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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-acetylmethyl-2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1H-imidazole 178982-47-3 C23H24Cl2N2O2S
    1-acetylmethyl-2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1H-imidazole
    —— 3-AMINO-2-BROMO-5-METHYLTHIOPYRAZINE 250659-54-2 C5H6BrN3S
    3-AMINO-2-BROMO-5-METHYLTHIOPYRAZINE
    —— 2-azidomethyl-1-benzyl-5-(3,5-dichlorophenylthio)-4-isopropylimidazole 178981-69-6 C20H19Cl2N5S
    2-azidomethyl-1-benzyl-5-(3,5-dichlorophenylthio)-4-isopropylimidazole
    —— 2-(N-chloroacetylcarbamoyloxy)methyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(pyridin-3-yl)methyl-1H-imidazole 178981-86-7 C22H21Cl3N4O3S
    2-(N-chloroacetylcarbamoyloxy)methyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(pyridin-3-yl)methyl-1H-imidazole
    —— 2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-1-(2-hydroxy-2-methylpropyl)-4-isopropyl-1H-imidazole 178982-51-9 C24H28Cl2N2O2S
    2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-1-(2-hydroxy-2-methylpropyl)-4-isopropyl-1H-imidazole
    —— 4-methyl-5-methylsulfanyl-2,4-dihydro-[1,2,4]triazole-3-thione 62770-12-1 C4H7N3S2
    4-methyl-5-methylsulfanyl-2,4-dihydro-[1,2,4]triazole-3-thione
    —— 5-(4-chlorophenylamino)-1,3-dimethyl-4-(2-pyrimidylthio)pyrazole 152527-25-8 C15H14ClN5S
    5-(4-chlorophenylamino)-1,3-dimethyl-4-(2-pyrimidylthio)pyrazole
    —— 1-bromo-3-[(3-chloropropyl)sulfanyl]benzene 19433-04-6 C9H10BrClS
    1-bromo-3-[(3-chloropropyl)sulfanyl]benzene
    —— 1-Bromo-2-[(3-chloropropyl)sulfanyl]benzene 487058-85-5 C9H10BrClS
    1-Bromo-2-[(3-chloropropyl)sulfanyl]benzene
    —— 5,5-dimethoxy-1-(4,4,5,5,5-pentafluoropentylsulfinyl)pentane 252947-04-9 C12H21F5O3S
    5,5-dimethoxy-1-(4,4,5,5,5-pentafluoropentylsulfinyl)pentane
    —— 2-thioxo-cyclohexanecarboxylic acid 824934-63-6 C7H10O2S
    2-thioxo-cyclohexanecarboxylic acid
    —— 2-Bromo-5-(methylsulfanyl)furan 474710-68-4 C5H5BrOS
    2-Bromo-5-(methylsulfanyl)furan
    —— 2,6-bis(benzylthio)pyrimidine-4,5-diamine 415920-33-1 C18H18N4S2
    2,6-bis(benzylthio)pyrimidine-4,5-diamine
    —— [[4-amino-2,6-bis[[(3-chloro-2-fluorophenyl)methyl]thio]-5-pyrimidinyl]amino]acetonitrile 415920-38-6 C20H15Cl2F2N5S2
    [[4-amino-2,6-bis[[(3-chloro-2-fluorophenyl)methyl]thio]-5-pyrimidinyl]amino]acetonitrile
    —— 1,3-bis(4-hydroxyphenylthio)-2-hydroxypropane 95971-33-8 C15H16O3S2
    1,3-bis(4-hydroxyphenylthio)-2-hydroxypropane
