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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— n-butyl 1-octynyl sulfide 1173005-26-9 C12H22S
    n-butyl 1-octynyl sulfide
    —— 6-benzyl-4-methylthio-2-oxo-1,2-dihydropyrimidine-5-carbonitrile 95064-58-7 C13H11N3OS
    6-benzyl-4-methylthio-2-oxo-1,2-dihydropyrimidine-5-carbonitrile
    —— 3-(3-fluoro-4-nitro-phenylsulfanyl)-6-(1-methyl-1H-pyrazol-4-yl)-[1,2,4]triazolo[4,3-b]pyridazine 1022151-39-8 C15H10FN7O2S
    3-(3-fluoro-4-nitro-phenylsulfanyl)-6-(1-methyl-1H-pyrazol-4-yl)-[1,2,4]triazolo[4,3-b]pyridazine
    —— N-cyclopropyl-2-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenylthio)acetamide 1595291-46-5 C17H24BNO3S
    N-cyclopropyl-2-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenylthio)acetamide
    —— (cycloprop-2-ene-1,1-diylbis(methylene)) bis((4-bromophenyl)sulfane) 1407709-21-0 C17H14Br2S2
    (cycloprop-2-ene-1,1-diylbis(methylene)) bis((4-bromophenyl)sulfane)
    —— 7-methyl-6-[6-(1-methyl-1H-pyrazol-4-yl)-[1,2,4]triazolo[4,3-b]pyridazin-3-ylsulfanyl]-quinoline 1022150-69-1 C19H15N7S
    7-methyl-6-[6-(1-methyl-1H-pyrazol-4-yl)-[1,2,4]triazolo[4,3-b]pyridazin-3-ylsulfanyl]-quinoline
    —— 3-hydroxy-4-(p-tolylthio)thiolane 1,1-dioxide 163775-88-0 C11H14O3S2
    3-hydroxy-4-(p-tolylthio)thiolane 1,1-dioxide
    —— (<i>E</i>)-5,5'-dichloro-[2,2']bi[benzo[<i>b</i>]thiophenylidene]-3,3'-dione 73280-98-5 C16H6Cl2O2S2
    (<i>E</i>)-5,5'-dichloro-[2,2']bi[benzo[<i>b</i>]thiophenylidene]-3,3'-dione
    —— 5-(3,5-Dichlorophenylthio)-1-ethyl-4-isopropyl-1H-imidazol-2-ylmethyl pivaloylcarbamate 196406-00-5 C21H27Cl2N3O3S
    5-(3,5-Dichlorophenylthio)-1-ethyl-4-isopropyl-1H-imidazol-2-ylmethyl pivaloylcarbamate
    —— (3-Chloro-2-phenylsulfanylphenyl)methanol 13421-16-4 C13H11ClOS
    (3-Chloro-2-phenylsulfanylphenyl)methanol
    —— 6,6-ditert-butyl-1,1,3,3-tetramethyl-5-thia-7,8-diazaspiro[3.4]oct-7-ene-2-thione 124992-80-9 C17H30N2S2
    6,6-ditert-butyl-1,1,3,3-tetramethyl-5-thia-7,8-diazaspiro[3.4]oct-7-ene-2-thione
    —— <5-Chloro-2-(2-thienylthio)phenyl>acetic acid thiomorpholide 89011-36-9 C16H16ClNOS3
    <5-Chloro-2-(2-thienylthio)phenyl>acetic acid thiomorpholide
    —— 1,3-dichloro-2,2,4,4-tetramethylcyclobutane-1,3-bis(sulfenyl chloride) 220184-79-2 C8H12Cl4S2
    1,3-dichloro-2,2,4,4-tetramethylcyclobutane-1,3-bis(sulfenyl chloride)
    —— 2-<5-chloro-2-(4-chlorophenylthio)phenyl>acetic acid 13420-71-8 C14H10Cl2O2S
    2-<5-chloro-2-(4-chlorophenylthio)phenyl>acetic acid
    —— 2-Chloro-2-(2-thienylthio)phenylglyoxylic acid thiomorpholide 89011-35-8 C16H14ClNO2S3
    2-Chloro-2-(2-thienylthio)phenylglyoxylic acid thiomorpholide
    —— 5-Chloro-2-(2-thienylthio)benzoic acid 13125-02-5 C11H7ClO2S2
    5-Chloro-2-(2-thienylthio)benzoic acid
