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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (R)-tert-butyl 3-benzyl-4-(2-(2-cyanophenylthio)benzoyl)piperazine-1-carboxylate 1144508-61-1 C30H31N3O3S
    (R)-tert-butyl 3-benzyl-4-(2-(2-cyanophenylthio)benzoyl)piperazine-1-carboxylate
    —— ethyl (6-hydroxy-2,3-dihydro-1-benzothiophen-3-yl)acetate 1022979-94-7 C12H14O3S
    ethyl (6-hydroxy-2,3-dihydro-1-benzothiophen-3-yl)acetate
    —— 1-methyl-3-methylthio-5-phenyl-1,2,4-triazin-1-ium iodide 35102-16-0 C11H12N3S*I
    1-methyl-3-methylthio-5-phenyl-1,2,4-triazin-1-ium iodide
    —— S-ethyl diisobutylthiocarbamate S,S-dioxide 51892-57-0 C11H23NO3S
    S-ethyl diisobutylthiocarbamate S,S-dioxide
    —— <i>S</i>-heptyl-isothiourea; <i>S</i>-heptyl-isothiuronium-bromide 4270-02-4 BrH*C8H18N2S
    <i>S</i>-heptyl-isothiourea; <i>S</i>-heptyl-isothiuronium-bromide
    —— 1-(4-(5-chloro-2-(phenylthio)phenyl)but-3-ynyl)-4-methylpiperazine 1100794-09-9 C21H23ClN2S
    1-(4-(5-chloro-2-(phenylthio)phenyl)but-3-ynyl)-4-methylpiperazine
    —— S-((2,3-dihydrothieno[3,4-b][1,4]oxathiin-3-yl)-methyl) 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononanethioate 1333236-73-9 C16H11F13O2S3
    S-((2,3-dihydrothieno[3,4-b][1,4]oxathiin-3-yl)-methyl) 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononanethioate
    —— <3>Thienylmercapto-essigsaeure-methylester 1723-32-6 C7H8O2S2
    <3>Thienylmercapto-essigsaeure-methylester
    —— 2-(thiophen-3-ylsulfanyl)phenylamine 23699-18-5 C10H9NS2
    2-(thiophen-3-ylsulfanyl)phenylamine
    —— 3-(butylsulfanyl)thiophene 3988-72-5 C8H12S2
    3-(butylsulfanyl)thiophene
    —— allyl 4,4-difluoro-2-methyl-4-phenylsulfanylbutanoate 776313-44-1 C14H16F2O2S
    allyl 4,4-difluoro-2-methyl-4-phenylsulfanylbutanoate
    —— 4-Isopropylidene-2,2,5,5-tetramethyl-[1,3]oxathiolane 94398-59-1 C10H18OS
    4-Isopropylidene-2,2,5,5-tetramethyl-[1,3]oxathiolane
    —— 3-(2-chlorophenyl)-2-benzylthio-4(3H)-pyrimidinone 89069-57-8 C17H13ClN2OS
    3-(2-chlorophenyl)-2-benzylthio-4(3H)-pyrimidinone
    —— 5-phenylthio-2-furylmethylenepropanedinitrile 56656-64-5 C14H8N2OS
    5-phenylthio-2-furylmethylenepropanedinitrile
    —— 2-{[5-(phenylsulfanyl)furan-2-yl]methyl}propanedinitrile 1432613-99-4 C14H10N2OS
    2-{[5-(phenylsulfanyl)furan-2-yl]methyl}propanedinitrile
    —— 6-but-3-en-1-yl-7-methyl-1,4-dithiaspiro[4.5]dec-6-ene 1292848-64-6 C13H20S2
    6-but-3-en-1-yl-7-methyl-1,4-dithiaspiro[4.5]dec-6-ene
    —— 2-methylthioethoxyamine 101512-32-7 C3H9NOS
    2-methylthioethoxyamine
    —— O-(2-methylsulfinyl)ethylhydroxylamine 504436-71-9 C3H9NO2S
    O-(2-methylsulfinyl)ethylhydroxylamine
    —— 5H-2,4-Dithia-1,3,8-triaza-cyclopenta[a]naphthalene 179334-00-0 C8H5N3S2
    5H-2,4-Dithia-1,3,8-triaza-cyclopenta[a]naphthalene
    —— 4-Methyl-3-(4-methylsulfanyl-[1,2,5]thiadiazol-3-yl)-pyridine 201533-58-6 C9H9N3S2
    4-Methyl-3-(4-methylsulfanyl-[1,2,5]thiadiazol-3-yl)-pyridine
    —— 2-methylthio-3-(2-ethylphenyl)-4(3H)-pyrimidinone 89069-36-3 C13H14N2OS
    2-methylthio-3-(2-ethylphenyl)-4(3H)-pyrimidinone
    —— 6H-Spiro[bicyclo[3.3.1]nonane-2,2'-[1,3]dithiolan]-6-one 27581-54-0 C11H16OS2
    6H-Spiro[bicyclo[3.3.1]nonane-2,2'-[1,3]dithiolan]-6-one
    —— 5-cyano-2-(nitromethylthio)thiophene 126715-75-1 C6H4N2O2S2
    5-cyano-2-(nitromethylthio)thiophene
    —— Benzene, ((2-(ethenylseleno)ethyl)thio)- 90053-42-2 C10H14SSe
    Benzene, ((2-(ethenylseleno)ethyl)thio)-
    —— Benzenemethanol, 2-((2-((4-methyl-1-piperazinyl)methyl)phenyl)thio)-, dihydrochloride 93288-97-2 C19H26Cl2N2OS
