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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3,3,4,4,5,5,6,6,6-nonafluorohexylsulfonyl)acetonitrile 1097630-70-0 C8H6F9NO2S
    (3,3,4,4,5,5,6,6,6-nonafluorohexylsulfonyl)acetonitrile
    —— 2-(4-oxocyclohexyl)-2-(3,3,4,4,5,5,6,6,6-nonafluorohexylsulfonyl)acetonitrile 1097630-58-4 C14H14F9NO3S
    2-(4-oxocyclohexyl)-2-(3,3,4,4,5,5,6,6,6-nonafluorohexylsulfonyl)acetonitrile
    —— (3,3,4,4,5,5,6,6,6-nonafluorohexylsulfinyl)acetonitrile 1097630-69-7 C8H6F9NOS
    (3,3,4,4,5,5,6,6,6-nonafluorohexylsulfinyl)acetonitrile
    —— ethyl 4-[[2-[2-[(trifluoroacetyl)amino]ethyl]phenyl]thio]-2-pyridinecarboxylate 699013-01-9 C18H17F3N2O3S
    ethyl 4-[[2-[2-[(trifluoroacetyl)amino]ethyl]phenyl]thio]-2-pyridinecarboxylate
    —— methyl 4-[[4-[2-[(tert-butoxycarbonyl)amino]ethyl]phenyl]thio]-2-pyridinecarboxylate 699013-03-1 C20H24N2O4S
    methyl 4-[[4-[2-[(tert-butoxycarbonyl)amino]ethyl]phenyl]thio]-2-pyridinecarboxylate
    —— 2-(4-fluorophenyl)-3-hydroxy-3-(2-methylsulfanyl-pyrimidin-4-yl)-propionic acid methyl ester 503071-70-3 C15H15FN2O3S
    2-(4-fluorophenyl)-3-hydroxy-3-(2-methylsulfanyl-pyrimidin-4-yl)-propionic acid methyl ester
    —— 5-(4-methylsulfanylphenyl)furan-2-carbaldehyde 57666-97-4 C12H10O2S
    5-(4-methylsulfanylphenyl)furan-2-carbaldehyde
    —— 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylsulfonylsulfanyl)octane 76598-00-0 C16H8F26O2S2
    1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylsulfonylsulfanyl)octane
    —— 4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylsulfanyl)-but-2-en-1-ol 909025-55-4 C12H11F13OS
    4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylsulfanyl)-but-2-en-1-ol
    —— 9-(1H-indazol-5-yl)-2-phenylsulfanyl-9H-purine 1332367-72-2 C18H12N6S
    9-(1H-indazol-5-yl)-2-phenylsulfanyl-9H-purine
    —— 6-Bromo-4-(3-bromophenylthio)quinazoline 1202228-43-0 C14H8Br2N2S
    6-Bromo-4-(3-bromophenylthio)quinazoline
    —— 2-(4-fluorophenyl)-3-oxo-3-(2-methylsulfanyl-pyrimidin-4-yl)-propionic acid methyl ester 503071-67-8 C15H13FN2O3S
    2-(4-fluorophenyl)-3-oxo-3-(2-methylsulfanyl-pyrimidin-4-yl)-propionic acid methyl ester
    —— Methyl 2,2-dimethyl-3-(4,4,4-trifluorobutylsulfonyl)propanoate 1356116-82-9 C10H17F3O4S
    Methyl 2,2-dimethyl-3-(4,4,4-trifluorobutylsulfonyl)propanoate
    —— 2,2-Dimethyl-3-(4,4,4-trifluorobutylsulfonyl)propanoic acid 1356116-84-1 C9H15F3O4S
    2,2-Dimethyl-3-(4,4,4-trifluorobutylsulfonyl)propanoic acid
    —— ethyl 7-(4-methoxyphenyl)sulfanyl-4-oxo-3H-pyrimido[4,5-b]quinoline-2-carboxylate 72784-20-4 C21H17N3O4S
    ethyl 7-(4-methoxyphenyl)sulfanyl-4-oxo-3H-pyrimido[4,5-b]quinoline-2-carboxylate
    —— 2-methyl-2-(methylsulfonyl)-4-[4-(phenylthio)phenyl]-butanoic acid 1289627-15-1 C18H20O4S2
    2-methyl-2-(methylsulfonyl)-4-[4-(phenylthio)phenyl]-butanoic acid
