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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(7(9)<i>H</i>-purin-6-ylmercapto)-benzoic acid 99971-18-3 C12H8N4O2S
    2-(7(9)<i>H</i>-purin-6-ylmercapto)-benzoic acid
    —— 3-(2-aminophenylthio)-4-pyridazinecarbonitrile 135128-11-9 C11H8N4S
    3-(2-aminophenylthio)-4-pyridazinecarbonitrile
    —— 1,2-bis(4-amino-1,2,4-triazol-3-ylsulfanyl)ethane 178384-09-3 C6H10N8S2
    1,2-bis(4-amino-1,2,4-triazol-3-ylsulfanyl)ethane
    —— 2,2'-sulfonylbis<N-(2,2-dimethoxyethyl)acetamide> 132417-38-0 C12H24N2O8S
    2,2'-sulfonylbis<N-(2,2-dimethoxyethyl)acetamide>
    —— 5,5-Bis(ethylthio)-6-(2-methyl-1-propenyliden)-1,4-diphenyl-2,7-dithiabicyclo<2.2.1>heptan-3-on 100094-80-2 C25H26OS4
    5,5-Bis(ethylthio)-6-(2-methyl-1-propenyliden)-1,4-diphenyl-2,7-dithiabicyclo<2.2.1>heptan-3-on
    —— 5,5-Dimethyl-1,4-diphenyl-2,7-dithiabicyclo<2.2.1>heptan-3,6-dion 100094-94-8 C19H16O2S2
    5,5-Dimethyl-1,4-diphenyl-2,7-dithiabicyclo<2.2.1>heptan-3,6-dion
    —— 8-(Aminomethyl)10H-pyrazino[2,3-b][1,4]benzothiazine 203656-60-4 C11H10N4S
    8-(Aminomethyl)10H-pyrazino[2,3-b][1,4]benzothiazine
    —— 2-(6,6-Dimethyl-3-oxo-1,4-diphenyl-2,7-dithiabicyclo<2.2.1>hept-5-yliden)acetaldehyd 100094-90-4 C21H18O2S2
    2-(6,6-Dimethyl-3-oxo-1,4-diphenyl-2,7-dithiabicyclo<2.2.1>hept-5-yliden)acetaldehyd
    —— 5-<2,2-Bis(ethylthio)vinyliden>-6,6-dimethyl-1,4-diphenyl-2,7-dithiabicyclo<2.2.1>heptan-3-on 100094-81-3 C25H26OS4
    5-<2,2-Bis(ethylthio)vinyliden>-6,6-dimethyl-1,4-diphenyl-2,7-dithiabicyclo<2.2.1>heptan-3-on
    —— 6,6-Dimethyl-1,4-diphenyl-2,7-dithiabicyclo<2.2.1>heptan-3,5-dion 100094-95-9 C19H16O2S2
    6,6-Dimethyl-1,4-diphenyl-2,7-dithiabicyclo<2.2.1>heptan-3,5-dion
    —— 1-[3-(4-[2-(2,2,2-trifluoroethyl)guanidino]pyrimid-2-ylthio)propylamino]-1-methylamino-2-nitroethylene 79651-55-1 C13H19F3N8O2S
    1-[3-(4-[2-(2,2,2-trifluoroethyl)guanidino]pyrimid-2-ylthio)propylamino]-1-methylamino-2-nitroethylene
    —— 2-ethoxycarbonylmethylmercapto-3-cyano-5-nitropyridine 31309-26-9 C10H9N3O4S
    2-ethoxycarbonylmethylmercapto-3-cyano-5-nitropyridine
    —— tris(2-(methylthiocarbonylamino)ethyl)amine 183864-14-4 C12H24N4O3S3
    tris(2-(methylthiocarbonylamino)ethyl)amine
    —— diethyl 2-(1H-1,2,4-triazol-5-ylsulfanyl)propanedioate 61631-36-5 C9H13N3O4S
    diethyl 2-(1H-1,2,4-triazol-5-ylsulfanyl)propanedioate
    —— 3-methyl-N-(2-(methylsulfanyl)-5,6-dihydro-4H-furo[2,3-b]pyridin-7-yl)but-3-enamide 438044-93-0 C13H17NO2S
