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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— dithiodecanediamide 7773-78-6 C10H20N2S2
    dithiodecanediamide
    —— bis-(3-amino-propyl)-sulfone 102203-35-0 C6H16N2O2S
    bis-(3-amino-propyl)-sulfone
    —— 4-chloro-5-methylthio-6-methylthiomethylpyrimidine 147115-20-6 C7H9ClN2S2
    4-chloro-5-methylthio-6-methylthiomethylpyrimidine
    —— (5S)-3-[(R)-2-(tert-butyldimethylsilyloxy)non-8-enyl]-5-methyl-3-phenylthio-3H-dihydrofuran-2-one 862603-33-6 C26H42O3SSi
    (5S)-3-[(R)-2-(tert-butyldimethylsilyloxy)non-8-enyl]-5-methyl-3-phenylthio-3H-dihydrofuran-2-one
    —— 1-{2,6-dichloro-4-[(phenylthio)methyl]pyridin-3-yl}hept-6-en-1-ol 607708-23-6 C19H21Cl2NOS
    1-{2,6-dichloro-4-[(phenylthio)methyl]pyridin-3-yl}hept-6-en-1-ol
    —— 2-(2,4-difluorophenyl)-1-(4-(3-((5-(3-fluorophenyl)-1,3,4-oxadiazol-2-yl)thio)propyl)piperazin-1-yl)-3-(1H-1,2,4-triazol-1-yl)propan-2-ol 1528792-75-7 C26H28F3N7O2S
    2-(2,4-difluorophenyl)-1-(4-(3-((5-(3-fluorophenyl)-1,3,4-oxadiazol-2-yl)thio)propyl)piperazin-1-yl)-3-(1H-1,2,4-triazol-1-yl)propan-2-ol
    —— 3-(3,3-Dimethylbutan-2-ylamino)-4-(4-methylsulfanylanilino)cyclobut-3-ene-1,2-dione 266318-17-6 C17H22N2O2S
    3-(3,3-Dimethylbutan-2-ylamino)-4-(4-methylsulfanylanilino)cyclobut-3-ene-1,2-dione
    —— 3,3-dimethyl-2-butanethiol 1638-99-9 C6H14S
    3,3-dimethyl-2-butanethiol
    —— 1-{2,6-dichloro-4-[(phenylthio)methyl]pyridin-3-yl}hex-5-en-1-ol 607708-22-5 C18H19Cl2NOS
    1-{2,6-dichloro-4-[(phenylthio)methyl]pyridin-3-yl}hex-5-en-1-ol
    —— 6-[(E)-3-oxooct-1-enyl]sulfanyl-2H-1,2,4-triazine-3,5-dione 80037-03-2 C11H15N3O3S
    6-[(E)-3-oxooct-1-enyl]sulfanyl-2H-1,2,4-triazine-3,5-dione
    —— Pent-3-en-2-yl-methylsulfid 89534-73-6 C6H12S
    Pent-3-en-2-yl-methylsulfid
    —— 2-(dimethylhydrazinylidene)-1-(4-phenylsulfanylphenyl)ethanone 25555-15-1 C16H16N2OS
    2-(dimethylhydrazinylidene)-1-(4-phenylsulfanylphenyl)ethanone
    —— N-methoxy-N,3-dimethyl-4-phenylsulfanyl-1,2-oxazole-5-carboxamide 916922-04-8 C13H14N2O3S
    N-methoxy-N,3-dimethyl-4-phenylsulfanyl-1,2-oxazole-5-carboxamide
    —— 3-Methyl-4-phenylsulfanyl-1,2-oxazole-5-carboxylic acid 916922-03-7 C11H9NO3S
    3-Methyl-4-phenylsulfanyl-1,2-oxazole-5-carboxylic acid
    —— 4-Benzo[1,3]dithiol-2-yl-phenol 76381-53-8 C13H10OS2
    4-Benzo[1,3]dithiol-2-yl-phenol
    —— 2-[1-methoxy-3-(phenylthio)-2-propyn-1-yl]thiophene 1356910-87-6 C14H12OS2
    2-[1-methoxy-3-(phenylthio)-2-propyn-1-yl]thiophene
