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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— hydron;phenyl N'-benzylcarbamimidothioate;chloride —— C14H15ClN2S
    hydron;phenyl N'-benzylcarbamimidothioate;chloride
    —— 3-Methyl-1-(4-phenylsulfanyl-butyl)-piperidin-2-one 643744-73-4 C16H23NOS
    3-Methyl-1-(4-phenylsulfanyl-butyl)-piperidin-2-one
    —— 4-Phenylmercapto-butylhydrazin 69782-04-3 C10H16N2S
    4-Phenylmercapto-butylhydrazin
    —— 7-Phenylthio-3-heptanon 62358-98-9 C13H18OS
    7-Phenylthio-3-heptanon
    —— 1-(4-Phenylsulfanyl-butyl)-azocan-2-one 643744-71-2 C17H25NOS
    1-(4-Phenylsulfanyl-butyl)-azocan-2-one
    —— 5,5-dimethylcyclohexane-1,3-dione 1-(ethylene dithioacetal) 83182-07-4 C10H16OS2
    5,5-dimethylcyclohexane-1,3-dione 1-(ethylene dithioacetal)
    —— 2-(4-chlorophenylmercapto)-6-(3-diethylamino-propoxy)-benzothiazole 184832-78-8 C20H23ClN2OS2
    2-(4-chlorophenylmercapto)-6-(3-diethylamino-propoxy)-benzothiazole
    —— 1-phenyl-1,3-bis(phenylthio)-2-butanone 104354-56-5 C22H20OS2
    1-phenyl-1,3-bis(phenylthio)-2-butanone
    —— alpha-(p-Isopropylthiophenyl)-1-imidazoleethanol 73973-71-4 C14H18N2OS
    alpha-(p-Isopropylthiophenyl)-1-imidazoleethanol
    —— S-(7,7-Dichlor-hepten-(6)-yl-(1))-isothioharnstoff 100793-80-4 C8H14Cl2N2S
    S-(7,7-Dichlor-hepten-(6)-yl-(1))-isothioharnstoff
    —— 2-[(1R)-3-azido-1-phenylpropyl]sulfanyl-6-methylpyridine-3-carbonitrile 496870-58-7 C16H15N5S
    2-[(1R)-3-azido-1-phenylpropyl]sulfanyl-6-methylpyridine-3-carbonitrile
    —— N<sup>3</sup>-(3-chloro-4-(phenylthio)phenyl)-1H-1,2,4-triazole-3,5-diamine 1620782-72-0 C14H12ClN5S
    N<sup>3</sup>-(3-chloro-4-(phenylthio)phenyl)-1H-1,2,4-triazole-3,5-diamine
    —— 2-chloro-4-nitrophenyl 3-methylpyrid-2-yl sulphide 179687-72-0 C12H9ClN2O2S
    2-chloro-4-nitrophenyl 3-methylpyrid-2-yl sulphide
    —— 2-(4-chlorophenylmercapto)-6-hydroxy-benzothiazole 184836-67-7 C13H8ClNOS2
    2-(4-chlorophenylmercapto)-6-hydroxy-benzothiazole
    —— 4-amino-2-chlorophenyl 2-tolyl sulphide 141550-77-8 C13H12ClNS
    4-amino-2-chlorophenyl 2-tolyl sulphide
    —— 2-(2-Chloro-4-nitro-phenylsulfanyl)-napthalene 76180-95-5 C16H10ClNO2S
    2-(2-Chloro-4-nitro-phenylsulfanyl)-napthalene
    —— N-(3-(4-amino-2-(6-iodobenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-1-yl)propyl)acetamide 1061318-12-4 C18H18IN5O3S
    N-(3-(4-amino-2-(6-iodobenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-1-yl)propyl)acetamide
    —— 2-[(2-chloro-4-nitrophenyl)thio]pyridine 524955-87-1 C11H7ClN2O2S
    2-[(2-chloro-4-nitrophenyl)thio]pyridine
    —— 2-Chlor-2-methansulfonyl-ethan 25093-85-0 C3H7ClO2S
    2-Chlor-2-methansulfonyl-ethan
    —— 4-amino-2-chlorophenyl 3-methylpyrid-2-yl sulphide 741232-06-4 C12H11ClN2S
    4-amino-2-chlorophenyl 3-methylpyrid-2-yl sulphide
    —— hexylsulfanylmethyl carbamimidothioate;hydron;chloride —— C8H19ClN2S2
    hexylsulfanylmethyl carbamimidothioate;hydron;chloride
    —— 4-[(2-chloro-4-nitrophenyl)thio]pyridine 91058-77-4 C11H7ClN2O2S
    4-[(2-chloro-4-nitrophenyl)thio]pyridine
    —— 3-chloro-4-(3,5-dichloro-phenylsulfanyl)-phenylamine 315228-54-7 C12H8Cl3NS
    3-chloro-4-(3,5-dichloro-phenylsulfanyl)-phenylamine
    —— 2-(2-chloro-4-nitro-phenylsulfanyl)-benzothiazole-5-carbonitrile 315228-93-4 C14H6ClN3O2S2
    2-(2-chloro-4-nitro-phenylsulfanyl)-benzothiazole-5-carbonitrile
    —— <2-<(2,3,5,6-tetrachlorophenyl)thio>phenyl>acetic acid 86335-31-1 C14H8Cl4O2S
    <2-<(2,3,5,6-tetrachlorophenyl)thio>phenyl>acetic acid