    3-methyl-N-(2-(methylsulfanyl)-5,6-dihydro-4H-furo[2,3-b]pyridin-7-yl)but-3-enamide
    —— 5-formyl-3-methyl-6-phenylthiouracil 69139-09-9 C12H10N2O3S
    5-formyl-3-methyl-6-phenylthiouracil
    —— (1R,3aR,7aR)-1-[(2R,3E,5E)-6-tert-butylsulfonylhexa-3,5-dien-2-yl]-7a-methyl-2,3,3a,5,6,7-hexahydro-1H-inden-4-one 300344-98-3 C20H32O3S
    (1R,3aR,7aR)-1-[(2R,3E,5E)-6-tert-butylsulfonylhexa-3,5-dien-2-yl]-7a-methyl-2,3,3a,5,6,7-hexahydro-1H-inden-4-one
    —— phenyl bis(dimethylamino)methylenecarbamodithioate 1564286-43-6 C12H17N3S2
    phenyl bis(dimethylamino)methylenecarbamodithioate
    —— Propanoic acid, 3-(octylsulfonyl)- 125534-36-3 C11H22O4S
    Propanoic acid, 3-(octylsulfonyl)-
    —— 5-(Diisopropylamino)-3-(4-nitrophenyl)-4-(phenylthio)isoxazol 125379-83-1 C21H23N3O3S
    5-(Diisopropylamino)-3-(4-nitrophenyl)-4-(phenylthio)isoxazol
    —— (phenyl-[1,3,4]oxadiazol-2-ylmercapto)-acetic acid ethyl ester 104496-93-7 C12H12N2O3S
    (phenyl-[1,3,4]oxadiazol-2-ylmercapto)-acetic acid ethyl ester
    —— N-benzyl-6-chloro-2-methylthiopyrimidin-4-amine 709639-84-9 C12H12ClN3S
    N-benzyl-6-chloro-2-methylthiopyrimidin-4-amine
    —— ethyl (E)-2-(2-oxobenzo[b]thiophen-3(2H)-ylidene)acetate 1344679-62-4 C12H10O3S
    ethyl (E)-2-(2-oxobenzo[b]thiophen-3(2H)-ylidene)acetate
    —— N,N'-Dimethyl-N,N'-diethylthiomethyl-ethylendiamin 51-76-3 C10H24N2S2
    N,N'-Dimethyl-N,N'-diethylthiomethyl-ethylendiamin
    —— 3-(Diethylamino)thiete 1,1-dioxide 59514-12-4 C7H13NO2S
    3-(Diethylamino)thiete 1,1-dioxide
    —— methyl 2-cyano-3-(5-phenylthio-2-furyl)acrylate 56656-71-4 C15H11NO3S
    methyl 2-cyano-3-(5-phenylthio-2-furyl)acrylate
    —— 2-phenyl-2-[6-(phenylthio)pyridazin-3-yl]acetonitrile 209412-02-2 C18H13N3S
    2-phenyl-2-[6-(phenylthio)pyridazin-3-yl]acetonitrile
    —— 3,4-dihydro-2H-pyrimido[1,2-c]pyrido[4,3-e][1,3]thiazine-6-thione 1202519-01-4 C10H9N3S2
    3,4-dihydro-2H-pyrimido[1,2-c]pyrido[4,3-e][1,3]thiazine-6-thione
    —— N-benzyl-2-oxo-5-(4-propan-2-ylphenyl)sulfanyl-1H-pyridine-3-carboxamide 1426959-64-9 C22H22N2O2S
    N-benzyl-2-oxo-5-(4-propan-2-ylphenyl)sulfanyl-1H-pyridine-3-carboxamide
    —— 2-[6-(ethylthio)pyridazin-3-yl]-2-phenylacetonitrile 1159497-77-4 C14H13N3S
    2-[6-(ethylthio)pyridazin-3-yl]-2-phenylacetonitrile
    —— 2-(ω-morpholinohexylthio)-4,6-dimethylpyrimidine 90094-36-3 C16H27N3OS
    2-(ω-morpholinohexylthio)-4,6-dimethylpyrimidine
    —— 2-(ω-anilinohexylthio)-4,6-dimethylpyrimidine 90094-34-1 C18H25N3S
