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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N2,N4-diisopropyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diamine 1228759-19-0 C19H23N9S
    N2,N4-diisopropyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diamine
    —— 5-methyl-3-(6-methyl-2-(piperidin-1-yl)pyrimidin-4-ylthio)-5H-[1,2,4]triazino[5,6-b]indole 1228759-24-7 C20H21N7S
    5-methyl-3-(6-methyl-2-(piperidin-1-yl)pyrimidin-4-ylthio)-5H-[1,2,4]triazino[5,6-b]indole
    —— N2,N4-di-tert-butyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diamine 1228759-18-9 C21H27N9S
    N2,N4-di-tert-butyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diamine
    —— N1,N1'-(6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diyl)bis(N2,N2-dimethylethane-1,2-diamine) 1228759-22-5 C21H29N11S
    N1,N1'-(6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diyl)bis(N2,N2-dimethylethane-1,2-diamine)
    —— N-isopropyl-4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-amine 1228759-30-5 C18H19N7S
    N-isopropyl-4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-amine
    —— 3-(4,6-dichloro-1,3,5-triazin-2-ylthio)-5-methyl-5H-[1,2,4]triazino[5,6-b]indole 1228759-11-2 C13H7Cl2N7S
    3-(4,6-dichloro-1,3,5-triazin-2-ylthio)-5-methyl-5H-[1,2,4]triazino[5,6-b]indole
    —— 4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N-(2-morpholinoethyl)pyrimidin-2-amine 1228759-31-6 C21H24N8OS
    4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N-(2-morpholinoethyl)pyrimidin-2-amine
    —— 4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N-(3-morpholinopropyl)pyrimidin-2-amine 1228759-32-7 C22H26N8OS
    4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N-(3-morpholinopropyl)pyrimidin-2-amine
    —— N-tert-butyl-4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-amine 1228759-29-2 C19H21N7S
    N-tert-butyl-4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-amine
    —— N1,N1-diethyl-N2-(4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-yl)ethane-1,2-diamine 1228759-35-0 C21H26N8S
    N1,N1-diethyl-N2-(4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-yl)ethane-1,2-diamine
    —— 4-(4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-yl)morpholine 1228759-25-8 C19H19N7OS
    4-(4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-yl)morpholine
    —— 2,3-dihydrobenzo[b]thiophene-7-sulfonylisocyanate-1,1-dioxide 100594-14-7 C9H7NO5S2
    2,3-dihydrobenzo[b]thiophene-7-sulfonylisocyanate-1,1-dioxide
    —— 1,6-dihydro-3-(phenylthio)-7H-pyrrolo[2,3-c]pyridin-7-one 259684-39-4 C13H10N2OS
    1,6-dihydro-3-(phenylthio)-7H-pyrrolo[2,3-c]pyridin-7-one
    —— 2-(3-amino-2-methoxypyridin-4-yl)-2-(phenylthio)acetaldehyde dimethylacetal 259684-48-5 C16H20N2O3S
    2-(3-amino-2-methoxypyridin-4-yl)-2-(phenylthio)acetaldehyde dimethylacetal
    —— 1-Isopropyl-3-hydroxy-5-aethylthio-1,2,4-triazol 55375-82-1 C7H13N3OS
    1-Isopropyl-3-hydroxy-5-aethylthio-1,2,4-triazol
    —— O,O-dimethyl 2-chloro-1-phenylthioisopropylphosphonate 88691-18-3 C11H16ClO3PS
    O,O-dimethyl 2-chloro-1-phenylthioisopropylphosphonate
    —— 4-methoxy-6-methyl-2-(methylthio)-3-nitropyridine 179056-95-2 C8H10N2O3S
    4-methoxy-6-methyl-2-(methylthio)-3-nitropyridine
    —— 6-methyl-2-(methylthio)-3-nitro-1H-pyridin-4-one 179056-96-3 C7H8N2O3S
    6-methyl-2-(methylthio)-3-nitro-1H-pyridin-4-one
    —— 4-chloro-6-methyl-2-(methylthio)-3-nitropyridine 179056-97-4 C7H7ClN2O2S
    4-chloro-6-methyl-2-(methylthio)-3-nitropyridine
    —— 3-amino-4-chloro-6-methyl-2-(methylthio)pyridine 179055-85-7 C7H9ClN2S
    3-amino-4-chloro-6-methyl-2-(methylthio)pyridine
    —— dichloroanhydride of 2-chloro-1-phenylthioisopropylphosphonic acid 88691-20-7 C9H10Cl3OPS
    dichloroanhydride of 2-chloro-1-phenylthioisopropylphosphonic acid
    —— 2-[(5,6,7,8-Tetrahydro-2-methyl[1,2,4]triazolo[5,1-b]quinazolin-9-yl)thio]benzenamine 1211496-18-2 C16H17N5S
