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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— bis-(4-hydroxy-3-methyl-5-t-butylphenyl) sulphide radical 40190-57-6 C22H29O2S
    bis-(4-hydroxy-3-methyl-5-t-butylphenyl) sulphide radical
    —— sec-butyl tert-butyl sulfoxide 13153-07-6 C8H18OS
    sec-butyl tert-butyl sulfoxide
    —— 2,3-dimethylphenyl ethyl xanthate 89816-80-8 C11H14OS2
    2,3-dimethylphenyl ethyl xanthate
    —— 4,8-Di-tert-butyl-2,10-dimethyl-6-phenyl-5,7-dioxa-12-thia-6-phospha-dibenzo[a,d]cyclooctene 95497-31-7 C28H33O2PS
    4,8-Di-tert-butyl-2,10-dimethyl-6-phenyl-5,7-dioxa-12-thia-6-phospha-dibenzo[a,d]cyclooctene
    —— (Z)-4-Mercapto-3-penten-2-one 73059-87-7 C5H8OS
    (Z)-4-Mercapto-3-penten-2-one
    —— 6-acetyl-2-(4-chlorophenyl)-4-(4-chlorophenylthio)-5-methyl-3(2H)-pyridazinone 259192-42-2 C19H14Cl2N2O2S
    6-acetyl-2-(4-chlorophenyl)-4-(4-chlorophenylthio)-5-methyl-3(2H)-pyridazinone
    —— 3-(phenylthio)-2-butenoic acid 67959-53-9 C10H10O2S
    3-(phenylthio)-2-butenoic acid
    —— 6-nitroso-2,3-dihydro-4H-5-aminothiazole<2,3-a>pyrimidin-7-one 224433-77-6 C6H6N4O2S
    6-nitroso-2,3-dihydro-4H-5-aminothiazole<2,3-a>pyrimidin-7-one
    —— 2-n-butylthio-1-hydroxymethyl-cyclohept-1-ene 119044-23-4 C12H22OS
    2-n-butylthio-1-hydroxymethyl-cyclohept-1-ene
    —— (Z)-8-bromo-3-(phenylthio)-1,3-octadiene 123289-34-9 C14H17BrS
    (Z)-8-bromo-3-(phenylthio)-1,3-octadiene
    —— 2-Propylmercapto-imidazol 17303-07-0 C6H10N2S
    2-Propylmercapto-imidazol
    —— N-(2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)ethyl)acrylamide 1299484-50-6 C19H15F2NOS2
    N-(2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)ethyl)acrylamide
    —— 8-(butylsulfanyl)-1,2,4-benzotriazin-3-amine 1-oxide 494226-33-4 C11H14N4OS
    8-(butylsulfanyl)-1,2,4-benzotriazin-3-amine 1-oxide
    —— 4,5-bis(propylthio)-5'-propylimidazole[4',5'-f]-2,2'-bi-1,3-dithiolylidene 1455499-66-7 C16H22N2S6
    4,5-bis(propylthio)-5'-propylimidazole[4',5'-f]-2,2'-bi-1,3-dithiolylidene
    —— (E)-2-Methyl-3-phenylsulfanyl-but-2-enoic acid ethyl ester 53700-03-1 C13H16O2S
    (E)-2-Methyl-3-phenylsulfanyl-but-2-enoic acid ethyl ester
    —— 3-(phenylthio)-5,6,4a,8a-tetrahydro-2,5,5-trimethylnaphthalene-1,8-(4H,7H)-dione 105090-19-5 C19H22O2S
    3-(phenylthio)-5,6,4a,8a-tetrahydro-2,5,5-trimethylnaphthalene-1,8-(4H,7H)-dione
    —— 1,1-dimethylethyl (4S)-4-[(2R)-2-[(2-cyano-3-thienyl)thio]-2-phenylethyl]-2,2-dimethyl-3-oxazolidinecarboxylate 651353-89-8 C23H28N2O3S2
    1,1-dimethylethyl (4S)-4-[(2R)-2-[(2-cyano-3-thienyl)thio]-2-phenylethyl]-2,2-dimethyl-3-oxazolidinecarboxylate
    —— 2-(4-(2-chloro-4-methylphenyl)thiazol-5-ylthio)acetic acid 871476-83-4 C12H10ClNO2S2
    2-(4-(2-chloro-4-methylphenyl)thiazol-5-ylthio)acetic acid
    —— 4-thiophenoxy<1>benzothieno<2,3-e>pyrrolo<1,2-a>pyrazine 107363-16-6 C19H12N2S2
    4-thiophenoxy<1>benzothieno<2,3-e>pyrrolo<1,2-a>pyrazine
    —— 4-chloro-N-(2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)ethyl)butanamide 1299484-49-3 C20H18ClF2NOS2
    4-chloro-N-(2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)ethyl)butanamide
    —— 2,2-bis(ethylthio)ethylamine 122807-21-0 C6H15NS2
    2,2-bis(ethylthio)ethylamine
    —— 3-(p-methylphenylthio)-2-decalone 83656-91-1 C17H22OS
    3-(p-methylphenylthio)-2-decalone
    —— 1-Ethylthio-3-phenylthiopropan 4911-42-6 C11H16S2
    1-Ethylthio-3-phenylthiopropan
    —— 1-Ethylthio-3-isopropylthio-propan 4911-39-1 C8H18S2
    1-Ethylthio-3-isopropylthio-propan
    —— 1-Ethylthio-3-n-propylthio-propan 4911-38-0 C8H18S2
