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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl 2-ethyl-3-methyl-2-phenylthiobut-3-enoate 86895-78-5 C14H18O2S
    methyl 2-ethyl-3-methyl-2-phenylthiobut-3-enoate
    —— N,N-Dimethyl-N'-(t-pentyl)-thioharnstoff 14294-22-5 C8H18N2S
    N,N-Dimethyl-N'-(t-pentyl)-thioharnstoff
    —— methyl(2-((2-(p-tolylethynyl)phenyl)ethynyl)phenyl)sulfane 1367458-45-4 C24H18S
    methyl(2-((2-(p-tolylethynyl)phenyl)ethynyl)phenyl)sulfane
    —— N-(4-((4-chloro-6-((5-methyl-1H-pyrazol-3-yl)amino)pyrimidin-2-yl)thio)phenyl)propionamide 639090-56-5 C17H17ClN6OS
    N-(4-((4-chloro-6-((5-methyl-1H-pyrazol-3-yl)amino)pyrimidin-2-yl)thio)phenyl)propionamide
    —— 4-chloro-2-(methylthio)-6-(m-tolylamino)pyrimidine-5-carbonitrile 1374157-11-5 C13H11ClN4S
    4-chloro-2-(methylthio)-6-(m-tolylamino)pyrimidine-5-carbonitrile
    —— 1,1,2-Trimethyl-isothioharnstoff 57618-94-7 C4H10N2S
    1,1,2-Trimethyl-isothioharnstoff
    —— 4-(4-chloro-phenylsulfanyl)-6-methyl-pyrrolo[3,4-c]pyridine-1,3-dione 227459-19-0 C14H9ClN2O2S
    4-(4-chloro-phenylsulfanyl)-6-methyl-pyrrolo[3,4-c]pyridine-1,3-dione
    —— 1-phenylsulfanyl-2,6-anhydro-1-deoxy-β-D-fructofuranose 445299-05-8 C12H14O4S
    1-phenylsulfanyl-2,6-anhydro-1-deoxy-β-D-fructofuranose
    —— Methyl-2-oxo-1-(phenyl-thio)cyclo-pentan-carboxylat 258823-01-7 C13H14O3S
    Methyl-2-oxo-1-(phenyl-thio)cyclo-pentan-carboxylat
    —— Allyl-N,N-diethylthiolcarbamat 18283-58-4 C8H15NOS
    Allyl-N,N-diethylthiolcarbamat
    —— phenyl 2-thio-β-D-fructopyranoside 1053626-36-0 C12H16O5S
    phenyl 2-thio-β-D-fructopyranoside
    —— 2-ethyl-4-methylsulfanyl-6-oxo-1H-pyrimidine-5-carbonitrile 96823-93-7 C8H9N3OS
    2-ethyl-4-methylsulfanyl-6-oxo-1H-pyrimidine-5-carbonitrile
    —— 3-bromo-4-(octylthio)thiophene 1608471-90-4 C12H19BrS2
    3-bromo-4-(octylthio)thiophene
    —— phenyl 1-phenylsulfanyl-2-thio-1-deoxy-β-D-fructopyranoside 445377-31-1 C18H20O4S2
    phenyl 1-phenylsulfanyl-2-thio-1-deoxy-β-D-fructopyranoside
    —— 3-hydroxy-5,5-dimethyl-2-phenylsulfanyl-cyclohex-2-enone 61908-09-6 C14H16O2S
    3-hydroxy-5,5-dimethyl-2-phenylsulfanyl-cyclohex-2-enone
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(5-methyl-[1,2,4]triazol-1-ylmethyl)pyridin-2(1H)-one 1185190-31-1 C18H19IN4OS
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(5-methyl-[1,2,4]triazol-1-ylmethyl)pyridin-2(1H)-one
    —— 3,4-Bis(methylthio)thiophene 150459-37-3 C6H8S3
    3,4-Bis(methylthio)thiophene
