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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-(6-Nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]-5-yl)sulfanylpyridine 1027294-88-7 C16H14N2O4S
    4-(6-Nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]-5-yl)sulfanylpyridine
    —— N-(4,5-dichlorothiophen-2-ylsulfonyl)-2-(3-(2,4-difluorophenylthio)-1H-indol-4-yloxy)acetamide 1057256-16-2 C20H12Cl2F2N2O4S3
    N-(4,5-dichlorothiophen-2-ylsulfonyl)-2-(3-(2,4-difluorophenylthio)-1H-indol-4-yloxy)acetamide
    —— 2,3-dichloro-7,8-dimethyl[1,4]benzodithiino[2,3-b]pyridine 245070-02-4 C13H9Cl2NS2
    2,3-dichloro-7,8-dimethyl[1,4]benzodithiino[2,3-b]pyridine
    —— 4-(6-Nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]-5-yl)sulfanyl-1,3-thiazole 1025975-17-0 C14H12N2O4S2
    4-(6-Nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]-5-yl)sulfanyl-1,3-thiazole
    —— 5-(4-Fluorophenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane] 1027933-91-0 C17H14FNO4S
    5-(4-Fluorophenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]
    —— 5-(6-Nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]-5-yl)sulfanyl-1,3-thiazole 1026806-34-7 C14H12N2O4S2
    5-(6-Nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]-5-yl)sulfanyl-1,3-thiazole
    —— 2-(6-Nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]-5-yl)sulfanylpyridine 1027571-86-3 C16H14N2O4S
    2-(6-Nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]-5-yl)sulfanylpyridine
    —— 6-Nitro-5-(4-propan-2-ylphenyl)sulfanylspiro[1,2-dihydroindene-3,2'-1,3-dioxolane] 1028292-63-8 C20H21NO4S
    6-Nitro-5-(4-propan-2-ylphenyl)sulfanylspiro[1,2-dihydroindene-3,2'-1,3-dioxolane]
    —— 6-Nitro-5-thiophen-2-ylsulfanylspiro[1,2-dihydroindene-3,2'-1,3-dioxolane] 1026980-70-0 C15H13NO4S2
    6-Nitro-5-thiophen-2-ylsulfanylspiro[1,2-dihydroindene-3,2'-1,3-dioxolane]
    —— 5-(4-Methoxyphenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane] 1026064-29-8 C18H17NO5S
    5-(4-Methoxyphenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]
    —— 5-(4-Bromophenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane] 1027080-41-6 C17H14BrNO4S
    5-(4-Bromophenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]
    —— 5-(3-Fluorophenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane] 1026500-55-9 C17H14FNO4S
    5-(3-Fluorophenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]
    —— 5-(2-Methylphenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane] 1026814-94-7 C18H17NO4S
    5-(2-Methylphenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]
    —— 6-(2,4-Difluoro-phenylsulfanyl)-2,5-dimethyl-benzothiazole-4,7-dione 650635-72-6 C15H9F2NO2S2
    6-(2,4-Difluoro-phenylsulfanyl)-2,5-dimethyl-benzothiazole-4,7-dione