    —— 2-(n-butylsulfanyl)-6-ethoxypyrimidin-4-amine 1228954-58-2 C10H17N3OS
    2-(n-butylsulfanyl)-6-ethoxypyrimidin-4-amine
    —— 2-amino-4-(2-(p-chlorophenylthio)-6-methylquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile 1376342-33-4 C26H18ClN3O3S
    2-amino-4-(2-(p-chlorophenylthio)-6-methylquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile
    —— 1-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)-1-phenylthiobutane 92405-65-7 C16H18O3S
    1-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)-1-phenylthiobutane
    —— 6-(4-trifluoromethoxy-phenylsulfanyl)-nicotinic acid methyl ester 911697-17-1 C14H10F3NO3S
    6-(4-trifluoromethoxy-phenylsulfanyl)-nicotinic acid methyl ester
    —— Ethyl 2-oxo-4,4-bis(phenylsulfanyl)but-3-enoate 105633-47-4 C18H16O3S2
    Ethyl 2-oxo-4,4-bis(phenylsulfanyl)but-3-enoate
    —— 2-Amino-4-(2-(p-methylphenylthio)-6-methoxyquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile 1376342-42-5 C27H21N3O4S
    2-Amino-4-(2-(p-methylphenylthio)-6-methoxyquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile
    —— 2-amino-4-(2-(p-chlorophenylthio)-6-methoxyquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile 1376342-35-6 C26H18ClN3O4S
    2-amino-4-(2-(p-chlorophenylthio)-6-methoxyquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile
    —— 6-Methoxy-2-p-tolylsulfanyl-quinoline-3-carbaldehyde 1376342-19-6 C18H15NO2S
    6-Methoxy-2-p-tolylsulfanyl-quinoline-3-carbaldehyde
    —— 1-(4-Hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)-1-phenylthioethane 82420-08-4 C14H14O3S
    1-(4-Hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)-1-phenylthioethane
    —— 2-(4-Chlorophenyl)sulfanyl-6-methoxyquinoline-3-carbaldehyde 433694-74-7 C17H12ClNO2S
    2-(4-Chlorophenyl)sulfanyl-6-methoxyquinoline-3-carbaldehyde
    —— 2-amino-4-(2-(phenylthio)-6-methoxyquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile 1376342-27-6 C26H19N3O4S
    2-amino-4-(2-(phenylthio)-6-methoxyquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile
    —— 2-amino-4-(2-(p-methylphenylthio)-6-methylquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile 1376342-40-3 C27H21N3O3S
    2-amino-4-(2-(p-methylphenylthio)-6-methylquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile
    —— 2-amino-4-(2-(phenylthio)-6-methylquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile 1376342-24-3 C26H19N3O3S
    2-amino-4-(2-(phenylthio)-6-methylquinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile
    —— S-isobutyl methanesulfonothioate 52017-47-7 C5H12O2S2
    S-isobutyl methanesulfonothioate
    —— 1-(2-(methylthio)benzyl)-4-hydroxy-6-methylpyridin-2(1H)-one 945994-87-6 C14H15NO2S
    1-(2-(methylthio)benzyl)-4-hydroxy-6-methylpyridin-2(1H)-one