    —— 3,4-di(p-tolylthio)thiophene 1263672-69-0 C18H16S3
    3,4-di(p-tolylthio)thiophene
    —— Diethyl 2-(2-phenylsulfanylprop-2-enyl)-2-prop-2-enylpropanedioate 141928-36-1 C19H24O4S
    Diethyl 2-(2-phenylsulfanylprop-2-enyl)-2-prop-2-enylpropanedioate
    —— 2-[(2-Nitro-1-phenylethyl)thio]aniline 176261-33-9 C14H14N2O2S
    2-[(2-Nitro-1-phenylethyl)thio]aniline
    —— 3,4-di(4-methoxyphenylthio)thiophene 1263672-67-8 C18H16O2S3
    3,4-di(4-methoxyphenylthio)thiophene
    —— 2-(4-Methylsulfanylphenyl)sulfanylbenzoic acid 17097-86-8 C14H12O2S2
    2-(4-Methylsulfanylphenyl)sulfanylbenzoic acid
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(3-methyl-[1,2,4]triazol-1-ylmethyl)pyridin-2(1H)-one 1185190-19-5 C18H19IN4OS
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(3-methyl-[1,2,4]triazol-1-ylmethyl)pyridin-2(1H)-one
    —— 3-allylthio-4-bromothiophene 99219-93-9 C7H7BrS2
    3-allylthio-4-bromothiophene
    —— methyl (Z)-3,5-bis(phenylsulfanyl)pent-2-enoate 1338989-74-4 C18H18O2S2
    methyl (Z)-3,5-bis(phenylsulfanyl)pent-2-enoate
    —— 1,1'-((2-(2-(phenylthio)phenylthio)phenyl)-methylene)bis(1H-pyrazole) 1210393-66-0 C25H20N4S2
    1,1'-((2-(2-(phenylthio)phenylthio)phenyl)-methylene)bis(1H-pyrazole)
    —— 1,1'-((2-(phenylthio)phenyl)methylene)bis(1H-pyrazole) 1292840-70-0 C19H16N4S
    1,1'-((2-(phenylthio)phenyl)methylene)bis(1H-pyrazole)
    —— 2-acetamido-1-(3-carbomethoxy-2-thioureido)-5-phenylthiobenzene 54394-10-4 C17H17N3O3S2
    2-acetamido-1-(3-carbomethoxy-2-thioureido)-5-phenylthiobenzene
    —— (2-methylthio-7-oxo-6,7-dihydrothiazolo[4,5-d]pyrimidin-5-ylsulfanyl)acetic acid ethyl ester 146381-71-7 C10H11N3O3S3
    (2-methylthio-7-oxo-6,7-dihydrothiazolo[4,5-d]pyrimidin-5-ylsulfanyl)acetic acid ethyl ester
    —— 1,1'-(2-(phenylthio)ethane-1,1-diyl)bis(1H-pyrazole) 1292840-74-4 C14H14N4S
    1,1'-(2-(phenylthio)ethane-1,1-diyl)bis(1H-pyrazole)
    —— 7-chloro-1,1,3-trioxo-3,4-dihydro-2H-1,5,2-benzo[f]dithiazepin-8-carboxylic acid 348119-94-8 C9H6ClNO5S2
    7-chloro-1,1,3-trioxo-3,4-dihydro-2H-1,5,2-benzo[f]dithiazepin-8-carboxylic acid
    —— 6-(4-allyl-5-methylthio-1,2,4-triazol-3-yl)pyrimidine-2,4-dione 202746-10-9 C10H11N5O2S
    6-(4-allyl-5-methylthio-1,2,4-triazol-3-yl)pyrimidine-2,4-dione
    —— 5-methyl-4-morpholin-4-yl-5H-pyrimido[4,5-b][1,4]thiazin-6-one 54660-40-1 C11H14N4O2S
    5-methyl-4-morpholin-4-yl-5H-pyrimido[4,5-b][1,4]thiazin-6-one
    —— 4-morpholin-4-yl-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one 54660-32-1 C10H12N4O2S
