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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— tert.-Butylhydroxyhexylsulfoxid 62295-83-4 C10H22O2S
    tert.-Butylhydroxyhexylsulfoxid
    —— tert.-Butyl-hydroxypropylsulfoxid 40390-75-8 C7H16O2S
    tert.-Butyl-hydroxypropylsulfoxid
    —— [1-(Phenylsulfanylmethyl)cyclobutyl]methanamine 1387575-94-1 C12H17NS
    [1-(Phenylsulfanylmethyl)cyclobutyl]methanamine
    —— [(2R,4S,5R)-4-[(Z)-3-[(2R)-3,3-bis(ethylsulfanyl)oxan-2-yl]prop-2-enyl]-2-phenyl-1,3-dioxan-5-yl]oxy-tert-butyl-dimethylsilane 193970-57-9 C28H46O4S2Si
    [(2R,4S,5R)-4-[(Z)-3-[(2R)-3,3-bis(ethylsulfanyl)oxan-2-yl]prop-2-enyl]-2-phenyl-1,3-dioxan-5-yl]oxy-tert-butyl-dimethylsilane
    —— 6-(4-ethylphenyl)-3-(4-methylsulfanylphenyl)-4-phenylpyran-2-one 742699-43-0 C26H22O2S
    6-(4-ethylphenyl)-3-(4-methylsulfanylphenyl)-4-phenylpyran-2-one
    —— dimethyl 3-<(1,3-dithian-2-methyl-2-yl)methyl>pentanedioate 911801-86-0 C13H22O4S2
    dimethyl 3-<(1,3-dithian-2-methyl-2-yl)methyl>pentanedioate
    —— Methyl N-(carbamoyloxy)thioacetimidate 16960-39-7 C4H8N2O2S
    Methyl N-(carbamoyloxy)thioacetimidate
    —— [(Z)-(2,4-dimethyl-1,3-dithiolan-2-yl)methylideneamino] N-methylcarbamate —— C8H14N2O2S2
    [(Z)-(2,4-dimethyl-1,3-dithiolan-2-yl)methylideneamino] N-methylcarbamate
    —— Bis-<2-trimethylsilyl-aethyl>-sulfon 18001-74-6 C10H26O2SSi2
    Bis-<2-trimethylsilyl-aethyl>-sulfon
    —— Trimethyl[2-methylidene-4,4-bis(phenylsulfanyl)butyl]silane 215182-46-0 C20H26S2Si
    Trimethyl[2-methylidene-4,4-bis(phenylsulfanyl)butyl]silane
    —— 3,3-dimethyl-1,3-thiasilinane 1-oxide 209158-56-5 C6H14OSSi
    3,3-dimethyl-1,3-thiasilinane 1-oxide
    —— 4-[2-[[2-(Dimethylamino)pyrimido[4,5-d]pyrimidin-5-yl]amino]-4-methyl-phenyl]sulfanylphenol 1365922-64-0 C21H20N6OS
    4-[2-[[2-(Dimethylamino)pyrimido[4,5-d]pyrimidin-5-yl]amino]-4-methyl-phenyl]sulfanylphenol
    —— 4-[4-Methyl-2-[(7-propylpyrido[2,3-d]pyrimidin-4-yl)amino]phenyl]sulfanylphenol 944504-13-6 C23H22N4OS
    4-[4-Methyl-2-[(7-propylpyrido[2,3-d]pyrimidin-4-yl)amino]phenyl]sulfanylphenol
    —— 4-[2-[[2-(Ethylamino)pyrimido[4,5-d]pyrimidin-5-yl]amino]-4-methyl-phenyl]sulfanylphenol 1365922-60-6 C21H20N6OS
    4-[2-[[2-(Ethylamino)pyrimido[4,5-d]pyrimidin-5-yl]amino]-4-methyl-phenyl]sulfanylphenol
    —— 4-[2-[(7-Cyclopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-4-methyl-phenyl]sulfanylphenol 944503-98-4 C23H20N4OS
    4-[2-[(7-Cyclopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-4-methyl-phenyl]sulfanylphenol
    —— 4-(2-amino-4-methyl-phenylsulfanyl)-phenol 943614-81-1 C13H13NOS
    4-(2-amino-4-methyl-phenylsulfanyl)-phenol