    —— 2,6-bis[[(3-chloro-2-fluorophenyl)methyl]thio]-4,5-pyrimidinediamine 415920-37-5 C18H14Cl2F2N4S2
    2,6-bis[[(3-chloro-2-fluorophenyl)methyl]thio]-4,5-pyrimidinediamine
    —— tributyl[5-(methylsulfanyl)-furan-2-yl)stannane 474710-69-5 C17H32OSSn
    tributyl[5-(methylsulfanyl)-furan-2-yl)stannane
    —— Isopropyl-5-nitropyrid-2-yl-sulfid 573676-13-8 C8H10N2O2S
    Isopropyl-5-nitropyrid-2-yl-sulfid
    —— 2-Bromo-5-(3-chloropropylsulfanyl)thiophene 474710-73-1 C7H8BrClS2
    2-Bromo-5-(3-chloropropylsulfanyl)thiophene
    —— tributyl[5-(ethylsulfanyl)-thien-2-yl]stannane 474710-65-1 C18H34S2Sn
    tributyl[5-(ethylsulfanyl)-thien-2-yl]stannane
    —— N-[4-(4-methoxyphenylsulfanyl)phenyl]guanidine 827610-24-2 C14H15N3OS
    N-[4-(4-methoxyphenylsulfanyl)phenyl]guanidine
    —— [2-methylsulfanyl-6-(morpholin-4-yl)-pyrimidin-4-yl]-(5-methyl-1H-pyrazol-3-yl)-amine 1417340-73-8 C13H18N6OS
    [2-methylsulfanyl-6-(morpholin-4-yl)-pyrimidin-4-yl]-(5-methyl-1H-pyrazol-3-yl)-amine
    —— Trihexylsulfanium;bromide 469912-67-2 C18H39BrS
    Trihexylsulfanium;bromide
    —— 4-(3-Methylphenyl)-2-(4-methylsulfonylphenyl)-5-(2-phenylthio-4-pyridyl)-1,3-thiazole 303163-42-0 C28H22N2O2S3
    4-(3-Methylphenyl)-2-(4-methylsulfonylphenyl)-5-(2-phenylthio-4-pyridyl)-1,3-thiazole
    —— 6-Chloro-3,3-Dimethyl-Benzo[1,4]Oxathiin-2-One 519172-56-6 C10H9ClO2S
    6-Chloro-3,3-Dimethyl-Benzo[1,4]Oxathiin-2-One
    —— N,N-dipentylcarbamodithioate 134102-51-5 C11H22NS2
    N,N-dipentylcarbamodithioate
    —— 2H-1,5-benzoxathiepine 34392-11-5 C9H8OS
    2H-1,5-benzoxathiepine
    —— 2-(4-fluorobenzyl)thio-5-(2-(4-morpholino)pyrimid-5-ylmethyl)pyrimidin-4-one 304694-28-8 C20H20FN5O2S
    2-(4-fluorobenzyl)thio-5-(2-(4-morpholino)pyrimid-5-ylmethyl)pyrimidin-4-one
    —— Propanedithial 64174-60-3 C3H4S2
    Propanedithial
    —— 2-Methylbutane-2,3-dithiol 90942-12-4 C5H12S2
    2-Methylbutane-2,3-dithiol
    —— 2,2-Bis[(sulfanylmethyl)sulfanyl]ethane-1-thiol 574615-78-4 C4H10S5
    2,2-Bis[(sulfanylmethyl)sulfanyl]ethane-1-thiol
    —— 2,3-dihydrobenzo[1,4]oxathiin-7-ol 402911-51-7 C8H8O2S
    2,3-dihydrobenzo[1,4]oxathiin-7-ol
    —— 7-hydroxymethyl-1H-pyrido[2,3-b][1,4]thiazin-2-one 443955-73-5 C8H8N2O2S
    7-hydroxymethyl-1H-pyrido[2,3-b][1,4]thiazin-2-one
    —— 3-ethyl-6-(4-fluorophenylsulfanyl)-1H-indazole 753922-19-9 C15H13FN2S
    3-ethyl-6-(4-fluorophenylsulfanyl)-1H-indazole
    —— 4-(5-Bromo-pyridine-3-sulfonyl)-5-methylsulfanyl-thiophene-2-carboxamidine 631904-40-0 C11H10BrN3O2S3
    4-(5-Bromo-pyridine-3-sulfonyl)-5-methylsulfanyl-thiophene-2-carboxamidine
