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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Butylmercapto-2-phenylmercapto-propan 6839-01-6 C13H20S2
    2-Butylmercapto-2-phenylmercapto-propan
    —— (3-Methylthiophenyl)guanidin-nitrat 71198-44-2 C8H11N3S*HNO3
    (3-Methylthiophenyl)guanidin-nitrat
    —— 3,3-Dimethyl-2,4-dithiapentan-2-oxid 35493-34-6 C5H12OS2
    3,3-Dimethyl-2,4-dithiapentan-2-oxid
    —— methyl 2-methyl-2-methylsulfonylpropanoate 23550-42-7 C6H12O4S
    methyl 2-methyl-2-methylsulfonylpropanoate
    —— N-<Phenyl(phenylsulfanyl)methyl>formamide 177366-73-3 C14H13NOS
    N-<Phenyl(phenylsulfanyl)methyl>formamide
    —— 5-Methyl-4-(4-methylphenyl)thiomethyl-1,3-dioxol-2-one 111738-31-9 C12H12O3S
    5-Methyl-4-(4-methylphenyl)thiomethyl-1,3-dioxol-2-one
    —— 5-Methyl-4-phenylthiomethyl-1,3-dioxol-2-one 111738-33-1 C11H10O3S
    5-Methyl-4-phenylthiomethyl-1,3-dioxol-2-one
    —— 4-(4-Chlorophenyl)thiomethyl-5-methyl-1,3-dioxol-2-one 111738-34-2 C11H9ClO3S
    4-(4-Chlorophenyl)thiomethyl-5-methyl-1,3-dioxol-2-one
    —— 2H-Pyrazino(2,3-b)-1,4-thiazin-3(4H)-one, 4-(2-(dimethylamino)ethyl)-, monohydrochloride 55879-59-9 C10H15ClN4OS
    2H-Pyrazino(2,3-b)-1,4-thiazin-3(4H)-one, 4-(2-(dimethylamino)ethyl)-, monohydrochloride
    —— 1,5-dihydro-pyrimido[4,5-<i>b</i>][1,4]thiazine-2,4,6-trione 56223-56-4 C6H5N3O3S
    1,5-dihydro-pyrimido[4,5-<i>b</i>][1,4]thiazine-2,4,6-trione
    —— (E)-methoxycarbonyl methyl sulfine 247933-84-2 C4H6O3S
    (E)-methoxycarbonyl methyl sulfine
    —— 6-(phenylthio)-9-ethylpurine 83026-97-5 C13H12N4S
    6-(phenylthio)-9-ethylpurine
    —— 5-<4-Chlor-phenyl>-2-methylmercapto-1,3,4-oxadiazol 23767-37-5 C9H7ClN2OS
    5-<4-Chlor-phenyl>-2-methylmercapto-1,3,4-oxadiazol
    —— 2-[(4S,5S)-4,5-dimethyl-1,3-dioxolan-2-yl]-N-[(1S)-1-phenylethyl]-2-phenylsulfanylacetamide 1296255-08-7 C21H25NO3S
    2-[(4S,5S)-4,5-dimethyl-1,3-dioxolan-2-yl]-N-[(1S)-1-phenylethyl]-2-phenylsulfanylacetamide
    —— (-)-(R,R)-2,3-butanedithiol 68170-33-2 C4H10S2
    (-)-(R,R)-2,3-butanedithiol
    —— Dimethyl-(1-methylsulfanyl-allyl)-amine 89745-82-4 C6H13NS
    Dimethyl-(1-methylsulfanyl-allyl)-amine
    —— S-[[5-(2-hydroxyethoxy)-1,2,4-thiadiazol-3-yl]] N,N-dimethylcarbamothioate 1012073-48-1 C7H11N3O3S2
    S-[[5-(2-hydroxyethoxy)-1,2,4-thiadiazol-3-yl]] N,N-dimethylcarbamothioate
    —— ((Z)-N-Propenyl)-thioacetamide 56634-57-2 C5H9NS
    ((Z)-N-Propenyl)-thioacetamide
    —— 2-amino-3-methylthio-4-picoline 179554-97-3 C7H10N2S
    2-amino-3-methylthio-4-picoline