    4-morpholin-4-yl-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one
    —— N,N-diethyl-N'-pivaloylthiourea 398995-31-8 C10H20N2OS
    N,N-diethyl-N'-pivaloylthiourea
    —— 4-nitrophenyl 2',4',6'-trichlorophenyl sulfide 105456-68-6 C12H6Cl3NO2S
    4-nitrophenyl 2',4',6'-trichlorophenyl sulfide
    —— 2-Methylthio-4-keto-3,5,6-trimethylpyrimidin 90197-26-5 C8H12N2OS
    2-Methylthio-4-keto-3,5,6-trimethylpyrimidin
    —— N'-hydroxy-2-{[3-(trifluoromethyl)pyridin-2-yl]thio}ethanimidamide —— C8H8F3N3OS
    N'-hydroxy-2-{[3-(trifluoromethyl)pyridin-2-yl]thio}ethanimidamide
    —— 5,6-dimethoxy-2-(3-phenylsulfanyl-1H-indol-2-yl)-1H-indole 156749-36-9 C24H20N2O2S
    5,6-dimethoxy-2-(3-phenylsulfanyl-1H-indol-2-yl)-1H-indole
    —— 5-(1-imidazolyl)imidazo<2,1-b><1,3,5>benzothiadiazepine 88251-81-4 C13H9N5S
    5-(1-imidazolyl)imidazo<2,1-b><1,3,5>benzothiadiazepine
    —— 4-Amino-5-(2-bromo-phenylsulfanyl)-2-(2-bromo-phenylsulfanylmethoxy)-phenol 1026084-20-7 C19H15Br2NO2S2
    4-Amino-5-(2-bromo-phenylsulfanyl)-2-(2-bromo-phenylsulfanylmethoxy)-phenol
    —— 4-Methoxy-2-phenylsulfanyl-5-phenylsulfanylmethoxy-phenylamine 1027427-05-9 C20H19NO2S2
    4-Methoxy-2-phenylsulfanyl-5-phenylsulfanylmethoxy-phenylamine
    —— 1-<2-(2-imidazolyl)thiophenyliminothiocarbonyl>-4-methylpiperazine 81382-54-9 C15H19N5S2
    1-<2-(2-imidazolyl)thiophenyliminothiocarbonyl>-4-methylpiperazine
    —— 2-Chloro-N-(4-methoxy-2-phenylsulfanyl-5-phenylsulfanylmethoxy-phenyl)-acetamide 1026522-30-4 C22H20ClNO3S2
    2-Chloro-N-(4-methoxy-2-phenylsulfanyl-5-phenylsulfanylmethoxy-phenyl)-acetamide
    —— N-[2-(2-Bromo-phenylsulfanyl)-5-(2-bromo-phenylsulfanylmethoxy)-4-hydroxy-phenyl]-acetamide 158719-88-1 C21H17Br2NO3S2
    N-[2-(2-Bromo-phenylsulfanyl)-5-(2-bromo-phenylsulfanylmethoxy)-4-hydroxy-phenyl]-acetamide
    —— Propan-2-yl 2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate 313958-78-0 C13H14N2O3S
    Propan-2-yl 2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate
    —— 2-Chloro-N-[2-(6-nitro-benzo[1,3]dioxol-5-ylsulfanyl)-phenyl]-acetamide 1027182-42-8 C15H11ClN2O5S
    2-Chloro-N-[2-(6-nitro-benzo[1,3]dioxol-5-ylsulfanyl)-phenyl]-acetamide
    —— 2-(6-Nitro-benzo[1,3]dioxol-5-ylsulfanyl)-phenylamine 67851-24-5 C13H10N2O4S
    2-(6-Nitro-benzo[1,3]dioxol-5-ylsulfanyl)-phenylamine
    —— O-tert-butyl thiocarbamate 10381-25-6 C5H11NOS
    O-tert-butyl thiocarbamate
    —— O-Propyl-N-acetylthionocarbamat 19959-54-7 C6H11NO2S
    O-Propyl-N-acetylthionocarbamat