    —— (S)-3-(2,4-difluorophenylthio)cyclohexanone 1215843-26-7 C12H12F2OS
    (S)-3-(2,4-difluorophenylthio)cyclohexanone
    —— 2,4-Difluoro-1-(4-methoxyphenyl)sulfanylbenzene 1170116-17-2 C13H10F2OS
    2,4-Difluoro-1-(4-methoxyphenyl)sulfanylbenzene
    —— 2-chloro-6-(2,4-difluorophenylthio)nicotinonitrile 1392150-43-4 C12H5ClF2N2S
    2-chloro-6-(2,4-difluorophenylthio)nicotinonitrile
    —— 6-acetyl-3,4,5,6-tetrahydro-2-phenyl-2H-1,6-benzothiazocine 89569-14-2 C18H19NOS
    6-acetyl-3,4,5,6-tetrahydro-2-phenyl-2H-1,6-benzothiazocine
    —— 1-(2-(ethylsulfinyl)ethylsulfinyl)dodecane 1310681-75-4 C16H34O2S2
    1-(2-(ethylsulfinyl)ethylsulfinyl)dodecane
    —— dodecyl(2-(methylthio)phenyl)sulfane 1310681-81-2 C19H32S2
    dodecyl(2-(methylthio)phenyl)sulfane
    —— (1R,2R)-1,2-dihydroxy-4-[1-(phenylsulfanyl)cyclohexyl]butan-4-one 531557-71-8 C22H26O3S
    (1R,2R)-1,2-dihydroxy-4-[1-(phenylsulfanyl)cyclohexyl]butan-4-one
    —— 1-[Oxido-di(propan-2-yloxy)phosphaniumyl]-3-[2-[[oxido-di(propan-2-yloxy)phosphaniumyl]carbamothioylamino]ethyl]thiourea 1174003-26-9 C16H36N4O6P2S2
    1-[Oxido-di(propan-2-yloxy)phosphaniumyl]-3-[2-[[oxido-di(propan-2-yloxy)phosphaniumyl]carbamothioylamino]ethyl]thiourea
    —— 2-(10-Methoxy-10-phenylsulfanyl-decyl)-2-methyl-[1,3]dioxolane 89037-01-4 C21H34O3S
    2-(10-Methoxy-10-phenylsulfanyl-decyl)-2-methyl-[1,3]dioxolane
    —— 5-Chloro-1-[(4-methoxyphenyl)methyl]-6-methyl-3-phenylsulfanylpyrazin-2-one 936804-09-0 C19H17ClN2O2S
    5-Chloro-1-[(4-methoxyphenyl)methyl]-6-methyl-3-phenylsulfanylpyrazin-2-one
    —— 2-acetyl-5-methyl-3-(methylthio)furan 123958-34-9 C8H10O2S
    2-acetyl-5-methyl-3-(methylthio)furan
    —— 3-[(4-fluorobenzyl)thio]-4-methyl-4H-1,2,4-triazole 306744-28-5 C10H10FN3S
    3-[(4-fluorobenzyl)thio]-4-methyl-4H-1,2,4-triazole
    —— Ethyl-(1-methyl-pentyl)-sulfid 90952-35-5 C8H18S
    Ethyl-(1-methyl-pentyl)-sulfid
    —— 3,4,5,6-tetrahydro-6-ethyl-2-phenyl-2H-1,6-benzothiazocine 89569-13-1 C18H21NS
    3,4,5,6-tetrahydro-6-ethyl-2-phenyl-2H-1,6-benzothiazocine
    —— 5-(3-Chloro-5-fluorophenyl)sulfanyl-4-nitro-2,1,3-benzoxadiazole 1422955-22-3 C12H5ClFN3O3S
    5-(3-Chloro-5-fluorophenyl)sulfanyl-4-nitro-2,1,3-benzoxadiazole
    —— 1-(6-Methyl-4-methylsulfanyl-2-thioxo-1-o-tolyl-1,2-dihydro-pyridin-3-yl)-ethanone 90097-28-2 C16H17NOS2
    1-(6-Methyl-4-methylsulfanyl-2-thioxo-1-o-tolyl-1,2-dihydro-pyridin-3-yl)-ethanone
    —— 1-(1-Benzyl-6-methyl-4-methylsulfanyl-2-thioxo-1,2-dihydro-pyridin-3-yl)-ethanone 90097-33-9 C16H17NOS2
    1-(1-Benzyl-6-methyl-4-methylsulfanyl-2-thioxo-1,2-dihydro-pyridin-3-yl)-ethanone
    —— N-methyl-N-[(4-phenylthio)phenyl]-2,3-dioxo-1-methylpyrrolidine-4-carboxamide 77711-84-3 C19H18N2O3S