    —— N-hydroxy-2-methyl-2-(methylsulfonyl)-4-[4-(phenylthio)phenyl]butanamide 1289620-58-1 C18H21NO4S2
    N-hydroxy-2-methyl-2-(methylsulfonyl)-4-[4-(phenylthio)phenyl]butanamide
    —— 2-methyl-2-(methylsulfonyl)-4-[4-(phenylthio)phenyl]-N-(tetrahydro-2H-pyran-2-yloxy)butanamide 1289627-18-4 C23H29NO5S2
    2-methyl-2-(methylsulfonyl)-4-[4-(phenylthio)phenyl]-N-(tetrahydro-2H-pyran-2-yloxy)butanamide
    —— 4,6-diamino-1,2-dihydro-2,2-dimethyl-1-<3-<(phenylthio)methyl>phenyl>-s-triazine hydrochloride 87739-40-0 C18H21N5S*ClH
    4,6-diamino-1,2-dihydro-2,2-dimethyl-1-<3-<(phenylthio)methyl>phenyl>-s-triazine hydrochloride
    —— 5-(3,5-dichlorophenylthio)-2-hydroxymethyl-4-isopropyl-1-(m-nitrobenzyl)-1H-imidazole hydrochloride 178982-24-6 C20H19Cl2N3O3S*ClH
    5-(3,5-dichlorophenylthio)-2-hydroxymethyl-4-isopropyl-1-(m-nitrobenzyl)-1H-imidazole hydrochloride
    —— 3-methylsulfanyl-5-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)-[1,2,4]triazine-6-carbonitrile 478180-54-0 C16H15N5S
    3-methylsulfanyl-5-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)-[1,2,4]triazine-6-carbonitrile
    —— phenyl α-chlorocarbonylhexafluoroisopropyl sulfide 69162-16-9 C10H5ClF6OS
    phenyl α-chlorocarbonylhexafluoroisopropyl sulfide
    —— 4-(methylsulfanyl)pyridine-2-carboximidamide hydrochloride 1432681-07-6 C7H9N3S*ClH
    4-(methylsulfanyl)pyridine-2-carboximidamide hydrochloride
    —— 2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-4,7-dichloro-[1,3]dithiolo[4,5-d]pyridazine 1359021-09-2 C16H18Cl2N2S6
    2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-4,7-dichloro-[1,3]dithiolo[4,5-d]pyridazine
    —— Z-5-t-Butylthiocycloocten 64818-52-6 C12H22S
    Z-5-t-Butylthiocycloocten
    —— 2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-4,7-dimethoxy-[1,3]dithiolo[4,5-d]pyridazine 1359021-10-5 C18H24N2O2S6
    2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-4,7-dimethoxy-[1,3]dithiolo[4,5-d]pyridazine
    —— 2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-5,6-dihydro-[1,3]dithiolo[4,5-d]pyridazine-4,7-dione 1359021-05-8 C16H20N2O2S6
    2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-5,6-dihydro-[1,3]dithiolo[4,5-d]pyridazine-4,7-dione
    —— (3-fluorobenzyl)(p-tolyl)sulfane 712296-58-7 C14H13FS
    (3-fluorobenzyl)(p-tolyl)sulfane
    —— octanethiolate 134257-67-3 C8H17S
    octanethiolate
    —— 4-((4,4,5,5,5-pentafluoropentyl)sulfinyl)butan-1-ol 1332392-75-2 C9H15F5O2S
    4-((4,4,5,5,5-pentafluoropentyl)sulfinyl)butan-1-ol
    —— 2-[3-cyano-4-(3-fluorophenylthio)phenyl]thiazolo[5,4-d]pyrimidine 918880-54-3 C18H9FN4S2
    2-[3-cyano-4-(3-fluorophenylthio)phenyl]thiazolo[5,4-d]pyrimidine
    —— 2-[3-cyano-4-(2-fluorophenylthio)phenyl]thiazolo[5,4-d]pyrimidine 918880-45-2 C18H9FN4S2
    2-[3-cyano-4-(2-fluorophenylthio)phenyl]thiazolo[5,4-d]pyrimidine