    —— (4-chlorophenyl)(2-nitro-1-p-tolylethyl)sulfide 110113-23-0 C15H14ClNO2S
    (4-chlorophenyl)(2-nitro-1-p-tolylethyl)sulfide
    —— (2-nitro-1-p-tolyl-ethyl)(phenyl)sulfide 110113-16-1 C15H15NO2S
    (2-nitro-1-p-tolyl-ethyl)(phenyl)sulfide
    —— (2-nitro-1-p-tolylethyl)(p-tolyl)sulfide 110129-93-6 C16H17NO2S
    (2-nitro-1-p-tolylethyl)(p-tolyl)sulfide
    —— 2-Methyl-N-phenyl-thiopropionimidic acid p-tolyl ester 120346-02-3 C17H19NS
    2-Methyl-N-phenyl-thiopropionimidic acid p-tolyl ester
    —— 2-Methyl-N-phenyl-thiopropionimidic acid phenyl ester 120346-01-2 C16H17NS
    2-Methyl-N-phenyl-thiopropionimidic acid phenyl ester
    —— 2-Pyrimidinamine, 4,6-bis(2-(dimethylamino)ethoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide 57259-26-4 C17H35Br2N5O2S
    2-Pyrimidinamine, 4,6-bis(2-(dimethylamino)ethoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide
    —— Imidodicarbonimidic diamide, N-(4-((2-amino-4,5-dimethoxyphenyl)thio)phenyl)- 56948-13-1 C16H20N6O2S
    Imidodicarbonimidic diamide, N-(4-((2-amino-4,5-dimethoxyphenyl)thio)phenyl)-
    —— 3-(Thiophen-2-ylmethyl)-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine 1428566-00-0 C17H11F3N4S2
    3-(Thiophen-2-ylmethyl)-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine
    —— (2S,3R,4R,6R)-2,4-dimethyl-1-phenylsulfanyl-6-[(4S,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl]heptan-3-ol 1351657-01-6 C22H36O3S
    (2S,3R,4R,6R)-2,4-dimethyl-1-phenylsulfanyl-6-[(4S,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl]heptan-3-ol
    —— 5-nitrobenzo[b]thiophen-2(3H)-one 125772-34-1 C8H5NO3S
    5-nitrobenzo[b]thiophen-2(3H)-one
    —— [2-(2-phenylsulfanyl-ethylsulfanyl)-pyridin-3-yl]amine 1242435-97-7 C13H14N2S2
    [2-(2-phenylsulfanyl-ethylsulfanyl)-pyridin-3-yl]amine
    —— 4-[4,6-bis-(1-methyl-piperidin-4-yloxy)-5-methylsulfanyl-pyrimidin-2-yl]-morpholine 57304-24-2 C21H35N5O3S
    4-[4,6-bis-(1-methyl-piperidin-4-yloxy)-5-methylsulfanyl-pyrimidin-2-yl]-morpholine
    —— 4-phenylthio-2-buten-1-ol 20614-50-0 C10H12OS
    4-phenylthio-2-buten-1-ol
    —— 3-(5-Methylsulfanyl-furan-2-yl)-propionaldehyde 136093-81-7 C8H10O2S
    3-(5-Methylsulfanyl-furan-2-yl)-propionaldehyde
    —— (4S,5R)-2,2,5-trimethyl-4-[(2R,4R)-4-[(2R,3S)-3-(phenylsulfanylmethyl)oxiran-2-yl]pentan-2-yl]-1,3-dioxane 1351657-00-5 C21H32O3S
    (4S,5R)-2,2,5-trimethyl-4-[(2R,4R)-4-[(2R,3S)-3-(phenylsulfanylmethyl)oxiran-2-yl]pentan-2-yl]-1,3-dioxane
    —— 5-(benzylsulfanyl)-3-hydroxypyridin-2(1H)-one 1417709-95-5 C12H11NO2S
    5-(benzylsulfanyl)-3-hydroxypyridin-2(1H)-one