    —— (7-cyclopropyl-pyrido[2,3-d]pyrimidin-4-yl)-(5-methyl-2-phenylsulfanyl-phenyl)-amine 944503-96-2 C23H20N4S
    (7-cyclopropyl-pyrido[2,3-d]pyrimidin-4-yl)-(5-methyl-2-phenylsulfanyl-phenyl)-amine
    —— 2-(4-Methoxy-phenylsulfanyl)-5-methyl-phenylamine 1097818-27-3 C14H15NOS
    2-(4-Methoxy-phenylsulfanyl)-5-methyl-phenylamine
    —— 7-isopropyl-N-(5-methyl-2-phenylsulfanyl-phenyl)pyrido[2,3-d]pyrimidin-4-amine 1365921-39-6 C23H22N4S
    7-isopropyl-N-(5-methyl-2-phenylsulfanyl-phenyl)pyrido[2,3-d]pyrimidin-4-amine
    —— N-[2-(4-fluorophenyl)sulfanyl-5-methyl-phenyl]-7-isopropyl-pyrido[2,3-d]pyrimidin-4-amine 1365921-60-3 C23H21FN4S
    N-[2-(4-fluorophenyl)sulfanyl-5-methyl-phenyl]-7-isopropyl-pyrido[2,3-d]pyrimidin-4-amine
    —— 4-[2-[(7-Isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-4-methyl-phenyl]sulfanylphenol 944503-77-9 C23H22N4OS
    4-[2-[(7-Isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-4-methyl-phenyl]sulfanylphenol
    —— N-(5-methyl-2-phenylsulfanyl-phenyl)-7-propyl-pyrido[2,3-d]pyrimidin-4-amine 944504-08-9 C23H22N4S
    N-(5-methyl-2-phenylsulfanyl-phenyl)-7-propyl-pyrido[2,3-d]pyrimidin-4-amine
    —— 7-ethyl-N-(5-methyl-2-phenylsulfanyl-phenyl)pyrido[2,3-d]pyrimidin-4-amine 944504-42-1 C22H20N4S
    7-ethyl-N-(5-methyl-2-phenylsulfanyl-phenyl)pyrido[2,3-d]pyrimidin-4-amine
    —— 7-isopropyl-N-[2-(4-methoxyphenyl)sulfanyl-5-methyl-phenyl]pyrido[2,3-d]pyrimidin-4-amine 944503-94-0 C24H24N4OS
    7-isopropyl-N-[2-(4-methoxyphenyl)sulfanyl-5-methyl-phenyl]pyrido[2,3-d]pyrimidin-4-amine
    —— 4-[2-[(7-Ethylpyrido[2,3-d]pyrimidin-4-yl)amino]-4-methyl-phenyl]sulfanylphenol 1365921-19-2 C22H20N4OS
    4-[2-[(7-Ethylpyrido[2,3-d]pyrimidin-4-yl)amino]-4-methyl-phenyl]sulfanylphenol
    —— Trifluor-thioacethydrazid 4454-46-0 C2H3F3N2S
    Trifluor-thioacethydrazid
    —— 2,3-dichloro-7,8-dimethoxy[1,4]benzodithiino[2,3-b]pyridine 245070-05-7 C13H9Cl2NO2S2
    2,3-dichloro-7,8-dimethoxy[1,4]benzodithiino[2,3-b]pyridine
    —— Dithiotropolon 21505-25-9 C7H6S2
    Dithiotropolon
    —— 3-methylthio-1,1-dioxopyrido[4,3-e]-1,4,2-dithiazine 1078159-96-2 C7H6N2O2S3
    3-methylthio-1,1-dioxopyrido[4,3-e]-1,4,2-dithiazine
    —— 4-phenylthiobut-2-yn-1-ol tetrahydropyranyl ether 110284-19-0 C15H18O2S
    4-phenylthiobut-2-yn-1-ol tetrahydropyranyl ether
    —— Phenyl-thiobis(6-t-butyl-4-methyl-o-phenylen)phosphit 30008-05-0 C28H33O3PS
    Phenyl-thiobis(6-t-butyl-4-methyl-o-phenylen)phosphit
    —— Bis-(2,4-dimethoxyphenyl)-sulfid 30090-87-0 C16H18O4S
    Bis-(2,4-dimethoxyphenyl)-sulfid
    —— trans-3-nonen-1-thiol 265655-16-1 C9H18S
    trans-3-nonen-1-thiol
