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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-trimethylsilyl-6-phenylthionon-2-en-4-one 82202-00-4 C18H28OSSi
    2-trimethylsilyl-6-phenylthionon-2-en-4-one
    —— 3-((1-Phenylthio)butyl)-2-cyclohexen-1-one 133188-89-3 C16H20OS
    3-((1-Phenylthio)butyl)-2-cyclohexen-1-one
    —— (E)-1-trimethylsilyl-5-phenylthiooct-1-en-3-one 82201-89-6 C17H26OSSi
    (E)-1-trimethylsilyl-5-phenylthiooct-1-en-3-one
    —— 2-((5-chloro-3-cyano-4,6-dimethylpyridin-2-yl)thio)acetic acid 442655-61-0 C10H9ClN2O2S
    2-((5-chloro-3-cyano-4,6-dimethylpyridin-2-yl)thio)acetic acid
    —— methyl 2-(4-oxocyclohexyl)-2-(3,3,3-trifluoropropylsulfonyl)acetate 1097629-98-5 C12H17F3O5S
    methyl 2-(4-oxocyclohexyl)-2-(3,3,3-trifluoropropylsulfonyl)acetate
    —— (S)-2-Methyl-butyl-isothiocyanat 4404-51-7 C6H11NS
    (S)-2-Methyl-butyl-isothiocyanat
    —— N-(methylsulfanylmethyl)acetamide 83442-33-5 C4H9NOS
    N-(methylsulfanylmethyl)acetamide
    —— 2-ethylthio-3-phenylthioquinoline 1416169-29-3 C17H15NS2
    2-ethylthio-3-phenylthioquinoline
    —— 5-<bis(methoxycarbonyl)(phenylthio)methyl>-4-methoxy-6-methyl-2H-pyran-2-one 107468-02-0 C18H18O7S
    5-<bis(methoxycarbonyl)(phenylthio)methyl>-4-methoxy-6-methyl-2H-pyran-2-one
    —— 1-tert-butyl-3-(3-trifluoromethyl-phenylsulfanyl)-1H-pyrazolo[3,4-d]pyrimidin-4-ylamine 1151651-02-3 C16H16F3N5S
    1-tert-butyl-3-(3-trifluoromethyl-phenylsulfanyl)-1H-pyrazolo[3,4-d]pyrimidin-4-ylamine
    —— bis(4-(pyridin-2-yl)pyrimidin-2-yl)sulfane 1184175-29-8 C18H12N6S
    bis(4-(pyridin-2-yl)pyrimidin-2-yl)sulfane
    —— 3-thiophen-2-ylsulfanyl-propionitrile 57713-42-5 C7H7NS2
    3-thiophen-2-ylsulfanyl-propionitrile
    —— Methyl-[3-(5-methylsulfanyl-[1,3,4]thiadiazol-2-yl)-propyl]-amine; hydrochloride 140440-11-5 C7H13N3S2*ClH
    Methyl-[3-(5-methylsulfanyl-[1,3,4]thiadiazol-2-yl)-propyl]-amine; hydrochloride
    —— Dimethylester der 2,6-Bis-aethylendithiobicyclo<3.3.1>-nonan-1,5-dicarbonsaeure 26069-22-7 C17H24O4S4
    Dimethylester der 2,6-Bis-aethylendithiobicyclo<3.3.1>-nonan-1,5-dicarbonsaeure
    —— N-<1-Methoxy-propyl-(2)>-S-methyl-thiolurethan 23850-18-2 C6H13NO2S
    N-<1-Methoxy-propyl-(2)>-S-methyl-thiolurethan
    —— Ethyl 3-(2-amino-5-fluorophenyl)sulfanylpropanoate 1263798-58-8 C11H14FNO2S
    Ethyl 3-(2-amino-5-fluorophenyl)sulfanylpropanoate
    —— butyric acid-[4-(4-nitro-phenylsulfanyl)-anilide] 101480-61-9 C16H16N2O3S
    butyric acid-[4-(4-nitro-phenylsulfanyl)-anilide]
    —— N-(1-Chlor-2-propyl)-thiokohlensaeureamid-S-methylester 17643-66-2 C5H10ClNOS
    N-(1-Chlor-2-propyl)-thiokohlensaeureamid-S-methylester
