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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(2-bromo-4-chlorophenyl)thio]acetic acid 882689-76-1 C8H6BrClO2S
    [(2-bromo-4-chlorophenyl)thio]acetic acid
    —— 1-phenylsulfanyl-2(S)-3-buten-2-ol 783322-43-0 C10H12OS
    1-phenylsulfanyl-2(S)-3-buten-2-ol
    —— Ethyl 5-[4-(3-benzyloxyphenylthio)-2-chlorophenyl]-2-ethoxycarbonyl-2-methylpentanoate 676481-38-2 C30H33ClO5S
    Ethyl 5-[4-(3-benzyloxyphenylthio)-2-chlorophenyl]-2-ethoxycarbonyl-2-methylpentanoate
    —— 5-[4-(3-benzyloxyphenylthio)-2-chlorophenyl]-2-ethoxycarbonyl-2-methylpentanoic acid 676481-42-8 C28H29ClO5S
    5-[4-(3-benzyloxyphenylthio)-2-chlorophenyl]-2-ethoxycarbonyl-2-methylpentanoic acid
    —— (3-cyano-6-methyl-4-methoxymethyl-2-pyridylthio)acetic acid 170885-42-4 C11H12N2O3S
    (3-cyano-6-methyl-4-methoxymethyl-2-pyridylthio)acetic acid
    —— Pyridine-3-carbonitrile, 2-(2-amino-2-oxoethylthio)-4-methoxymethyl-6-methyl- 185430-17-5 C11H13N3O2S
    Pyridine-3-carbonitrile, 2-(2-amino-2-oxoethylthio)-4-methoxymethyl-6-methyl-
    —— (rac)-6-bromo-2,3-dihydrobenzo[b]thiophen-3-ol 737802-11-8 C8H7BrOS
    (rac)-6-bromo-2,3-dihydrobenzo[b]thiophen-3-ol
    —— Bis<(methylthio)methylthio>-methan 35167-22-7 C5H12S4
    Bis<(methylthio)methylthio>-methan
    —— methyl 3-((2-amino-4-chlorophenyl)thio)benzoate 1451261-93-0 C14H12ClNO2S
    methyl 3-((2-amino-4-chlorophenyl)thio)benzoate
    —— 3-bromothioindoxyl 67866-90-4 C8H5BrOS
    3-bromothioindoxyl
    —— methyl 2-((2-amino-4-chlorophenyl)thio)benzoate hydrochloride salt 1071718-24-5 C14H12ClNO2S*ClH
    methyl 2-((2-amino-4-chlorophenyl)thio)benzoate hydrochloride salt
    —— N-(vinyloxyethyl)dithiocarbamic acid 103538-67-6 C5H9NOS2
    N-(vinyloxyethyl)dithiocarbamic acid
    —— 7-(o-hydroxyphenyl)-N-phenyl-5,6-dihydrothiopyrano<2,3-d>thiazolidine-2-thione-5,6-dicarboxylic acid anhydride 98664-30-3 C14H9NO4S3
    7-(o-hydroxyphenyl)-N-phenyl-5,6-dihydrothiopyrano<2,3-d>thiazolidine-2-thione-5,6-dicarboxylic acid anhydride
    —— (Z)-1,1-dichloro-3-methyl-5-phenylthio-3-pentene 85914-69-8 C12H14Cl2S
    (Z)-1,1-dichloro-3-methyl-5-phenylthio-3-pentene
    —— (2S)-1-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-yl 4-(morpholin-4-yl)butanoate 1404474-05-0 C30H38BrN7O6S
    (2S)-1-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-yl 4-(morpholin-4-yl)butanoate
    —— 5-S-benzylthio-2-N,N-dimethylaminopyridine 1083329-64-9 C14H16N2S
    5-S-benzylthio-2-N,N-dimethylaminopyridine
    —— 4-bromo-2,3-dihydro-benzo[b]thiophen-3-ol 737802-12-9 C8H7BrOS
    4-bromo-2,3-dihydro-benzo[b]thiophen-3-ol