    —— 4-(2-Methyl-furan-3-sulfonyl)-5-methylsulfanyl-thiophene-2-carboxamidine hydrochloride 631904-29-5 C11H12N2O3S3*ClH
    4-(2-Methyl-furan-3-sulfonyl)-5-methylsulfanyl-thiophene-2-carboxamidine hydrochloride
    —— bis-(4-amino-3-chloro-phenyl)-sulfide 46833-81-2 C12H10Cl2N2S
    bis-(4-amino-3-chloro-phenyl)-sulfide
    —— 4-(6-Amino-5-bromo-pyridine-3-sulfonyl)-5-methylsulfanyl-thiophene-2-carboxamidine 631904-39-7 C11H11BrN4O2S3
    4-(6-Amino-5-bromo-pyridine-3-sulfonyl)-5-methylsulfanyl-thiophene-2-carboxamidine
    —— 7-hydroxymethyl-2-oxo-2,3-dihydro-1H-pyrido[3,4-b][1,4]thiazine 443956-30-7 C8H8N2O2S
    7-hydroxymethyl-2-oxo-2,3-dihydro-1H-pyrido[3,4-b][1,4]thiazine
    —— 4-fluoro-3-methylsulphanyl-phenol 836678-97-8 C7H7FOS
    4-fluoro-3-methylsulphanyl-phenol
    —— 7-chloro-6-hydroxymethyl-3-oxo-3,4-dihydro-2H-pyrido[3,2-b][1,4]thiazine 577691-71-5 C8H7ClN2O2S
    7-chloro-6-hydroxymethyl-3-oxo-3,4-dihydro-2H-pyrido[3,2-b][1,4]thiazine
    —— bis(isoamylsulfonyl)diazomethane 138529-90-5 C11H22N2O4S2
    bis(isoamylsulfonyl)diazomethane
    —— 4-etylthianapthen-2-one 346592-82-3 C10H10OS
    4-etylthianapthen-2-one
    —— (Dioxo-lambda~6~-sulfanylidene)acetaldehyde 921193-01-3 C2H2O3S
    (Dioxo-lambda~6~-sulfanylidene)acetaldehyde
    —— (5-amino-3-hydroxy-7-oxo-2,3-dihydro-7<i>H</i>-thiazolo[3,2-<i>a</i>]pyrimidin-3-yl)-acetic acid ethyl ester 72195-12-1 C10H13N3O4S
    (5-amino-3-hydroxy-7-oxo-2,3-dihydro-7<i>H</i>-thiazolo[3,2-<i>a</i>]pyrimidin-3-yl)-acetic acid ethyl ester
    —— 4-Amino-1-benzothiazol-2-yl-3-m-tolylsulfanyl-1H-pyrazolo[3,4-b]pyridine-5,6-dicarboxylic acid dimethyl ester 173260-16-7 C24H19N5O4S2
    4-Amino-1-benzothiazol-2-yl-3-m-tolylsulfanyl-1H-pyrazolo[3,4-b]pyridine-5,6-dicarboxylic acid dimethyl ester
    —— (3a<i>S</i>)-3<i>c</i>-hydroxy-2<i>t</i>-hydroxymethyl-7-methylsulfanyl-(3a<i>r</i>,9a<i>c</i>)-2,3,3a,9a-tetrahydro-furo[2',3':4,5]oxazolo[3,2-<i>a</i>]pyrimidin-6-one 72369-45-0 C10H12N2O5S
    (3a<i>S</i>)-3<i>c</i>-hydroxy-2<i>t</i>-hydroxymethyl-7-methylsulfanyl-(3a<i>r</i>,9a<i>c</i>)-2,3,3a,9a-tetrahydro-furo[2',3':4,5]oxazolo[3,2-<i>a</i>]pyrimidin-6-one
    —— 5-(5-isoquinolylsulfanyl)-6-nitro-2,3-dihydro-1H-benzo[d]imidazol-2-one 203338-61-8 C16H10N4O3S
    5-(5-isoquinolylsulfanyl)-6-nitro-2,3-dihydro-1H-benzo[d]imidazol-2-one
    —— 2-(4,4-difluorobut-3-enylthio)-5-nitropyridine 172935-20-5 C9H8F2N2O2S
    2-(4,4-difluorobut-3-enylthio)-5-nitropyridine
    —— 5-(5-isoquinolylsulfanyl)-2-nitroaniline 203113-10-4 C15H11N3O2S
    5-(5-isoquinolylsulfanyl)-2-nitroaniline