    2-(ω-anilinohexylthio)-4,6-dimethylpyrimidine
    —— <(4,6-dimethylpyrimidin-2-ylthio)hexyl>pyridinium bromide 90094-32-9 Br*C17H24N3S
    <(4,6-dimethylpyrimidin-2-ylthio)hexyl>pyridinium bromide
    —— 2-(ω-piperidinohexylthio)-4,6-dimethylpyrimidine 90094-35-2 C17H29N3S
    2-(ω-piperidinohexylthio)-4,6-dimethylpyrimidine
    —— 1-Acetoxy-1-phenylthio-2-butanon 67175-44-4 C12H14O3S
    1-Acetoxy-1-phenylthio-2-butanon
    —— 1,1-Bis(phenylsulfanyl)-2-butanone 77331-08-9 C16H16OS2
    1,1-Bis(phenylsulfanyl)-2-butanone
    —— (Z)-N,N-diethyl-1-methoxy-2-(trifluoromethanesulfonyl)ethenamine 1315550-04-9 C8H14F3NO3S
    (Z)-N,N-diethyl-1-methoxy-2-(trifluoromethanesulfonyl)ethenamine
    —— dimethyl meso-2,3-di(pyrimidin-2-ylthio)butane-1,4-dioate 77586-19-7 C14H14N4O4S2
    dimethyl meso-2,3-di(pyrimidin-2-ylthio)butane-1,4-dioate
    —— 5-ethylsulfanyl-6-methyl-pyrazine-2,3-dicarbonitrile 72112-31-3 C9H8N4S
    5-ethylsulfanyl-6-methyl-pyrazine-2,3-dicarbonitrile
    —— N-<2-(p-tolylthio)ethyl>acetamide 98225-03-7 C11H15NOS
    N-<2-(p-tolylthio)ethyl>acetamide
    —— (4S,4aR)-4,4a-dimethylspiro[1,2,3,4,5,6-hexahydronaphthalene-7,2'-1,3-dithiolane] 150930-70-4 C14H22S2
    (4S,4aR)-4,4a-dimethylspiro[1,2,3,4,5,6-hexahydronaphthalene-7,2'-1,3-dithiolane]
    —— N,N'-dimethyl-N,N'-bis(phenylsulfanylmethyl)ethane-1,2-diamine 214148-69-3 C18H24N2S2
    N,N'-dimethyl-N,N'-bis(phenylsulfanylmethyl)ethane-1,2-diamine
    —— 4-Methylsulfanyl-2-phenyl-[1,3]oxazin-6-one 135714-53-3 C11H9NO2S
    4-Methylsulfanyl-2-phenyl-[1,3]oxazin-6-one
    —— 4-(benzo-1,4-dithiafulven-6-yl)-1,2,3-thiadiazole 1028256-72-5 C10H6N2S3
    4-(benzo-1,4-dithiafulven-6-yl)-1,2,3-thiadiazole
    —— N<sup>1</sup>,N<sup>3</sup>-diphenyl-N<sup>2</sup>,N<sup>4</sup>-bis(6-methyl-3-(methylthio)-5-oxo-4,5-dihydro-1,2,4-triazin-4-yl)-N<sup>5</sup>-methylbiguanide 118458-63-2 C25H27N11O2S2
    N<sup>1</sup>,N<sup>3</sup>-diphenyl-N<sup>2</sup>,N<sup>4</sup>-bis(6-methyl-3-(methylthio)-5-oxo-4,5-dihydro-1,2,4-triazin-4-yl)-N<sup>5</sup>-methylbiguanide
    —— 2-Azathianthrene 2-oxide 106835-12-5 C11H7NOS2
    2-Azathianthrene 2-oxide
    —— 1-morpholino-2-(phenylthio)ethanone 425608-06-6 C12H15NO2S
    1-morpholino-2-(phenylthio)ethanone
    —— 1,7-diazathianthrene 113372-47-7 C10H6N2S2
    1,7-diazathianthrene
    —— 1,8-diazathianthrene 113372-48-8 C10H6N2S2
    1,8-diazathianthrene
    —— 2-Azathianthrene 106835-13-6 C11H7NS2
    2-Azathianthrene