    N-methyl-N-[(4-phenylthio)phenyl]-2,3-dioxo-1-methylpyrrolidine-4-carboxamide
    —— 5-(3-Fluorophenyl)sulfanyl-4-nitro-2,1,3-benzoxadiazole 1422955-21-2 C12H6FN3O3S
    5-(3-Fluorophenyl)sulfanyl-4-nitro-2,1,3-benzoxadiazole
    —— 5-Phenylmercapto-4-nitro-benzofurazan 18378-26-2 C12H7N3O3S
    5-Phenylmercapto-4-nitro-benzofurazan
    —— 2-bromo-4-methyl-1-p-tolylsulfanylbenzene 1293343-29-9 C14H13BrS
    2-bromo-4-methyl-1-p-tolylsulfanylbenzene
    —— Allyloxythiocarbonylhydrazin 29771-25-3 C4H8N2OS
    Allyloxythiocarbonylhydrazin
    —— N-methyl-2-<(4-methylphenyl)thio>ethanamine hydrochloride 115335-02-9 C10H15NS*ClH
    N-methyl-2-<(4-methylphenyl)thio>ethanamine hydrochloride
    —— 4-(2,6-Dichloro-phenylsulfanyl)-pyridine-3-sulfonic acid amide 64063-25-8 C11H8Cl2N2O2S2
    4-(2,6-Dichloro-phenylsulfanyl)-pyridine-3-sulfonic acid amide
    —— 1-methyl-5-(4'-methylphenyl)thio-4-nitroimidazole 18383-80-7 C11H11N3O2S
    1-methyl-5-(4'-methylphenyl)thio-4-nitroimidazole
    —— 1-[(4-Methylsulfanylphenyl)methylideneamino]-3-phenylthiourea 468087-10-7 C15H15N3S2
    1-[(4-Methylsulfanylphenyl)methylideneamino]-3-phenylthiourea
    —— 2-hydroxymethylbutanethiol 144686-31-7 C5H12OS
    2-hydroxymethylbutanethiol
    —— 5-{2-[(4-Fluorobenzyl)thio]phenyl}-1,3,4-thiadiazol-2-amine 4639-71-8 C15H12FN3S2
    5-{2-[(4-Fluorobenzyl)thio]phenyl}-1,3,4-thiadiazol-2-amine
    —— 8-N-(cyclopropylmethyl)-2-N-methyl-4-N-(2-methylsulfanylphenyl)-2-N-(piperidin-4-ylmethyl)pyrimido[5,4-d]pyrimidine-2,4,8-triamine 1392888-98-0 C24H32N8S
    8-N-(cyclopropylmethyl)-2-N-methyl-4-N-(2-methylsulfanylphenyl)-2-N-(piperidin-4-ylmethyl)pyrimido[5,4-d]pyrimidine-2,4,8-triamine
    —— 4,4'-Diethyl-5,5'-bis-methylsulfanyl-4H,4'H-[3,3']bi[[1,2,4]triazolyl] 124945-93-3 C10H16N6S2
    4,4'-Diethyl-5,5'-bis-methylsulfanyl-4H,4'H-[3,3']bi[[1,2,4]triazolyl]
    —— 2-Amino-1-(4-chloro-phenyl)-4-methylsulfanyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile 608519-81-9 C12H9ClN4OS
    2-Amino-1-(4-chloro-phenyl)-4-methylsulfanyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile
    —— 2-Amino-4-methylsulfanyl-6-oxo-1-p-tolyl-1,6-dihydro-pyrimidine-5-carbonitrile 608519-79-5 C13H12N4OS
    2-Amino-4-methylsulfanyl-6-oxo-1-p-tolyl-1,6-dihydro-pyrimidine-5-carbonitrile
    —— 1,2-bis(phenylthio)-4-nitrobenzene 67745-30-6 C18H13NO2S2
    1,2-bis(phenylthio)-4-nitrobenzene
    —— 4-(1-Methylethyl)-3-<(phenylthio)methyl>-1-oxetan-2-one 135638-66-3 C13H16O2S
    4-(1-Methylethyl)-3-<(phenylthio)methyl>-1-oxetan-2-one
    —— 2-(Decane-1-sulfinylmethyl)-oxirane 93248-03-4 C13H26O2S
    2-(Decane-1-sulfinylmethyl)-oxirane
    —— 5-butyl-3,7-dithianonane-1,9-dithiol 135472-45-6 C11H24S4
    5-butyl-3,7-dithianonane-1,9-dithiol