    —— 1-(2-fluoro-5-(trifluoromethyl)phenyl)-3-(4-(2-oxo-2,3-dihydro-1H-imidazo[4,5-b]pyridin-7-ylthio)phenyl)urea 1147504-52-6 C20H13F4N5O2S
    1-(2-fluoro-5-(trifluoromethyl)phenyl)-3-(4-(2-oxo-2,3-dihydro-1H-imidazo[4,5-b]pyridin-7-ylthio)phenyl)urea
    —— (S)-tert-butyl 1-amino-1-thioxopent-4-yn-2-ylcarbamate 1548865-13-9 C10H16N2O2S
    (S)-tert-butyl 1-amino-1-thioxopent-4-yn-2-ylcarbamate
    —— 3-(2-Methylprop-2-enylsulfanyl)propan-1-ol 147101-92-6 C7H14OS
    3-(2-Methylprop-2-enylsulfanyl)propan-1-ol
    —— 6-(cyclohexylmethoxy)-2-N-(4-methylsulfanylphenyl)pyrimidine-2,4-diamine 651734-03-1 C18H24N4OS
    6-(cyclohexylmethoxy)-2-N-(4-methylsulfanylphenyl)pyrimidine-2,4-diamine
    —— 2-ethylhexyl 3-((2-(((2S)-2-acetamidopropyl)oxy)-5-aminopyridin-4-yl)sulfanyl)propanoate 1431534-14-3 C21H35N3O4S
    2-ethylhexyl 3-((2-(((2S)-2-acetamidopropyl)oxy)-5-aminopyridin-4-yl)sulfanyl)propanoate
    —— Tetrathioxalat 78906-82-8 C2S4
    Tetrathioxalat
    —— Bis(1,1,2-tris-methylthio)-vinylsulfid 82766-69-6 C10H18S7
    Bis(1,1,2-tris-methylthio)-vinylsulfid
    —— 2-[4-(methylthio)-1,3-dithiol-2-ylidene]-5H-1,3-dithiolo[4,5-c]pyrrole 848153-08-2 C9H7NS5
    2-[4-(methylthio)-1,3-dithiol-2-ylidene]-5H-1,3-dithiolo[4,5-c]pyrrole
    —— 2,4-Bis(phenylmercapto)-1-nitrobenzol 62049-82-5 C18H13NO2S2
    2,4-Bis(phenylmercapto)-1-nitrobenzol
    —— 2-hydroxyethyl n-butyl sulfone 21975-09-7 C6H14O3S
    2-hydroxyethyl n-butyl sulfone
    —— 6,7-bis(thiophenyl)-2,3-dicyanonaphthalene 126750-55-8 C24H14N2S2
    6,7-bis(thiophenyl)-2,3-dicyanonaphthalene
    —— methyl 4-{[4-({[3-(2,6-dichlorophenyl)-5-(1-methylethyl)-4-isoxazolyl]methyl}oxy)phenyl]thio}-1-benzothiophene-2-carboxylate 1093632-04-2 C29H23Cl2NO4S2
    methyl 4-{[4-({[3-(2,6-dichlorophenyl)-5-(1-methylethyl)-4-isoxazolyl]methyl}oxy)phenyl]thio}-1-benzothiophene-2-carboxylate
    —— tert-butyl N-tert-butoxycarbonyl-N-(6-chloro-2-methylsulfanylpyrimidin-4-yl)carbamate 1052714-60-9 C15H22ClN3O4S
    tert-butyl N-tert-butoxycarbonyl-N-(6-chloro-2-methylsulfanylpyrimidin-4-yl)carbamate
    —— tert-butyl N-[6-chloro-2-(methylsulfanyl)pyrimidin-4-yl]carbamate 309256-03-9 C10H14ClN3O2S
    tert-butyl N-[6-chloro-2-(methylsulfanyl)pyrimidin-4-yl]carbamate
    —— 1-[(2-Bromoethyl)sulfonyl]butane 82811-10-7 C6H13BrO2S
    1-[(2-Bromoethyl)sulfonyl]butane
    —— methyl 4-[(4-hydroxyphenyl)thio]-1-benzothiophene-2-carboxylate 1093632-03-1 C16H12O3S2
    methyl 4-[(4-hydroxyphenyl)thio]-1-benzothiophene-2-carboxylate
    —— bromoethyl butyl sulfide 94500-19-3 C6H13BrS
    bromoethyl butyl sulfide
    —— 2-(n-butylsulfinyl) ethanol 17655-54-8 C6H14O2S
    2-(n-butylsulfinyl) ethanol
    —— 4-(3-methyl-1,4-benzoxathiin-2-yl)phenol 935859-03-3 C15H12O2S
    4-(3-methyl-1,4-benzoxathiin-2-yl)phenol