    —— 2-(2-chloro-4-nitrophenylsulfanyl)-1-ethyl-4,5-dimethyl-1H-imidazole 1125455-50-6 C13H14ClN3O2S
    2-(2-chloro-4-nitrophenylsulfanyl)-1-ethyl-4,5-dimethyl-1H-imidazole
    —— 1-ethoxy-1-methylsulfanyl-ethane 117583-94-5 C5H12OS
    1-ethoxy-1-methylsulfanyl-ethane
    —— methyl 4-phenylthiopent-2-enoate 88087-84-7 C12H14O2S
    methyl 4-phenylthiopent-2-enoate
    —— 2-Imidazol-1-yl-1-(4-propylsulfanyl-phenyl)-ethanol 73973-70-3 C14H18N2OS
    2-Imidazol-1-yl-1-(4-propylsulfanyl-phenyl)-ethanol
    —— 2-Imidazol-1-yl-1-(2-phenylsulfanyl-phenyl)-ethanol 73932-27-1 C17H16N2OS
    2-Imidazol-1-yl-1-(2-phenylsulfanyl-phenyl)-ethanol
    —— methyl 5-(phenylthio)tetronate 108932-52-1 C11H10O3S
    methyl 5-(phenylthio)tetronate
    —— 4-(2-nitro phenylthio)benzyl alcohol 126585-10-2 C13H11NO3S
    4-(2-nitro phenylthio)benzyl alcohol
    —— 4-(2-nitro phenylthio)benzaldehyde 126585-08-8 C13H9NO3S
    4-(2-nitro phenylthio)benzaldehyde
    —— Pent-1-ene-1-thione 131136-77-1 C5H8S
    Pent-1-ene-1-thione
    —— 1-(4-Butylsulfanyl-phenyl)-2-imidazol-1-yl-ethanol 73973-72-5 C15H20N2OS
    1-(4-Butylsulfanyl-phenyl)-2-imidazol-1-yl-ethanol
    —— 4,6-Diamino-2-methylmercapto-thioformamido-pyrimidin 98197-66-1 C6H9N5S2
    4,6-Diamino-2-methylmercapto-thioformamido-pyrimidin
    —— 1-<3'-deoxy-3'-phenylthio-2,2'-O-anhydro-β-D-lyxo-furanosyl>uracil 134357-13-4 C15H14N2O4S
    1-<3'-deoxy-3'-phenylthio-2,2'-O-anhydro-β-D-lyxo-furanosyl>uracil
    —— 7-amino-5-methylthio-[1,2,5]thiadiazolo[3,4-d]pyrimidine 6306-87-2 C5H5N5S2
    7-amino-5-methylthio-[1,2,5]thiadiazolo[3,4-d]pyrimidine
    —— 3-(3-(3-(thien-2-yl)-1-propylthio)-1,2,5-thiadiazol-4-yl)pyridine 165116-44-9 C14H13N3S3
    3-(3-(3-(thien-2-yl)-1-propylthio)-1,2,5-thiadiazol-4-yl)pyridine
    —— 2-hydroxy-2-methyl-4-(phenylthio)octan-3-one 131864-16-9 C15H22O2S
    2-hydroxy-2-methyl-4-(phenylthio)octan-3-one
    —— 2-Aethylmercapto-4-hydrazino-6-methyl-pyrimidin 89852-74-4 C7H12N4S
    2-Aethylmercapto-4-hydrazino-6-methyl-pyrimidin
    —— 6-[(4'-chlorophenyl)-thio]-3-methylphenyl acetic acid 54506-87-5 C15H13ClO2S
    6-[(4'-chlorophenyl)-thio]-3-methylphenyl acetic acid
    —— 1-<3'-deoxy-3'-phenylthio-2,2'-O-anhydro-β-D-arabino-furanosyl>uracil 134304-05-5 C15H14N2O4S
    1-<3'-deoxy-3'-phenylthio-2,2'-O-anhydro-β-D-arabino-furanosyl>uracil
    —— 4-hydroxyphenyl 2-(tetrahydropyran-2-yloxy)ethyl sulfide 114568-47-7 C13H18O3S
    4-hydroxyphenyl 2-(tetrahydropyran-2-yloxy)ethyl sulfide
    —— 2-ethoxyethyl 4-hydroxyphenyl sulfide 17178-13-1 C10H14O2S
    2-ethoxyethyl 4-hydroxyphenyl sulfide
    —— tert-butyl 5-amino-2-(ethylthio)benzyl(methyl)carbamate 943740-52-1 C15H24N2O2S
    tert-butyl 5-amino-2-(ethylthio)benzyl(methyl)carbamate
    —— 2-(2-(methylthio)phenyl)pyrimidine 1219699-60-1 C11H10N2S
    2-(2-(methylthio)phenyl)pyrimidine
    —— (1S,3R,8R,10S,12R,14R,15S,17R,19R)-15-[tert-butyl(dimethyl)silyl]oxy-17-[3-[tert-butyl(diphenyl)silyl]oxypropyl]-7,7-bis(ethylsulfanyl)-10-methyl-2,9,13,18-tetraoxatetracyclo[10.8.0.03,10.014,19]icosane-8-carbaldehyde 205864-92-2 C47H74O7S2Si2
    (1S,3R,8R,10S,12R,14R,15S,17R,19R)-15-[tert-butyl(dimethyl)silyl]oxy-17-[3-[tert-butyl(diphenyl)silyl]oxypropyl]-7,7-bis(ethylsulfanyl)-10-methyl-2,9,13,18-tetraoxatetracyclo[10.8.0.03,10.014,19]icosane-8-carbaldehyde
    —— 2-(2,6-bis(phenylthio)phenyl)pyrimidine 1584673-53-9 C22H16N2S2
    2-(2,6-bis(phenylthio)phenyl)pyrimidine
    —— 2-(phenyl(p-tolylthio)methyl)cyclohex-2-enone 1198078-58-8 C20H20OS
    2-(phenyl(p-tolylthio)methyl)cyclohex-2-enone