    —— 2-Pyrimidinamine, 4,6-bis((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-N,N-diethyl-, hydrobromide, hydrate (1:2:1) 57259-13-9 C21H39Br2N5O2S
    2-Pyrimidinamine, 4,6-bis((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-N,N-diethyl-, hydrobromide, hydrate (1:2:1)
    —— Pyrimidine, 4,6-bis((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-2-(1-piperidinyl)-, dihydrobromide 57259-16-2 C22H39Br2N5O2S
    Pyrimidine, 4,6-bis((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-2-(1-piperidinyl)-, dihydrobromide
    —— 2,4'-Diamino-4,5-dimethoxy-diphenylsulfid 56948-12-0 C14H16N2O2S
    2,4'-Diamino-4,5-dimethoxy-diphenylsulfid
    —— Thallium, dimethyl-, diethyldithiocarbamate 57025-28-2 C7H16NS2Tl
    Thallium, dimethyl-, diethyldithiocarbamate
    —— (E)-1-acetoxy-2-phenylthiohex-1-ene 123630-48-8 C14H18O2S
    (E)-1-acetoxy-2-phenylthiohex-1-ene
    —— 2-Pyrimidinamine, 4,6-bis(3-(dimethylamino)propoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide 57259-25-3 C19H39Br2N5O2S
    2-Pyrimidinamine, 4,6-bis(3-(dimethylamino)propoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide
    —— trans-2-allylcyclohexanethiol 63714-87-4 C9H16S
    trans-2-allylcyclohexanethiol
    —— 3-(adamant-1-yl)-1,1,1-tris(methylthio)propane 480425-03-4 C16H28S3
    3-(adamant-1-yl)-1,1,1-tris(methylthio)propane
    —— 2-Pyrimidinamine, 4-chloro-N,N-diethyl-6-((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-, monohydrobromide 57259-19-5 C15H26BrClN4OS
    2-Pyrimidinamine, 4-chloro-N,N-diethyl-6-((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-, monohydrobromide
    —— 2-Pyrimidinamine, 4,6-bis(2-(bis(1-methylethyl)amino)ethoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide 57259-27-5 C25H51Br2N5O2S
    2-Pyrimidinamine, 4,6-bis(2-(bis(1-methylethyl)amino)ethoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide
    —— N,N-diethyl-4-methoxy-6-(1-methylpiperidin-4-yl)oxy-5-methylsulfanylpyrimidin-2-amine;hydron;bromide —— C16H29BrN4O2S
    N,N-diethyl-4-methoxy-6-(1-methylpiperidin-4-yl)oxy-5-methylsulfanylpyrimidin-2-amine;hydron;bromide
    —— 2-(3-methylene-cyclopentyl)-2-(2-nitro-ethyl)-[1,3]dithiane 1254074-43-5 C12H19NO2S2
    2-(3-methylene-cyclopentyl)-2-(2-nitro-ethyl)-[1,3]dithiane
    —— (E)-2-acetoxy-1-phenylthiohex-1-ene 123630-47-7 C14H18O2S
    (E)-2-acetoxy-1-phenylthiohex-1-ene
    —— 3-(adamant-1-yl)-2-bromo-1,1-difluoro-1-methylthiopropane 480425-10-3 C14H21BrF2S
    3-(adamant-1-yl)-2-bromo-1,1-difluoro-1-methylthiopropane
    —— (E)-1-acetoxy-2-phenylthiopropene 123630-42-2 C11H12O2S
    (E)-1-acetoxy-2-phenylthiopropene