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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-Benzyl-8-Phenyl-1,2,4-triazolo<3,4-b>-1,3,4-thiadiazepine 76457-86-8 C18H14N4S
    3-Benzyl-8-Phenyl-1,2,4-triazolo<3,4-b>-1,3,4-thiadiazepine
    —— 1,4-bis(4-amino-5-benzyl-1,2,4-triazol-3-ylsulfanyl)butane 263900-73-8 C22H26N8S2
    1,4-bis(4-amino-5-benzyl-1,2,4-triazol-3-ylsulfanyl)butane
    —— 7H-6-Phenyl-3-phenylmethyl-s-triazolo<3,4-b><1,3,4>thiadiazine 79074-64-9 C17H14N4S
    7H-6-Phenyl-3-phenylmethyl-s-triazolo<3,4-b><1,3,4>thiadiazine
    —— 2,6-bis(4-amino-5-benzyl-1,2,4-triazol-3-ylsulfanylmethyl)pyridine 1001126-66-4 C25H25N9S2
    2,6-bis(4-amino-5-benzyl-1,2,4-triazol-3-ylsulfanylmethyl)pyridine
    —— (4-amino-5-benzyl-4H-1,2,4-triazol-3-ylsulphanyl)-methylenenitrile 111828-06-9 C11H11N5S
    (4-amino-5-benzyl-4H-1,2,4-triazol-3-ylsulphanyl)-methylenenitrile
    —— 6-(p-chlorophenyl)-3-ethoxycarbonyl-5H-1,2,3-triazolo<5,1-b><1,3,4>thiadiazine 127045-32-3 C13H11ClN4O2S
    6-(p-chlorophenyl)-3-ethoxycarbonyl-5H-1,2,3-triazolo<5,1-b><1,3,4>thiadiazine
    —— 3-ethoxycarbonyl-6-methyl-5H-1,2,3-triazolo<5,1-b><1,3,4>thiadiazine 127045-30-1 C8H10N4O2S
    3-ethoxycarbonyl-6-methyl-5H-1,2,3-triazolo<5,1-b><1,3,4>thiadiazine
    —— 2,4-Dimethyl-5-(methylthio)pyrimidine 91157-96-9 C7H10N2S
    2,4-Dimethyl-5-(methylthio)pyrimidine
    —— N-Methyl-amidosulfonsaeure-thiomethylester 26118-77-4 C2H7NO2S2
    N-Methyl-amidosulfonsaeure-thiomethylester
    —— 6-amino-2-methyl-4-methylthio-5-(2-pyridinyl)pyrimidine 122851-66-5 C11H12N4S
    6-amino-2-methyl-4-methylthio-5-(2-pyridinyl)pyrimidine
    —— 6,7-dihydro-2-methyl-4(3H)-oxopyrimido[5,4-b][1,4]thiazine 124724-42-1 C7H9N3OS
    6,7-dihydro-2-methyl-4(3H)-oxopyrimido[5,4-b][1,4]thiazine
    —— 1-methylene-2-(phenylthio)cyclohexane 67957-89-5 C13H16S
    1-methylene-2-(phenylthio)cyclohexane
    —— S-(4-chlorophenyl) N-ethylcarbamothioate 14467-72-2 C9H10ClNOS
    S-(4-chlorophenyl) N-ethylcarbamothioate
    —— (S)-2-(2-hydroxymethyl-1-pyrrolidinyl)-4-phenylthio-5-[N-(2-pyrimidylmethyl)carbamoyl]pyrimidine 476449-27-1 C21H22N6O2S
    (S)-2-(2-hydroxymethyl-1-pyrrolidinyl)-4-phenylthio-5-[N-(2-pyrimidylmethyl)carbamoyl]pyrimidine
    —— S-(4-methylphenyl) N-ethylcarbamothioate 815582-19-5 C10H13NOS
    S-(4-methylphenyl) N-ethylcarbamothioate
    —— S-(4-bromophenyl) N-ethylcarbamothioate 815582-22-0 C9H10BrNOS
    S-(4-bromophenyl) N-ethylcarbamothioate
    —— 6-phenyl-3-(1,2,3,4-tetrahydroxybutan-1-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine 1056757-68-6 C14H16N4O4S