    —— (5Z)-(3S,4S)-6-bromo-1,1-bis-ethylsulfanyl-4-methoxymethoxyhex-5-en-3-ol 651043-75-3 C12H23BrO3S2
    (5Z)-(3S,4S)-6-bromo-1,1-bis-ethylsulfanyl-4-methoxymethoxyhex-5-en-3-ol
    —— N-(Cycloheptyl)-S-n-propyl-thiolurethan 24363-66-4 C11H21NOS
    N-(Cycloheptyl)-S-n-propyl-thiolurethan
    —— 8,9-Dihydro-6-phenyl-5H,15H-dibenzo<d,h><1,6,10,2>oxadithiaphosphacyclododecin-6-oxid 122278-87-9 C22H21O2PS2
    8,9-Dihydro-6-phenyl-5H,15H-dibenzo<d,h><1,6,10,2>oxadithiaphosphacyclododecin-6-oxid
    —— 1-Methylsulfonyl-2-bromo-cycloheptane 59060-03-6 C8H15BrO2S
    1-Methylsulfonyl-2-bromo-cycloheptane
    —— methyl t-2-(phenylthio)-1-methyl-r-1-cyclopropanecarboxylate 100045-93-0 C12H14O2S
    methyl t-2-(phenylthio)-1-methyl-r-1-cyclopropanecarboxylate
    —— 3-(4-chlorophenyl)sulfanyl-2-hydroxy-4-methyl-2H-furan-5-one 1379781-64-2 C11H9ClO3S
    3-(4-chlorophenyl)sulfanyl-2-hydroxy-4-methyl-2H-furan-5-one
    —— N,N'-ditert-butyl-2,3-bis[(Z)-[tert-butyl(oxido)azaniumylidene]methyl]-2,3-bis(tert-butylsulfonyl)butane-1,4-diimine oxide 126994-49-8 C30H58N4O8S2
    N,N'-ditert-butyl-2,3-bis[(Z)-[tert-butyl(oxido)azaniumylidene]methyl]-2,3-bis(tert-butylsulfonyl)butane-1,4-diimine oxide
    —— 2-Cyclohepten-1-yl-phenylsulfid 64741-12-4 C13H16S
    2-Cyclohepten-1-yl-phenylsulfid
    —— 4-bromo-5-[(3-methoxyphenyl)thio]thiophene-2-carbaldehyde 1138032-94-6 C12H9BrO2S2
    4-bromo-5-[(3-methoxyphenyl)thio]thiophene-2-carbaldehyde
    —— 3-(phenylthio)isonicotinic acid 412339-07-2 C12H9NO2S
    3-(phenylthio)isonicotinic acid
    —— methyl 2,2-bis(phenylthio)-1-methylcyclopropanecarboxylate 100082-42-6 C18H18O2S2
    methyl 2,2-bis(phenylthio)-1-methylcyclopropanecarboxylate
    —— 1-octylsulfonyl-2-butene 78652-00-3 C12H24O2S
    1-octylsulfonyl-2-butene
    —— 6-((3-Oxohept-1-en-1-yl)thio)-1,2,4-triazine-3,5(2H,4H)-dione 80037-02-1 C10H13N3O3S
    6-((3-Oxohept-1-en-1-yl)thio)-1,2,4-triazine-3,5(2H,4H)-dione
    —— 3-t-Butyl-9-methyl-9-trichloromethyl-1,5-dithiaspiro[5.5]undecane 130338-07-7 C15H25Cl3S2
    3-t-Butyl-9-methyl-9-trichloromethyl-1,5-dithiaspiro[5.5]undecane
    —— Isobutyl-N-isobutoxycarbonylthiocarbamat 39142-39-7 C10H19NO3S
    Isobutyl-N-isobutoxycarbonylthiocarbamat
    —— 2,2-bis(3-methylthio-1H-1,2,4-triazol-1-yl)-propane 118718-07-3 C9H14N6S2
    2,2-bis(3-methylthio-1H-1,2,4-triazol-1-yl)-propane
    —— 1,4-diacetyl-5,5-dimethyl-3-methylsulfonyl-4,5-dihydro-1H-1,2,4-triazole 118807-27-5 C9H15N3O4S