    —— (E)-6'-(4-ethylbenzylidene)-4a'-methyl-4',4a',7',8'-tetrahydro-3'H-spiro[[1,3]dithiolane-2,2'-naphthalen]-5'(6'H)-one 1289642-57-4 C22H26OS2
    (E)-6'-(4-ethylbenzylidene)-4a'-methyl-4',4a',7',8'-tetrahydro-3'H-spiro[[1,3]dithiolane-2,2'-naphthalen]-5'(6'H)-one
    —— magnesium thiocarbonate 65727-88-0 CS3*Mg
    magnesium thiocarbonate
    —— 1-benzyl-5-butyl-3-chloro-6-(4-chlorophenylthio)pyridazin-4(1H)-one 919198-00-8 C21H20Cl2N2OS
    1-benzyl-5-butyl-3-chloro-6-(4-chlorophenylthio)pyridazin-4(1H)-one
    —— methyl 6-(4-dimethylaminophenylsulfanyl)hexanoate 698352-26-0 C15H23NO2S
    methyl 6-(4-dimethylaminophenylsulfanyl)hexanoate
    —— 4,6-dichloro-2-(p-tolylthio)pyrimidine 1394124-22-1 C11H8Cl2N2S
    4,6-dichloro-2-(p-tolylthio)pyrimidine
    —— 4-(7-methoxy-1,5-naphthyridin-4-ylthio)benzenamine 1071539-92-8 C15H13N3OS
    4-(7-methoxy-1,5-naphthyridin-4-ylthio)benzenamine
    —— diallyl α-fluoro-(α-phenylthio)-4-pentenylphosphonate 870193-87-6 C17H22FO3PS
    diallyl α-fluoro-(α-phenylthio)-4-pentenylphosphonate
    —— 2-Phenylthio-4,5-dimethoxyaniline 30058-48-1 C14H15NO2S
    2-Phenylthio-4,5-dimethoxyaniline
    —— 1,3-di(adamantan-2-yl)thiourea 57568-84-0 C21H32N2S
    1,3-di(adamantan-2-yl)thiourea
    —— 3-phenylsulfanyl-2-prop-2-enoxy-4,7-dihydro-3H-1,2lambda5-oxaphosphepine 2-oxide 870193-84-3 C14H17O3PS
    3-phenylsulfanyl-2-prop-2-enoxy-4,7-dihydro-3H-1,2lambda5-oxaphosphepine 2-oxide
    —— 3-({4-[(1-isopropylazetidin-3-yl)oxy]phenyl}thio)-N-(3-methyl-1,2,4-thiadiazol-5-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide 1018966-27-2 C24H26N8O2S3
    3-({4-[(1-isopropylazetidin-3-yl)oxy]phenyl}thio)-N-(3-methyl-1,2,4-thiadiazol-5-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide
    —— diethyl (α-phenylthio)-3-butenylphosphonate 194999-08-1 C14H21O3PS
    diethyl (α-phenylthio)-3-butenylphosphonate
    —— 1-[1-Bis(prop-2-enoxy)phosphorylbut-3-enylsulfanyl]-4-chlorobenzene 870193-92-3 C16H20ClO3PS
    1-[1-Bis(prop-2-enoxy)phosphorylbut-3-enylsulfanyl]-4-chlorobenzene
    —— 3-(4-chlorophenyl)sulfanyl-2-prop-2-enoxy-4,7-dihydro-3H-1,2lambda5-oxaphosphepine 2-oxide 870193-85-4 C14H16ClO3PS
    3-(4-chlorophenyl)sulfanyl-2-prop-2-enoxy-4,7-dihydro-3H-1,2lambda5-oxaphosphepine 2-oxide
    —— diallyl α-fluoro-(α-phenylthio)-3-butenylphosphonate 870193-86-5 C16H20FO3PS
    diallyl α-fluoro-(α-phenylthio)-3-butenylphosphonate
    —— 4-{[(1-propyl-1H-imidazol-5-yl)methyl]sulfanyl}aniline 497853-81-3 C13H17N3S
    4-{[(1-propyl-1H-imidazol-5-yl)methyl]sulfanyl}aniline
    —— diallyl 1-phenylthio-3-butenylphosphonate 870193-91-2 C16H21O3PS
    diallyl 1-phenylthio-3-butenylphosphonate