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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— cis-N-(2-phenylthio-1-methylvinyl)methylurethane 85212-37-9 C11H13NO2S
    cis-N-(2-phenylthio-1-methylvinyl)methylurethane
    —— 1-t-Butoxycarbonyl-4-((2-bromophenyl)thio)methyl-1,2,5,6-tetrahydropyridine 159635-24-2 C17H22BrNO2S
    1-t-Butoxycarbonyl-4-((2-bromophenyl)thio)methyl-1,2,5,6-tetrahydropyridine
    —— trans-N-(2-phenylthio-1-methylvinyl)methylurethane 85212-38-0 C11H13NO2S
    trans-N-(2-phenylthio-1-methylvinyl)methylurethane
    —— N-n-Butyl-N'-(2-mercaptoethyl)-thioharnstoff 89851-15-0 C7H16N2S2
    N-n-Butyl-N'-(2-mercaptoethyl)-thioharnstoff
    —— 2-Amino-2-methylethanthiol-hydrochlorid 4145-98-6 C3H9NS*ClH
    2-Amino-2-methylethanthiol-hydrochlorid
    —— N,N-diisopropyl-6-(phenylthio)-1-cyclohexenecarboxamide 80997-44-0 C19H27NOS
    N,N-diisopropyl-6-(phenylthio)-1-cyclohexenecarboxamide
    —— 2-[4-methyl-3-(methylsulfanyl)phenyl]-1,3-dioxolane 315188-39-7 C11H14O2S
    2-[4-methyl-3-(methylsulfanyl)phenyl]-1,3-dioxolane
    —— Bis-(2-amino-propyl)-disulfid 4390-09-4 C6H16N2S2
    Bis-(2-amino-propyl)-disulfid
    —— [1-benzyl-3-(2-nitro-phenylsulfanyl)-1H-indol-6-yl]-methyl-carbamic acid tert-butyl ester 868673-20-5 C27H27N3O4S
    [1-benzyl-3-(2-nitro-phenylsulfanyl)-1H-indol-6-yl]-methyl-carbamic acid tert-butyl ester
    —— [1-(2-fluoro-benzyl)-3-(2-nitro-phenylsulfanyl)-1H-indol-6-yl]-methyl-carbamic acid tert-butyl ester 868673-21-6 C27H26FN3O4S
    [1-(2-fluoro-benzyl)-3-(2-nitro-phenylsulfanyl)-1H-indol-6-yl]-methyl-carbamic acid tert-butyl ester
    —— 1-[5-(methylthio)thiophen-2-yl]ethanone 22102-48-3 C7H8OS2
    1-[5-(methylthio)thiophen-2-yl]ethanone
    —— 2-(ethylthio)-5-methylthiophene 6522-11-8 C7H10S2
    2-(ethylthio)-5-methylthiophene
    —— (5-methylsulfanyl-thiophen-2-yl)-oxo-acetic acid ethyl ester 731017-53-1 C9H10O3S2
    (5-methylsulfanyl-thiophen-2-yl)-oxo-acetic acid ethyl ester
    —— 5-(methylthio)-2-thiophenesulfonamide 142294-53-9 C5H7NO2S3
    5-(methylthio)-2-thiophenesulfonamide
    —— (3-methylsulfanyl-thiophen-2-yl)-oxo-acetic acid ethyl ester 731017-54-2 C9H10O3S2
    (3-methylsulfanyl-thiophen-2-yl)-oxo-acetic acid ethyl ester
    —— thiocarbamic acid <i>S</i>-thiophen-2-yl ester 60830-65-1 C5H5NOS2
    thiocarbamic acid <i>S</i>-thiophen-2-yl ester
    —— 4-(4-aminophenyl)sulfanyl-N-[(1S)-1-cyclohexylethyl]-3-[(7-propan-2-ylpyrido[2,3-d]pyrimidin-4-yl)amino]benzamide 943779-36-0 C31H36N6OS
    4-(4-aminophenyl)sulfanyl-N-[(1S)-1-cyclohexylethyl]-3-[(7-propan-2-ylpyrido[2,3-d]pyrimidin-4-yl)amino]benzamide
    —— 4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(4-pyridyl)ethyl]benzamide 943779-32-6 C30H29N7OS
    4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(4-pyridyl)ethyl]benzamide
    —— 4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(2-pyridyl)ethyl]benzamide 943779-28-0 C30H29N7OS
    4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(2-pyridyl)ethyl]benzamide
    —— 4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(3-pyridyl)ethyl]benzamide 943779-30-4 C30H29N7OS
    4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(3-pyridyl)ethyl]benzamide
    —— (+/-)-ethyl 2-[4-[(2-chlorophenylthio)methyl]phenyl]-2-bromoacetate 1268473-48-8 C17H16BrClO2S
    (+/-)-ethyl 2-[4-[(2-chlorophenylthio)methyl]phenyl]-2-bromoacetate
    —— 2-[4,5-bis(pentylthio)-1,3-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole 300766-21-6 C18H25NS6
    2-[4,5-bis(pentylthio)-1,3-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole
    —— 2-Amino-4-(3-methyl-pyrazol-1-yl)-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile 357289-36-2 C16H15N7S
    2-Amino-4-(3-methyl-pyrazol-1-yl)-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile
    —— 2-Amino-4-(4-methyl-pyrazol-1-yl)-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile 357289-33-9 C16H15N7S
    2-Amino-4-(4-methyl-pyrazol-1-yl)-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile
    —— 3,6-bis(2,6-dimethylphenylthio)phthalonitrile 1519102-86-3 C24H20N2S2
    3,6-bis(2,6-dimethylphenylthio)phthalonitrile
    —— 4-Furan-2-yl-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidin-2-yl-amine 357288-38-1 C15H14N4OS
    4-Furan-2-yl-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidin-2-yl-amine
    —— 2-Amino-4-(5-cyano-furan-2-yl)-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile 357289-57-7 C17H12N6OS
    2-Amino-4-(5-cyano-furan-2-yl)-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile
    —— 2-Amino-4-pyridin-2-yl-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile 357284-55-0 C17H14N6S
    2-Amino-4-pyridin-2-yl-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile
    —— 2,4,6,8-tetramethylcyclotetrasiloxane-2,4,6,8-tetraethanethiol 607388-75-0 C12H32O4S4Si4
    2,4,6,8-tetramethylcyclotetrasiloxane-2,4,6,8-tetraethanethiol
    —— 3-phenylthiobenzo<c>thiophene-1(3H)-one 159528-42-4 C14H10OS2
    3-phenylthiobenzo<c>thiophene-1(3H)-one
    —— tert-butyl-[(3S)-4-[2-[(E)-5-(furan-3-yl)-2-methylpent-2-enyl]-1,3-dithian-2-yl]-3-methylbutoxy]-dimethylsilane 1351446-09-7 C25H44O2S2Si
    tert-butyl-[(3S)-4-[2-[(E)-5-(furan-3-yl)-2-methylpent-2-enyl]-1,3-dithian-2-yl]-3-methylbutoxy]-dimethylsilane
    —— (3S)-4-[2-[(E)-5-(furan-3-yl)-2-methylpent-2-enyl]-1,3-dithian-2-yl]-3-methylbutanal 1351446-11-1 C19H28O2S2
    (3S)-4-[2-[(E)-5-(furan-3-yl)-2-methylpent-2-enyl]-1,3-dithian-2-yl]-3-methylbutanal
    —— 2-ethylthio-3-benzyl-5-fluoropyrimidin-4-one 81560-07-8 C13H13FN2OS
    2-ethylthio-3-benzyl-5-fluoropyrimidin-4-one
    —— 2-ethylthio-5-fluoropyrimidine 6090-39-7 C6H7FN2S
    2-ethylthio-5-fluoropyrimidine
    —— 1-benzyl-2-ethylthio-5-fluoropyrimidin-4-one 81560-04-5 C13H13FN2OS
    1-benzyl-2-ethylthio-5-fluoropyrimidin-4-one
    —— 2-ethylthio-4-benzyloxy-5-fluoropyrimidine 81560-10-3 C13H13FN2OS
    2-ethylthio-4-benzyloxy-5-fluoropyrimidine
    —— 2-methyl-2-<3'(1,3-dithiolanyl)butyl>thiazolidine 156000-10-1 C10H19NS3
    2-methyl-2-<3'(1,3-dithiolanyl)butyl>thiazolidine
    —— 2,2,10,10,-Tetramethyl-6-thiaundeca-3,8-diin 56147-05-8 C14H22S
    2,2,10,10,-Tetramethyl-6-thiaundeca-3,8-diin
    —— 4,4-dimethyl-1-phenylthio-1,2-pentadiene 88096-96-2 C13H16S
    4,4-dimethyl-1-phenylthio-1,2-pentadiene
    —— 2-(3'-nitropyridin-2'-ylsulfanyl)ethanamine 1228879-86-4 C7H9N3O2S
    2-(3'-nitropyridin-2'-ylsulfanyl)ethanamine
    —— 2-[2'-(ethylthio)benzyl]pyridine 359015-80-8 C14H15NS
    2-[2'-(ethylthio)benzyl]pyridine
    —— N,N,4-trimethylpent-2-enethioamide 95679-71-3 C8H15NS
    N,N,4-trimethylpent-2-enethioamide
    —— 3-Oxo-2-(phenylsulfanylmethyl)cyclopentane-1-carbaldehyde 127477-62-7 C13H14O2S
    3-Oxo-2-(phenylsulfanylmethyl)cyclopentane-1-carbaldehyde
    —— 4,4-dimethylsulfanyl-2-butanone 77953-59-4 C6H12OS2
    4,4-dimethylsulfanyl-2-butanone
    —— 3-bromo-5-<(ethoxycarbonyl)(phenylthio)methyl>-4-methoxy-6-methyl-2H-pyran-2-one 93338-85-3 C17H17BrO5S
    3-bromo-5-<(ethoxycarbonyl)(phenylthio)methyl>-4-methoxy-6-methyl-2H-pyran-2-one
    —— 2-[α-hydroxy-2-(ethylthio)benzyl]pyridine 359015-65-9 C14H15NOS
    2-[α-hydroxy-2-(ethylthio)benzyl]pyridine
    —— 3-<(phenylthio)methyl>-2-methylenecyclopentan-1-one 96245-48-6 C13H14OS
    3-<(phenylthio)methyl>-2-methylenecyclopentan-1-one
    —— 2-phenylthiomethyl-3-dimethoxymethyl-cyclopentan-1-one 127477-61-6 C15H20O3S
    2-phenylthiomethyl-3-dimethoxymethyl-cyclopentan-1-one
    —— 3-((2-aminoethyl)thio)propan-1-ol 121519-97-9 C5H13NOS
    3-((2-aminoethyl)thio)propan-1-ol
    —— Benzyl-(2,5-dimethyl-phenyl)-sulfid 5023-62-1 C15H16S
    Benzyl-(2,5-dimethyl-phenyl)-sulfid