    1,4-diacetyl-5,5-dimethyl-3-methylsulfonyl-4,5-dihydro-1H-1,2,4-triazole
    —— 1-(3,3-dimethyl-5-methylsulfonyl-1H-1,2,4-triazol-2-yl)ethanone 118807-33-3 C7H13N3O3S
    1-(3,3-dimethyl-5-methylsulfonyl-1H-1,2,4-triazol-2-yl)ethanone
    —— 2-(3-ethylthio-1H-1,2,4-triazol-1-yl)-2-(3-methylthio-1H-1,2,4-triazol-1-yl)propane 118718-18-6 C10H16N6S2
    2-(3-ethylthio-1H-1,2,4-triazol-1-yl)-2-(3-methylthio-1H-1,2,4-triazol-1-yl)propane
    —— 3-ethylsulfanyl-1-[2-(3-ethylsulfanyl-1,2,4-triazol-1-yl)propan-2-yl]-1,2,4-triazole 118718-08-4 C11H18N6S2
    3-ethylsulfanyl-1-[2-(3-ethylsulfanyl-1,2,4-triazol-1-yl)propan-2-yl]-1,2,4-triazole
    —— methyl (1E)-N-[methyl-[methyl-[(Z)-1-methylsulfanylethylideneamino]oxycarbonylamino]sulfanylcarbamoyl]oxyethanimidothioate 59669-26-0 C10H18N4O4S3
    methyl (1E)-N-[methyl-[methyl-[(Z)-1-methylsulfanylethylideneamino]oxycarbonylamino]sulfanylcarbamoyl]oxyethanimidothioate
    —— 2-phenylsulfanyl-[1]naphthylamine 858431-60-4 C16H13NS
    2-phenylsulfanyl-[1]naphthylamine
    —— 6-Amino-2-methyl-2-phenylsulfanylhexan-3-ol 852806-73-6 C13H21NOS
    6-Amino-2-methyl-2-phenylsulfanylhexan-3-ol
    —— 1,3-bis[(Z)-dodecylideneamino]thiourea 7400-39-7 C25H50N4S
    1,3-bis[(Z)-dodecylideneamino]thiourea
    —— bis(2-methyltetrahydrothienyl-2)sulfide 62308-53-6 C10H18S3
    bis(2-methyltetrahydrothienyl-2)sulfide
    —— 2-<<(p-bromophenyl)thio>methyl>-6-chloropyridine 83782-48-3 C12H9BrClNS
    2-<<(p-bromophenyl)thio>methyl>-6-chloropyridine
    —— ethyl n-octyl sulfone 34008-69-0 C10H22O2S
    ethyl n-octyl sulfone
    —— N-(4-hydroxy-5-methyl-5-phenylsulfanylhexyl)formamide 852806-78-1 C14H21NO2S
    N-(4-hydroxy-5-methyl-5-phenylsulfanylhexyl)formamide
    —— methyl N-(4-hydroxy-5-methyl-5-phenylsulfanylhexyl)carbamate 852806-74-7 C15H23NO3S
    methyl N-(4-hydroxy-5-methyl-5-phenylsulfanylhexyl)carbamate
    —— ethyl octyl sulfoxide 13126-09-5 C10H22OS
    ethyl octyl sulfoxide
    —— (E)-2-ethylsulfanylhept-2-enenitrile 68872-39-9 C9H15NS
    (E)-2-ethylsulfanylhept-2-enenitrile
    —— (-)-(1S,6S,9S)-8-phenylthio-5,5,9-trimethyltricyclo[7.2.1.0<sup>1,6</sup>]dodec-7-en-10-one 674781-50-1 C21H26OS
    (-)-(1S,6S,9S)-8-phenylthio-5,5,9-trimethyltricyclo[7.2.1.0<sup>1,6</sup>]dodec-7-en-10-one
    —— 4-(2-Bromophenyl)sulfanylbenzene-1,2-diamine 164801-40-5 C12H11BrN2S
    4-(2-Bromophenyl)sulfanylbenzene-1,2-diamine
    —— methyl N-[(E)-4-methylpentan-2-ylideneamino]carbamodithioate —— C8H16N2S2
    methyl N-[(E)-4-methylpentan-2-ylideneamino]carbamodithioate