    2-[(5,6,7,8-Tetrahydro-2-methyl[1,2,4]triazolo[5,1-b]quinazolin-9-yl)thio]benzenamine
    —— 5-amino-2-methylthiopyrimidine-4,6-diol 884861-16-9 C5H7N3O2S
    5-amino-2-methylthiopyrimidine-4,6-diol
    —— N-Methylthiopropionimidsaeure-methylester 117966-03-7 C5H11NS
    N-Methylthiopropionimidsaeure-methylester
    —— 2-(bromophenyl-2-thioyl)tetrahydro-2H-pyran 620988-02-5 C11H13BrOS
    2-(bromophenyl-2-thioyl)tetrahydro-2H-pyran
    —— methyl (Z)-2-(N-methyl)aminomethyl-3-phenylthio-2-propenoate 156263-70-6 C12H15NO2S
    methyl (Z)-2-(N-methyl)aminomethyl-3-phenylthio-2-propenoate
    —— (+)-(S)-1-(phenylthio)pentan-2-ol 1073528-75-2 C11H16OS
    (+)-(S)-1-(phenylthio)pentan-2-ol
    —— allyl (phenylthio)ethyl ether 122396-65-0 C11H14OS
    allyl (phenylthio)ethyl ether
    —— (2-bromo-4-chloro-6-(methylthio)pyrimidin-5-yl)(phenyl)methanol 1034619-72-1 C12H10BrClN2OS
    (2-bromo-4-chloro-6-(methylthio)pyrimidin-5-yl)(phenyl)methanol
    —— 4-butylamino-6-chloro-2-methylthiopyrimidine-5-carbonitrile 169473-38-5 C10H13ClN4S
    4-butylamino-6-chloro-2-methylthiopyrimidine-5-carbonitrile
    —— 2-[4-(3-Bromopropylsulfanyl)phenyl]acetic acid 185802-94-2 C11H13BrO2S
    2-[4-(3-Bromopropylsulfanyl)phenyl]acetic acid
    —— 2-(phenylamino)-2-(2-(phenylthio)phenyl)acetonitrile 1529776-75-7 C20H16N2S
    2-(phenylamino)-2-(2-(phenylthio)phenyl)acetonitrile
    —— 2-(Phenylsulfanyl)ethyl 3-methylbut-2-enoate 60359-71-9 C13H16O2S
    2-(Phenylsulfanyl)ethyl 3-methylbut-2-enoate
    —— N-benzyl-N-[2-[4-[(4-methoxyphenyl)thio]-phenyl]ethyl]amine 477256-58-9 C22H23NOS
    N-benzyl-N-[2-[4-[(4-methoxyphenyl)thio]-phenyl]ethyl]amine
    —— tert-butyl N-(5-sec-butyl-6-chloro-2-methylthiopyrimidin-4-yl)-N-(2,2,2-trifluoroethyl)carbamate 944740-22-1 C16H23ClF3N3O2S
    tert-butyl N-(5-sec-butyl-6-chloro-2-methylthiopyrimidin-4-yl)-N-(2,2,2-trifluoroethyl)carbamate
    —— 5-<i>sec</i>-butyl-2-methylsulfanyl-1<i>H</i>-pyrimidine-4,6-dione 42039-72-5 C9H14N2O2S
    5-<i>sec</i>-butyl-2-methylsulfanyl-1<i>H</i>-pyrimidine-4,6-dione
    —— 4-difluoromethylthiophenyl isocyanate 50844-56-9 C8H5F2NOS
    4-difluoromethylthiophenyl isocyanate
    —— Acetic acid, methoxy-, 2-(phenylthio)ethyl ester 60359-69-5 C11H14O3S
    Acetic acid, methoxy-, 2-(phenylthio)ethyl ester
    —— dimethyl 1-[2-(phenylthio)ethyl]-1H-1,2,3-triazole-4,5-dicarboxylate 478626-19-6 C14H15N3O4S
    dimethyl 1-[2-(phenylthio)ethyl]-1H-1,2,3-triazole-4,5-dicarboxylate
    —— 2-(Phenylthio)ethyl formate 91228-20-5 C9H10O2S
    2-(Phenylthio)ethyl formate
    —— dimethyl 2-[2-(phenylthio)ethyl]-2H-1,2,3-triazole-4,5-dicarboxylate 478626-21-0 C14H15N3O4S
    dimethyl 2-[2-(phenylthio)ethyl]-2H-1,2,3-triazole-4,5-dicarboxylate
    —— (6-amino-4-methylsulfanyl-pyridin-2-yl)-methanol 1158787-60-0 C7H10N2OS
    (6-amino-4-methylsulfanyl-pyridin-2-yl)-methanol
    —— 1-(4-pyridyl)-3-(5-(4-thiazolyl)methylthio-2-pyridyloxy)pyrrolidine 194667-88-4 C18H18N4OS2
    1-(4-pyridyl)-3-(5-(4-thiazolyl)methylthio-2-pyridyloxy)pyrrolidine
    —— 5-(2,3-dichlorophenylsulfanyl)-N-methyl-4-nitrothiophene-2-carboxamide 1247820-22-9 C12H8Cl2N2O3S2
    5-(2,3-dichlorophenylsulfanyl)-N-methyl-4-nitrothiophene-2-carboxamide
    —— S-2,3-dichloroallyl di-isopropylthiocarbamate 17708-57-5 C10H17Cl2NOS
    S-2,3-dichloroallyl di-isopropylthiocarbamate
    —— 1-bromo-4-[(3-methylbut-3-en-1-yl)sulfanyl]benzene 1360916-04-6 C11H13BrS
    1-bromo-4-[(3-methylbut-3-en-1-yl)sulfanyl]benzene
    —— 2-chloro-5-(4-thiazolyl)methylthiopyridine 194668-58-1 C9H7ClN2S2
    2-chloro-5-(4-thiazolyl)methylthiopyridine
    —— tert-pentylthioethanol 26901-96-2 C7H16OS
    tert-pentylthioethanol
    —— 1,8-Dithiophenyl-3,6-dioxyoctan 30983-01-8 C18H22O2S2
    1,8-Dithiophenyl-3,6-dioxyoctan
    —— 1,2-bis(2-(pyridin-2-ylthio)ethoxy)ethane 501935-17-7 C16H20N2O2S2
    1,2-bis(2-(pyridin-2-ylthio)ethoxy)ethane