    —— n-pentadecylmethyl sulphide 62155-10-6 C16H34S
    n-pentadecylmethyl sulphide
    —— 6-cyano-7-(o-hydroxyphenyl)-5,6-dihydrothiopyrano<2,3-d>thiazolidine-2-thione 98664-27-8 C13H10N2OS3
    6-cyano-7-(o-hydroxyphenyl)-5,6-dihydrothiopyrano<2,3-d>thiazolidine-2-thione
    —— (1R,5S)-1-hydroxymethyl-2-methylene-7-phenylsulfanylbicyclo[3.2.0]hept-6-ene 925413-80-5 C15H16OS
    (1R,5S)-1-hydroxymethyl-2-methylene-7-phenylsulfanylbicyclo[3.2.0]hept-6-ene
    —— dimethyl 7-(o-hydroxyphenyl)thiopyrano<2,3-d>thiazolidine-2-thione-5,6-dicarboxylate 98664-31-4 C16H13NO5S3
    dimethyl 7-(o-hydroxyphenyl)thiopyrano<2,3-d>thiazolidine-2-thione-5,6-dicarboxylate
    —— (1S,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxybicyclo[3.2.0]hept-6-ene-1-carbaldehyde 686737-96-2 C22H30O2SSi
    (1S,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxybicyclo[3.2.0]hept-6-ene-1-carbaldehyde
    —— 1-[(1R,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxy-1-bicyclo[3.2.0]hept-6-enyl]prop-2-en-1-ol 686737-80-4 C24H34O2SSi
    1-[(1R,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxy-1-bicyclo[3.2.0]hept-6-enyl]prop-2-en-1-ol
    —— 1-Benzenesulfenylmethyl-1-(2-propyl)cyclopropane 148258-88-2 C13H18S
    1-Benzenesulfenylmethyl-1-(2-propyl)cyclopropane
    —— (2S)-1-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-yl hydrogen sulfate sodium salt 1404473-71-7 C22H24BrN6O7S2*Na
    (2S)-1-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-yl hydrogen sulfate sodium salt
    —— [(1R,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxy-1-bicyclo[3.2.0]hept-6-enyl]methanol 686737-94-0 C22H32O2SSi
    [(1R,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxy-1-bicyclo[3.2.0]hept-6-enyl]methanol
    —— 4-({(2S)-1-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-yl} oxy)-4-oxobutanoic acid sodium salt 1404473-59-1 C26H28BrN6O7S*Na
    4-({(2S)-1-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-yl} oxy)-4-oxobutanoic acid sodium salt
    —— (1S,2S,5S)-1-hydroxymethyl-2-methyl-7-phenylsulfanylbicyclo[3.2.0]hept-6-ene 925413-81-6 C15H18OS
    (1S,2S,5S)-1-hydroxymethyl-2-methyl-7-phenylsulfanylbicyclo[3.2.0]hept-6-ene
    —— (1S,5R)-1-methoxycarbonyl-2-oxo-7-(phenylthio)bicyclo[3.2.0]hept-6-ene 686738-16-9 C15H14O3S
    (1S,5R)-1-methoxycarbonyl-2-oxo-7-(phenylthio)bicyclo[3.2.0]hept-6-ene
    —— dipyrido[3,4-b;4',3'-e][1,4]dithiin 503321-46-8 C10H6N2S2
    dipyrido[3,4-b;4',3'-e][1,4]dithiin
    —— methyl (1S,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxybicyclo[3.2.0]hept-6-ene-1-carboxylate 686737-92-8 C23H32O3SSi
    methyl (1S,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxybicyclo[3.2.0]hept-6-ene-1-carboxylate