    Benzenemethanol, 2-((2-((4-methyl-1-piperazinyl)methyl)phenyl)thio)-, dihydrochloride
    —— 1,4-tert-butyl-2,5,7-trithiabicyclo[2.2.1]heptane 124782-81-6 C12H22S3
    1,4-tert-butyl-2,5,7-trithiabicyclo[2.2.1]heptane
    —— 1-(2-(4-Chloro-2-(1-hydroxyethyl)phenylthio)benzyl)-4-methylpiperazine dihydrochloride 93288-37-0 C20H27Cl3N2OS
    1-(2-(4-Chloro-2-(1-hydroxyethyl)phenylthio)benzyl)-4-methylpiperazine dihydrochloride
    —— 3-(5-chloro-2-methylphenyl)-2-methylthio-4(3H)-pyrimidinone 89069-30-7 C12H11ClN2OS
    3-(5-chloro-2-methylphenyl)-2-methylthio-4(3H)-pyrimidinone
    —— 2,5-Dimethyl-2-phenylthiohexanonitril 66164-80-5 C14H19NS
    2,5-Dimethyl-2-phenylthiohexanonitril
    —— 2,5-Dimethyl-2-(phenylthio)hexan-1-ol 66332-74-9 C14H22OS
    2,5-Dimethyl-2-(phenylthio)hexan-1-ol
    —— 1-Cyclohexyl-3-hexylthiourea 401640-79-7 C13H26N2S
    1-Cyclohexyl-3-hexylthiourea
    —— Piperidine, 1-(3-((2-((p-chlorophenyl)thio)ethyl)amino)propyl)- 93144-71-9 C16H25ClN2S
    Piperidine, 1-(3-((2-((p-chlorophenyl)thio)ethyl)amino)propyl)-
    —— 6,6'-Diethoxy-thioindigo 42917-53-3 C20H16O4S2
    6,6'-Diethoxy-thioindigo
    —— Morpholine, 4-(3-((2-((p-chlorophenyl)thio)ethyl)amino)propyl)- 92724-93-1 C15H23ClN2OS
    Morpholine, 4-(3-((2-((p-chlorophenyl)thio)ethyl)amino)propyl)-
    —— (E)-1-cyclohexyl-2-(phenylthio)-1,3-butadiene 83877-76-3 C16H20S
    (E)-1-cyclohexyl-2-(phenylthio)-1,3-butadiene
    —— 1-methyl-2-phenylsulfanyl-cyclohex-2-enecarboxylic acid ethyl ester 862563-51-7 C16H20O2S
    1-methyl-2-phenylsulfanyl-cyclohex-2-enecarboxylic acid ethyl ester
    —— 1,3-Dimethyl-5-methylmercapto-pyrazol 32323-16-3 C6H10N2S
    1,3-Dimethyl-5-methylmercapto-pyrazol
    —— 1-methyl-2-phenylsulfanyl-cyclohex-2-enecarbaldehyde 862563-52-8 C14H16OS
    1-methyl-2-phenylsulfanyl-cyclohex-2-enecarbaldehyde
    —— 1,4-Dithia-spiro[4.5]decane-6-carboxylic acid 337468-24-3 C9H14O2S2
    1,4-Dithia-spiro[4.5]decane-6-carboxylic acid
    —— 4,6-di-methylthio-2-methyl-5-(2-imidazolin-2-yl)-aminopyrimidine 75438-59-4 C10H15N5S2
    4,6-di-methylthio-2-methyl-5-(2-imidazolin-2-yl)-aminopyrimidine
    —— 1-((methylsulfonyl)methyl)bicycle[3.1.0]hexan-2-one 1549803-77-1 C8H12O3S
    1-((methylsulfonyl)methyl)bicycle[3.1.0]hexan-2-one
    —— chloromethanesulfonyl chloride 112382-26-0 CHClO2S
    chloromethanesulfonyl chloride
    —— 2-tert-butoxycarbonylaminomethyl-3-(2-hydroxy-2-methylpropanethio)pyridine 342816-17-5 C15H24N2O3S
    2-tert-butoxycarbonylaminomethyl-3-(2-hydroxy-2-methylpropanethio)pyridine
    —— (4R)-4-hydroxy-4-(4-methylsulfanylphenyl)-butan-2-one 1147131-67-6 C11H14O2S
    (4R)-4-hydroxy-4-(4-methylsulfanylphenyl)-butan-2-one
    —— formic acid-[2-(2-nitro-5-trifluoromethyl-phenylsulfanyl)-anilide] 7639-63-6 C14H9F3N2O3S
    formic acid-[2-(2-nitro-5-trifluoromethyl-phenylsulfanyl)-anilide]
    —— 2-bromo-4-methyl-5-[(phenylthio)(2,3,6-trifluorophenyl)methyl]pyridine 913091-89-1 C19H13BrF3NS
    2-bromo-4-methyl-5-[(phenylthio)(2,3,6-trifluorophenyl)methyl]pyridine
    —— 3-Methylthio-1-cyclopentene 27557-68-2 C6H10S
    3-Methylthio-1-cyclopentene
    —— 2-bromo-4-methyl-5-[[[6-(trifluoromethyl)pyridin-3-yl]thio](2,3,6-trifluorophenyl)methyl]pyridine 913091-90-4 C19H11BrF6N2S
    2-bromo-4-methyl-5-[[[6-(trifluoromethyl)pyridin-3-yl]thio](2,3,6-trifluorophenyl)methyl]pyridine
    —— 2-Cyclopentenyl-butyl-sulfid 18508-17-3 C9H16S
    2-Cyclopentenyl-butyl-sulfid
    —— 6-(4-bromo-3-methyl-phenylsulfanyl)-3-methoxymethoxymethyl-2-methyl-pyridine 926640-01-9 C16H18BrNO2S
    6-(4-bromo-3-methyl-phenylsulfanyl)-3-methoxymethoxymethyl-2-methyl-pyridine