    —— (4R)-4-[[tert-butyl(dimethyl)silyl]oxymethyl]-4-methyl-3-(2-phenylsulfanylethyl)cyclohex-2-en-1-one 331627-34-0 C22H34O2SSi
    (4R)-4-[[tert-butyl(dimethyl)silyl]oxymethyl]-4-methyl-3-(2-phenylsulfanylethyl)cyclohex-2-en-1-one
    —— Ethyl 3-(2-amino-3-chlorophenyl)sulfanylpropanoate 1263798-51-1 C11H14ClNO2S
    Ethyl 3-(2-amino-3-chlorophenyl)sulfanylpropanoate
    —— [5-[[5-(6-Methyl-2-methylsulfanylpyrimidin-4-yl)-1,3-thiazol-2-yl]amino]pyrazin-2-yl]methanol 874476-62-7 C14H14N6OS2
    [5-[[5-(6-Methyl-2-methylsulfanylpyrimidin-4-yl)-1,3-thiazol-2-yl]amino]pyrazin-2-yl]methanol
    —— 3-(2-Amino-5-fluorophenyl)sulfanylpropanenitrile 1263798-34-0 C9H9FN2S
    3-(2-Amino-5-fluorophenyl)sulfanylpropanenitrile
    —— (17R)-17-methyl-16-oxa-1,5-dithiaspiro[5.12]octadecan-15-one 206124-26-7 C16H28O2S2
    (17R)-17-methyl-16-oxa-1,5-dithiaspiro[5.12]octadecan-15-one
    —— (R)-3-methyl-4-(phenylthio)-2-butanone 102710-81-6 C11H14OS
    (R)-3-methyl-4-(phenylthio)-2-butanone
    —— N-[5-[[tert-butyl(dimethyl)silyl]oxymethyl]pyrazin-2-yl]-5-(6-methyl-2-methylsulfanylpyrimidin-4-yl)-1,3-thiazol-2-amine 874476-63-8 C20H28N6OS2Si
    N-[5-[[tert-butyl(dimethyl)silyl]oxymethyl]pyrazin-2-yl]-5-(6-methyl-2-methylsulfanylpyrimidin-4-yl)-1,3-thiazol-2-amine
    —— α-Methoxy-β-chlorethylisopropylsulfid 51757-78-9 C6H13ClOS
    α-Methoxy-β-chlorethylisopropylsulfid
    —— tert-butyl-[(E)-2,2-dimethyl-4-phenylsulfanylbut-3-enoxy]-dimethylsilane 1026847-70-0 C18H30OSSi
    tert-butyl-[(E)-2,2-dimethyl-4-phenylsulfanylbut-3-enoxy]-dimethylsilane
    —— 2-Diethoxyphosphoryl-2-phenylsulfanylacetic acid 109632-33-9 C12H17O5PS
    2-Diethoxyphosphoryl-2-phenylsulfanylacetic acid
    —— (17S)-17-methyl-16-oxa-1,5-dithiaspiro[5.12]octadecan-15-one 206124-22-3 C16H28O2S2
    (17S)-17-methyl-16-oxa-1,5-dithiaspiro[5.12]octadecan-15-one
    —— 4-Chloro-2-methylsulfanyl-6-(propan-2-ylamino)pyrimidine-5-carbonitrile 169473-37-4 C9H11ClN4S
    4-Chloro-2-methylsulfanyl-6-(propan-2-ylamino)pyrimidine-5-carbonitrile
    —— E-pent-1-en-1-yl phenyl sulphide 75924-75-3 C11H14S
    E-pent-1-en-1-yl phenyl sulphide
    —— Phosphonic acid, [(phenylthio)(trimethylsilyl)methyl]-, diethyl ester 87762-56-9 C14H25O3PSSi
    Phosphonic acid, [(phenylthio)(trimethylsilyl)methyl]-, diethyl ester
    —— (1-Phenylthio-3-butinyl)phosphonsaeure-diethylester 108298-17-5 C14H19O3PS
    (1-Phenylthio-3-butinyl)phosphonsaeure-diethylester
    —— 2-(1-phenylthio-4-pentenyl)-4,7-dihydro-[1,3,2]dioxaphosphepine-2-oxide 870193-88-7 C15H19O3PS
    2-(1-phenylthio-4-pentenyl)-4,7-dihydro-[1,3,2]dioxaphosphepine-2-oxide