    6-phenyl-3-(1,2,3,4-tetrahydroxybutan-1-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine
    —— N,N-Diethyl-N-[3-({6-methoxy-4-[(5-nitro-2-thienyl)sulfanyl]-7-quinolyl}oxy)propyl]amine 417722-33-9 C21H25N3O4S2
    N,N-Diethyl-N-[3-({6-methoxy-4-[(5-nitro-2-thienyl)sulfanyl]-7-quinolyl}oxy)propyl]amine
    —— trans-3-(p-Tolyl-mercapto)-acrylsaeure 710-38-3 C10H10O2S
    trans-3-(p-Tolyl-mercapto)-acrylsaeure
    —— (Z)-2-Phenylsulfanylmethyl-but-2-enedioic acid 1-methyl ester 69804-89-3 C12H12O4S
    (Z)-2-Phenylsulfanylmethyl-but-2-enedioic acid 1-methyl ester
    —— tert-butyl N-[(4-chlorophenyl)methyl]-N-[(2R)-2-[(6-imidazol-1-yl-2-methylsulfanylpyrimidin-4-yl)amino]-4-methylpentyl]carbamate 321329-60-6 C26H35ClN6O2S
    tert-butyl N-[(4-chlorophenyl)methyl]-N-[(2R)-2-[(6-imidazol-1-yl-2-methylsulfanylpyrimidin-4-yl)amino]-4-methylpentyl]carbamate
    —— (S)-2-(tert-butoxycarbonylamino)-4-(methanesulfonyl)butanal 186203-23-6 C10H19NO5S
    (S)-2-(tert-butoxycarbonylamino)-4-(methanesulfonyl)butanal
    —— 6-(phenylthio)hept-1-en-4-ol 884598-67-8 C13H18OS
    6-(phenylthio)hept-1-en-4-ol
    —— (E)-2-{[(Cyclopropyl)amino]phenylmethylene}-benzo[b]thiophen-3(2H)-one 77946-86-2 C18H15NOS
    (E)-2-{[(Cyclopropyl)amino]phenylmethylene}-benzo[b]thiophen-3(2H)-one
    —— 6-(1-adamantyl)-3-cyano-2-allylmercaptopyridine 112629-74-0 C19H22N2S
    6-(1-adamantyl)-3-cyano-2-allylmercaptopyridine
    —— 2-{[(Benzylsulfanyl)methyl]sulfanyl}-4,6-dimethylpyridine-3-carbonitrile 442152-76-3 C16H16N2S2
    2-{[(Benzylsulfanyl)methyl]sulfanyl}-4,6-dimethylpyridine-3-carbonitrile
    —— α-Fluorocyanomethyl 2-(3-cyano-4,6-dimethyl)pyridyl sulfide 159831-91-1 C10H8FN3S
    α-Fluorocyanomethyl 2-(3-cyano-4,6-dimethyl)pyridyl sulfide
    —— 159717-91-6 C11H11N5S
    —— 2-pentafluorosulfanylheptanal 1122591-42-7 C7H13F5OS
    2-pentafluorosulfanylheptanal
    —— 3-cyano-4,6-dimethyl-2-[(2-thienylmethyl)thio]pyridine 1203929-22-9 C13H12N2S2
    3-cyano-4,6-dimethyl-2-[(2-thienylmethyl)thio]pyridine
    —— 2-Cyclohex-2-en-1-ylsulfanyl-4,6-dimethylpyridine-3-carbonitrile 121567-77-9 C14H16N2S
    2-Cyclohex-2-en-1-ylsulfanyl-4,6-dimethylpyridine-3-carbonitrile
    —— 2-(3-Cyano-4,6-dimethylpyridin-2-yl)sulfanyl-2-methylpropanoic acid 1103521-26-1 C12H14N2O2S
    2-(3-Cyano-4,6-dimethylpyridin-2-yl)sulfanyl-2-methylpropanoic acid
    —— 2-butylthio-3-cyano-4,6-dimethylpyridine 496778-32-6 C12H16N2S
    2-butylthio-3-cyano-4,6-dimethylpyridine
    —— 4-(3-Cyano-4,6-dimethyl-pyridin-2-ylsulfanyl)-3-oxo-butyric acid ethyl ester 290299-57-9 C14H16N2O3S