    —— 2-amino-5-[(2,3-dihydroxypropyl)thio]pyridine 221185-57-5 C8H12N2O2S
    2-amino-5-[(2,3-dihydroxypropyl)thio]pyridine
    —— (E)-1,1-dichloro-3-methyl-5-phenylthio-3-pentene 85914-68-7 C12H14Cl2S
    (E)-1,1-dichloro-3-methyl-5-phenylthio-3-pentene
    —— dipyrido[3,4-b;3',4'-e][1,4]dithiin 831-20-9 C10H6N2S2
    dipyrido[3,4-b;3',4'-e][1,4]dithiin
    —— 4,4'-Dimethyl-2,2'-dinitro-diphenyl-sulfid 75459-85-7 C14H12N2O4S
    4,4'-Dimethyl-2,2'-dinitro-diphenyl-sulfid
    —— 2-[2-(4-Chlorophenyl)sulfanyl-4,5-dimethoxyphenyl]acetic acid 60969-65-5 C16H15ClO4S
    2-[2-(4-Chlorophenyl)sulfanyl-4,5-dimethoxyphenyl]acetic acid
    —— 2-butyl-5-methylene-3-phenylthio-2-cyclopenten-1-one 189030-25-9 C16H18OS
    2-butyl-5-methylene-3-phenylthio-2-cyclopenten-1-one
    —— 5-chloro-6-methyl-3-phenylsulfenyl-2(H)-1,4-oxazin-2-one 155959-00-5 C11H8ClNO2S
    5-chloro-6-methyl-3-phenylsulfenyl-2(H)-1,4-oxazin-2-one
    —— 1,3-bis[3-(2-aminophenylthio)prop-1-ynyl]benzene 352556-07-1 C24H20N2S2
    1,3-bis[3-(2-aminophenylthio)prop-1-ynyl]benzene
    —— 5-((E)-2-(N,N-dimethylamino)ethenyl)-3-ethylmercapto-6-methyl-1,2,4-triazine 169060-69-9 C10H16N4S
    5-((E)-2-(N,N-dimethylamino)ethenyl)-3-ethylmercapto-6-methyl-1,2,4-triazine
    —— 4,4′-(1,3-phenylenebis(sulfanediyl))dianiline 118570-71-1 C18H16N2S2
    4,4′-(1,3-phenylenebis(sulfanediyl))dianiline
    —— 2-Phenylthio-4,5-dimethoxyphenylessigsaeure 60969-64-4 C16H16O4S
    2-Phenylthio-4,5-dimethoxyphenylessigsaeure
    —— (tert-Butyl)-methyl-propyl-sulfonium 920-92-3 C8H19S*I
    (tert-Butyl)-methyl-propyl-sulfonium
    —— ethyl N-(4-cyano-1-methyl-5-methylsulfanylpyrazol-3-yl)methanimidate 512845-71-5 C9H12N4OS
    ethyl N-(4-cyano-1-methyl-5-methylsulfanylpyrazol-3-yl)methanimidate
    —— 2-methylthio-5-phenyl-1,3-thiazole 25445-03-8 C10H9NS2
    2-methylthio-5-phenyl-1,3-thiazole
    —— (Z)-1-phenyl-2-<(phenylthio)methylidene>cyclohexane-1-ol 119044-33-6 C19H20OS
    (Z)-1-phenyl-2-<(phenylthio)methylidene>cyclohexane-1-ol
    —— 2H-1,4-benzoxathiane-2-carbonitrile 51263-42-4 C9H7NOS
    2H-1,4-benzoxathiane-2-carbonitrile
    —— 4-hydroxy-2-phenylsulfanyl-thieno[2,3-c]pyridine-5-carboxylic acid n-butyl ester 909010-79-3 C18H17NO3S2
    4-hydroxy-2-phenylsulfanyl-thieno[2,3-c]pyridine-5-carboxylic acid n-butyl ester
    —— 7-hydroxy-2-phenylsulfanyl-thieno[3,2-c]pyridine-6-carboxylic acid n-butyl ester 909010-78-2 C18H17NO3S2
    7-hydroxy-2-phenylsulfanyl-thieno[3,2-c]pyridine-6-carboxylic acid n-butyl ester
    —— 2-(chloromethylthio)-4-(pyridin-2-yl)pyrimidine 1231156-71-0 C10H8ClN3S
    2-(chloromethylthio)-4-(pyridin-2-yl)pyrimidine