    —— [(phenylsulfanyl)methyl]phosphonothioic acid O,S-diethyl ester 596107-34-5 C11H17O2PS2
    [(phenylsulfanyl)methyl]phosphonothioic acid O,S-diethyl ester
    —— diethyl α,α-difluoro-α-(phenylthio)methylphosphonate 197356-91-5 C11H15F2O3PS
    diethyl α,α-difluoro-α-(phenylthio)methylphosphonate
    —— 7-Methylthio-3-phenyl-thiazolo<4,5-d>pyrimidin-2-thion 130089-93-9 C12H9N3S3
    7-Methylthio-3-phenyl-thiazolo<4,5-d>pyrimidin-2-thion
    —— propionic acid-[4-(4-nitro-phenylsulfanyl)-anilide] 101480-60-8 C15H14N2O3S
    propionic acid-[4-(4-nitro-phenylsulfanyl)-anilide]
    —— 7,9,10-trimethoxy-indolo[2,3-b][1,4]benzothiazepine 1263431-19-1 C18H16N2O3S
    7,9,10-trimethoxy-indolo[2,3-b][1,4]benzothiazepine
    —— 4,7-dimethyl-2-methylamino-4H-pyridazino<4,5-e><1,3,4>thiadiazin-8(7H)-one 96988-28-2 C8H11N5OS
    4,7-dimethyl-2-methylamino-4H-pyridazino<4,5-e><1,3,4>thiadiazin-8(7H)-one
    —— 3-(4-methoxyphenylthio)-4-(3,4,5-trimethoxyphenyl)cyclobut-3-ene-1,2-dione 1257127-59-5 C20H18O6S
    3-(4-methoxyphenylthio)-4-(3,4,5-trimethoxyphenyl)cyclobut-3-ene-1,2-dione
    —— 6-amino-3-methylthio-1,2,4-triazin-5(2H)-one 89730-56-3 C4H6N4OS
    6-amino-3-methylthio-1,2,4-triazin-5(2H)-one
    —— 3-methylsulfanyl-N-phenyl-[1,3]thiazolo[5,4-e][1,2,4]triazin-6-amine 112394-35-1 C11H9N5S2
    3-methylsulfanyl-N-phenyl-[1,3]thiazolo[5,4-e][1,2,4]triazin-6-amine
    —— 3-Benzylamino-1,6-dimethyl-1H,6H-pyridazino[4,5-e][1,3,4]thiadiazin-5-one 96988-30-6 C14H15N5OS
    3-Benzylamino-1,6-dimethyl-1H,6H-pyridazino[4,5-e][1,3,4]thiadiazin-5-one
    —— 1,6-dimethyl-3-phenylimino-2H-pyridazino[4,5-e][1,3,4]thiadiazin-5-one 96988-29-3 C13H13N5OS
    1,6-dimethyl-3-phenylimino-2H-pyridazino[4,5-e][1,3,4]thiadiazin-5-one
    —— allyl 1,3-dimethyl-2-oxo-4-(phenylthio)cyclohex-3-ene-1-carboxylate 1101867-99-5 C18H20O3S
    allyl 1,3-dimethyl-2-oxo-4-(phenylthio)cyclohex-3-ene-1-carboxylate
    —— (+/-)-5-[2-chloro-4-(3-trifluoromethylphenylthio)phenyl]-2-ethoxycarbonyl-2-methylpentanoic acid 1006727-21-4 C22H22ClF3O4S
    (+/-)-5-[2-chloro-4-(3-trifluoromethylphenylthio)phenyl]-2-ethoxycarbonyl-2-methylpentanoic acid
    —— 1-(2-{[2-(1H-1,2,4-triazol-3-ylthio)ethyl]oxy}pyridin-4-yl)methanamine hydrochloride 935760-12-6 C10H13N5OS*ClH
    1-(2-{[2-(1H-1,2,4-triazol-3-ylthio)ethyl]oxy}pyridin-4-yl)methanamine hydrochloride
    —— (6R)-2,6-dimethyl-3-phenylsulfanyl-6-prop-2-enylcyclohex-2-en-1-one 1101868-07-8 C17H20OS
    (6R)-2,6-dimethyl-3-phenylsulfanyl-6-prop-2-enylcyclohex-2-en-1-one
    —— 1-phenyl-5,5-bis(phenylthio)-3-pentanol 332188-26-8 C23H24OS2
    1-phenyl-5,5-bis(phenylthio)-3-pentanol