    4-(3-Cyano-4,6-dimethyl-pyridin-2-ylsulfanyl)-3-oxo-butyric acid ethyl ester
    —— 4,6-dimethyl-2-(prop-2-yn-1-ylsulfanyl)pyridine-3-carbonitrile 285980-92-9 C11H10N2S
    4,6-dimethyl-2-(prop-2-yn-1-ylsulfanyl)pyridine-3-carbonitrile
    —— 2-(benzylsulfanyl)-4,6-dimethylpyridine-3-carbonitrile 97248-85-6 C15H14N2S
    2-(benzylsulfanyl)-4,6-dimethylpyridine-3-carbonitrile
    —— S-phenyl isopropylthiocarbamate 17671-79-3 C10H13NOS
    S-phenyl isopropylthiocarbamate
    —— methyl 2-(pentylsulfonyl)diazoacetate 1424362-20-8 C8H14N2O4S
    methyl 2-(pentylsulfonyl)diazoacetate
    —— ethyl 2-(pentylsulfonyl)acetate 921755-18-2 C9H18O4S
    ethyl 2-(pentylsulfonyl)acetate
    —— 5-(3-hydroxypropoxy)-2-(2-nitrophenylthio)-N,N-dimethylbenzamide 1004534-63-7 C18H20N2O5S
    5-(3-hydroxypropoxy)-2-(2-nitrophenylthio)-N,N-dimethylbenzamide
    —— 2-(4-bromo-2-nitrophenylthio)-5-(3-hydroxypropoxy)-N,N-dimethylbenzamide 1004534-67-1 C18H19BrN2O5S
    2-(4-bromo-2-nitrophenylthio)-5-(3-hydroxypropoxy)-N,N-dimethylbenzamide
    —— 2-(4-fluoro-2-nitrophenylthio)-5-(3-hydroxypropoxy)-N,N-dimethylbenzamide 1004534-65-9 C18H19FN2O5S
    2-(4-fluoro-2-nitrophenylthio)-5-(3-hydroxypropoxy)-N,N-dimethylbenzamide
    —— 2-(5-amino-2-phenyl-4-cyano-2-ethylsulfanyl-2,3-dihydrofuran-3-ylidene)propanedinitrile 1240182-11-9 C16H12N4OS
    2-(5-amino-2-phenyl-4-cyano-2-ethylsulfanyl-2,3-dihydrofuran-3-ylidene)propanedinitrile
    —— 16-phenylthiodidemnimide C 259752-97-1 C22H16N4O2S
    16-phenylthiodidemnimide C
    —— 3-(3-bromophenylthio)propan-1-ol 880157-87-9 C9H11BrOS
    3-(3-bromophenylthio)propan-1-ol
    —— 4-[(3-chloro-2-methylphenyl)methyl]-5-(methylthio)-2-(4-morpholinyl)[1,3]thiazolo[4,5-d]pyrimidin-7(4H)-one 1256290-16-0 C18H19ClN4O2S2
    4-[(3-chloro-2-methylphenyl)methyl]-5-(methylthio)-2-(4-morpholinyl)[1,3]thiazolo[4,5-d]pyrimidin-7(4H)-one
    —— Methyl E-2,3-dihydro-1,4-benzoxathiin-2-ylidene acetate 111042-26-3 C11H10O3S
    Methyl E-2,3-dihydro-1,4-benzoxathiin-2-ylidene acetate
    —— 1-(4-methoxyphenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)thiourea 1395063-44-1 C24H24N4O2S2
    1-(4-methoxyphenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)thiourea
    —— 2,4,6-tris(methylsulfanyl)pyrimidine-5-carbonitrile 501433-97-2 C8H9N3S3
    2,4,6-tris(methylsulfanyl)pyrimidine-5-carbonitrile
    —— 2,4-bis(morpholinocarbonylmethylsulfanyl)-6-methylsulfanylpyrimidin-5-carbonitrile 501434-01-1 C18H23N5O4S3
    2,4-bis(morpholinocarbonylmethylsulfanyl)-6-methylsulfanylpyrimidin-5-carbonitrile