    —— 2-(3-cyano-4-phenylthiophenyl)thiazolo[5,4-d]pyrimidine 918880-46-3 C18H10N4S2
    2-(3-cyano-4-phenylthiophenyl)thiazolo[5,4-d]pyrimidine
    —— 2-amino-5-[(m-fluorobenzyl)thio]-1,3,4-thiadiazole 685108-09-2 C9H8FN3S2
    2-amino-5-[(m-fluorobenzyl)thio]-1,3,4-thiadiazole
    —— 6-(4-chlorophenylthio)-2,4(1H,3H)-quinazolinedione 1354385-99-1 C14H9ClN2O2S
    6-(4-chlorophenylthio)-2,4(1H,3H)-quinazolinedione
    —— N-tert-butyl-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine 1353009-20-7 C12H22F5NO2S
    N-tert-butyl-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine
    —— 4-((4,4,5,5,5-pentafluoropentyl)thio)butan-1-ol 1332392-74-1 C9H15F5OS
    4-((4,4,5,5,5-pentafluoropentyl)thio)butan-1-ol
    —— methyl 3-{[5,6-bis(methoxymethoxy)pyridin-3-yl]sulfanyl} propanoate 1417710-69-0 C13H19NO6S
    methyl 3-{[5,6-bis(methoxymethoxy)pyridin-3-yl]sulfanyl} propanoate
    —— 5-[(3-FIuorobenzyI)sulfanyl]-2,3-bis(methoxymethoxy)-pyridine 1417710-70-3 C16H18FNO4S
    5-[(3-FIuorobenzyI)sulfanyl]-2,3-bis(methoxymethoxy)-pyridine
    —— 2-propyl-2-(10,12-dioxatridecyl)-1,3-dithiane 317801-89-1 C18H36O2S2
    2-propyl-2-(10,12-dioxatridecyl)-1,3-dithiane
    —— N-methyl-3-[(4,4,5,5,5-pentafluoropentyl)sulphinyl]propan-1-amine 228569-85-5 C9H16F5NOS
    N-methyl-3-[(4,4,5,5,5-pentafluoropentyl)sulphinyl]propan-1-amine
    —— N-{3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propyl}cyclopropanamine 1353009-18-3 C11H18F5NO2S
    N-{3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propyl}cyclopropanamine
    —— N-(2,2-difluoroethyl)-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine 1353009-22-9 C10H16F7NO2S
    N-(2,2-difluoroethyl)-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine
    —— 6-(4-fluorophenylthio)-2,4(1H,3H)-quinazolinedione 1354386-00-7 C14H9FN2O2S
    6-(4-fluorophenylthio)-2,4(1H,3H)-quinazolinedione
    —— 6-(4-tolylthio)-2,4(1H,3H)-quinazolinedione 1354385-98-0 C15H12N2O2S
    6-(4-tolylthio)-2,4(1H,3H)-quinazolinedione
    —— 2-methyl-1-({3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propyl}amino)propan-2-ol 1353009-14-9 C12H22F5NO3S
    2-methyl-1-({3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propyl}amino)propan-2-ol
    —— N-(2-fluoroethyl)-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine 1353009-17-2 C10H17F6NO2S
    N-(2-fluoroethyl)-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine
    —— 3-chloropropyl 4,4,5,5,5-pentafluoropentyl sulphide 199730-47-7 C8H12ClF5S
    3-chloropropyl 4,4,5,5,5-pentafluoropentyl sulphide
    —— 3-chloropropyl-4,4,5,5,5-pentafluoropentylsulphoxide 240121-79-3 C8H12ClF5OS
    3-chloropropyl-4,4,5,5,5-pentafluoropentylsulphoxide
    —— 2-Amino-6,7-dihydro-4-methylthio-5H-cyclopentapyrimidin 7511-83-3 C8H11N3S
    2-Amino-6,7-dihydro-4-methylthio-5H-cyclopentapyrimidin