS
    3-(2-furyl)-6-(4-methylphenyl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadizine
    —— 4-acetyl-5-chloro-2-methylthiopyrimidine 122372-21-8 C7H7ClN2OS
    4-acetyl-5-chloro-2-methylthiopyrimidine
    —— 2,3-Bis(methylthio)cyclopropenethione 60288-63-3 C5H6S3
    2,3-Bis(methylthio)cyclopropenethione
    —— 2-methylsulphenyl-4-methylamino-5-chloro-pyrimidine 515824-56-3 C6H8ClN3S
    2-methylsulphenyl-4-methylamino-5-chloro-pyrimidine
    —— 1,1 diethoxy 2-phenylthio 2(Z)-butene 90935-42-5 C14H20O2S
    1,1 diethoxy 2-phenylthio 2(Z)-butene
    —— (dimethyl-1',1' ethyl)thio-1 butadiene-1,3 26822-52-6 C8H14S
    (dimethyl-1',1' ethyl)thio-1 butadiene-1,3
    —— 2-n-Propylthio-aethanthiol 26733-37-9 C5H12S2
    2-n-Propylthio-aethanthiol
    —— bis-[2-(2-hydroxy-ethylsulfanyl)-propyl]-sulfide 872299-78-0 C10H22O2S3
    bis-[2-(2-hydroxy-ethylsulfanyl)-propyl]-sulfide
    —— 2-Chlorethyl-propylsulfon 55750-94-2 C5H11ClO2S
    2-Chlorethyl-propylsulfon
    —— S-methyl N-hexylthiocarbamate 120904-15-6 C8H17NOS
    S-methyl N-hexylthiocarbamate
    —— ethyl 3-(5-(pyrrolo[2,1-f][1,2,4]-triazin-4-ylamino)-2H-pyrazol-3-ylthio)benzoate 1039630-78-8 C18H16N6O2S
    ethyl 3-(5-(pyrrolo[2,1-f][1,2,4]-triazin-4-ylamino)-2H-pyrazol-3-ylthio)benzoate
    —— 4'-chloro-6-methylsulfanyl-[4,5']bipyrimidinyl 946422-12-4 C9H7ClN4S
    4'-chloro-6-methylsulfanyl-[4,5']bipyrimidinyl
    —— (2,6-dimethylphenylsulfanylmethyl)diphenylphosphine oxide 1574323-26-4 C21H21OPS
    (2,6-dimethylphenylsulfanylmethyl)diphenylphosphine oxide
    —— methyl 1-13C-2-thiophenyl acetate 169518-57-4 C9H10O2S
    methyl 1-13C-2-thiophenyl acetate
    —— [4-Tert-butyl-2-[5-tert-butyl-3-[5-tert-butyl-3-[5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfanyl-2-hydroxyphenyl]sulfanyl-2-hydroxyphenyl]sulfanylphenyl] trifluoromethanesulfonate 1293286-39-1 C42H48F6O8S5
    [4-Tert-butyl-2-[5-tert-butyl-3-[5-tert-butyl-3-[5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfanyl-2-hydroxyphenyl]sulfanyl-2-hydroxyphenyl]sulfanylphenyl] trifluoromethanesulfonate
    —— 2-β-methylsulphonylethylcycloheptanone 130898-33-8 C10H18O3S
    2-β-methylsulphonylethylcycloheptanone
    —— Triphenyl-[phenyl(phenylsulfanyl)methyl]silane 159956-87-3 C31H26SSi
    Triphenyl-[phenyl(phenylsulfanyl)methyl]silane
    —— phenyl 4-bromo-2-butenyl sulfide 114996-62-2 C10H11BrS
    phenyl 4-bromo-2-butenyl sulfide
    —— 4-{[2-(Chloromethyl)phenyl]sulfanyl}-2-fluoro-1-methylbenzene 64359-36-0 C14H12ClFS
    4-{[2-(Chloromethyl)phenyl]sulfanyl}-2-fluoro-1-methylbenzene
    —— (2-amino-1-methyl-propyl)-dithiocarbamic acid 873989-97-0 C5H12N2S2
    (2-amino-1-methyl-propyl)-dithiocarbamic acid
    —— (E)-4-[5-(2-methylsulfanylpyrimidin-4-yl)-thiophen-2-yl]-but-3-en-2-one 778646-54-1 C13H12N2OS2
    (E)-4-[5-(2-methylsulfanylpyrimidin-4-yl)-thiophen-2-yl]-but-3-en-2-one
    —— 6-amino-5-cyano-7,8-dihydro-4H-1,2,3-trithiocine 132843-53-9 C6H8N2S3
    6-amino-5-cyano-7,8-dihydro-4H-1,2,3-trithiocine
    —— 2-bis(tert-butoxycarbonyl)amino-6-((1S,2R)-2-(3-bromophenyl)-2-(pyridin-2-ylthio)cyclopropyl)-3-methylpyrimidin-4(3H)-one 1402883-40-2 C29H33BrN4O5S
    2-bis(tert-butoxycarbonyl)amino-6-((1S,2R)-2-(3-bromophenyl)-2-(pyridin-2-ylthio)cyclopropyl)-3-methylpyrimidin-4(3H)-one
    —— 1-Benzyl-5-chloro-4-(2,4-dimethoxy-3-methylphenylthio)-1H-1,2,3-triazole 96938-86-2 C18H18ClN3O2S
    1-Benzyl-5-chloro-4-(2,4-dimethoxy-3-methylphenylthio)-1H-1,2,3-triazole
    —— 1-benzyl-5-(phenylthio)-1,2,3-triazole-4-carboxylic acid 84158-71-4 C16H13N3O2S
    1-benzyl-5-(phenylthio)-1,2,3-triazole-4-carboxylic acid
    —— 1-benzyl-5-(phenylthio)-1,2,3-triazole-4-carbonyl chloride 87598-59-2 C16H12ClN3OS
    1-benzyl-5-(phenylthio)-1,2,3-triazole-4-carbonyl chloride
    —— 1-Benzyl-5-chloro-4-(2-hydroxy-4-methoxy-3-methylphenylthio)-1H-1,2,3-triazole 96938-85-1 C17H16ClN3O2S
    1-Benzyl-5-chloro-4-(2-hydroxy-4-methoxy-3-methylphenylthio)-1H-1,2,3-triazole
    —— 5-phenylthiofuran-2(5H)-one 77734-59-9 C10H10O2S
    5-phenylthiofuran-2(5H)-one