    1-Ethylthio-3-n-propylthio-propan
    —— (4-phenyl-thiazol-2-ylmercapto)-acetic acid 15208-27-2 C11H9NO2S2
    (4-phenyl-thiazol-2-ylmercapto)-acetic acid
    —— 4,4,5-Trimethyl-4,5-dihydro-[1,2,5]thiadiazin-6-one 113817-46-2 C6H10N2OS
    4,4,5-Trimethyl-4,5-dihydro-[1,2,5]thiadiazin-6-one
    —— 2,2-Dimethyl-6-methylsulfon-capronitril 90950-52-0 C9H17NO2S
    2,2-Dimethyl-6-methylsulfon-capronitril
    —— 2-Chlor-6-phenylthiobenzonitril 38615-62-2 C13H8ClNS
    2-Chlor-6-phenylthiobenzonitril
    —— phenyl N-bis(dimethylamino)methylene-N'-phenylcarbamimidothioate 1564286-31-2 C18H22N4S
    phenyl N-bis(dimethylamino)methylene-N'-phenylcarbamimidothioate
    —— 1-((2-hydroxyethylthio)carbonyloxy)ethyl acetate 928370-73-4 C7H12O5S
    1-((2-hydroxyethylthio)carbonyloxy)ethyl acetate
    —— 3-(6-chloro-2-methyl-1-pyridin-3-yl-1H-indol-3-ylsulfanyl)-phenylboronic acid 1359982-14-1 C20H16BClN2O2S
    3-(6-chloro-2-methyl-1-pyridin-3-yl-1H-indol-3-ylsulfanyl)-phenylboronic acid
    —— 6-(3-Trifluoromethyl-phenylsulfanyl)-pteridine-2,4-diamine 77900-96-0 C13H9F3N6S
    6-(3-Trifluoromethyl-phenylsulfanyl)-pteridine-2,4-diamine
    —— 5-[[3-(trifluoromethyl)phenyl]sulfanyl]pyridin-2-carbonitrile 1454252-66-4 C13H7F3N2S
    5-[[3-(trifluoromethyl)phenyl]sulfanyl]pyridin-2-carbonitrile
    —— 4-((3-(trifluoromethyl)phenyl)thio)picolinonitrile 1374864-80-8 C13H7F3N2S
    4-((3-(trifluoromethyl)phenyl)thio)picolinonitrile
    —— 3-(3-trifluoromethylphenylthio)-5-methyl[1,2,4]triazine 1313039-57-4 C11H8F3N3S
    3-(3-trifluoromethylphenylthio)-5-methyl[1,2,4]triazine
    —— 2-chloro-4-[(3-trifluoromethyl)phenylthio]benzaldehyde 509088-81-7 C14H8ClF3OS
    2-chloro-4-[(3-trifluoromethyl)phenylthio]benzaldehyde
    —— 5-(3-Trifluoromethyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide 63032-30-4 C11H8F3NO2S3
    5-(3-Trifluoromethyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide
    —— 1-ethyl-5-phenylthio-1H-1,2,4-triazole 535961-28-5 C10H11N3S
    1-ethyl-5-phenylthio-1H-1,2,4-triazole
    —— 3-hydroxy-4-cyano-5-phenylthioisothiazole 154845-93-9 C10H6N2OS2
    3-hydroxy-4-cyano-5-phenylthioisothiazole
    —— N-Hexyl-N-methylthiopivalamid 58832-24-9 C12H25NS
    N-Hexyl-N-methylthiopivalamid
    —— N-Athyl-N-methylthiopivalamid 58856-07-8 C8H17NS
    N-Athyl-N-methylthiopivalamid
    —— phenyl 3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-β-ribo-hexopyranoside 241490-67-5 C20H25NO3S
    phenyl 3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-β-ribo-hexopyranoside
    —— α-(phenylthio)-octyl cyanide 112921-77-4 C15H21NS
    α-(phenylthio)-octyl cyanide
    —— N-(2-Hydroxy-3-methylbutyl)-N-methylthiopivalamid 58832-29-4 C11H23NOS
    N-(2-Hydroxy-3-methylbutyl)-N-methylthiopivalamid
    —— 2,4-diamino-5-methyl-6-(3',5'-dimethylphenylthio)pyrrolo[2,3-d]pyrimidine 1221521-88-5 C15H17N5S
    2,4-diamino-5-methyl-6-(3',5'-dimethylphenylthio)pyrrolo[2,3-d]pyrimidine
    —— (3,5-dimethylphenyl)(ethyl)sulfane 1108726-18-6 C10H14S
    (3,5-dimethylphenyl)(ethyl)sulfane
    —— 3-(3,5-dimethylphenylsulfanyl)-propanoic acid 102143-17-9 C11H14O2S
    3-(3,5-dimethylphenylsulfanyl)-propanoic acid
    —— 4-(3,5-dimethylphenylsulfanyl)-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarbonitrile 1185189-90-5 C15H14N2OS
    4-(3,5-dimethylphenylsulfanyl)-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarbonitrile
    —— 4-Chloro-3-(3,5-dimethylphenylthio)-9H-thioxanthen-9-one 1372152-31-2 C21H15ClOS2
    4-Chloro-3-(3,5-dimethylphenylthio)-9H-thioxanthen-9-one