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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6,11:21,26-dimethano-1,16-dithia<30>annulene 128654-24-0 C30H28S2
    6,11:21,26-dimethano-1,16-dithia<30>annulene
    —— 4,9:17,22-dimethano-1,14-dithia<26>annulene 128677-59-8 C26H24S2
    4,9:17,22-dimethano-1,14-dithia<26>annulene
    —— 4-ethanesulfonyl-butan-2-one 136819-47-1 C6H12O3S
    4-ethanesulfonyl-butan-2-one
    —— phenyl 1-methyl-1-phenyl-2-propynyl sulfide 928842-71-1 C16H14S
    phenyl 1-methyl-1-phenyl-2-propynyl sulfide
    —— phenyl 1,3-dimethyl-1-phenyl-2-propynyl sulfide 928842-77-7 C17H16S
    phenyl 1,3-dimethyl-1-phenyl-2-propynyl sulfide
    —— Trimethyl-((E)-1-phenylsulfanyl-undeca-1,10-dienyloxy)-silane 68117-67-9 C20H32OSSi
    Trimethyl-((E)-1-phenylsulfanyl-undeca-1,10-dienyloxy)-silane
    —— 2-(2,2-Diethoxy-ethylsulfanyl)-1,4-dimethyl-benzene 1026131-47-4 C14H22O2S
    2-(2,2-Diethoxy-ethylsulfanyl)-1,4-dimethyl-benzene
    —— 1-(4-bromo-phenylsulfanyl)-3,5-bis-trifluoromethyl-benzene 1451093-05-2 C14H7BrF6S
    1-(4-bromo-phenylsulfanyl)-3,5-bis-trifluoromethyl-benzene
    —— 2-(2-Chlorophenyl)sulfanyl-1-(2,5-dichlorothiophen-3-yl)ethanone 1152628-27-7 C12H7Cl3OS2
    2-(2-Chlorophenyl)sulfanyl-1-(2,5-dichlorothiophen-3-yl)ethanone
    —— 3-chloro-4-methylthiophenylacetic thiomorpholide 947701-14-6 C13H16ClNOS2
    3-chloro-4-methylthiophenylacetic thiomorpholide
    —— Diselenadithiafulvalen 55681-24-8 C6H4S2Se2
    Diselenadithiafulvalen
    —— dibenzo[b,f][1,4,5]thiadiazepine 257-17-0 C12H8N2S
    dibenzo[b,f][1,4,5]thiadiazepine
    —— Benzyl-[3-(benzyl-tert-butoxycarbonyl-amino)-2-oxo-3-phenylsulfanyl-propyl]-carbamic acid tert-butyl ester 253590-93-1 C33H40N2O5S
    Benzyl-[3-(benzyl-tert-butoxycarbonyl-amino)-2-oxo-3-phenylsulfanyl-propyl]-carbamic acid tert-butyl ester
    —— 2,4,5-tri(2-bromophenylthio)-3,6-difluoropyridine 1292800-79-3 C23H12Br3F2NS3
    2,4,5-tri(2-bromophenylthio)-3,6-difluoropyridine
    —— 2-(2-bromophenylthio)-N-tert-butylbenzamide 1002759-94-5 C17H18BrNOS
    2-(2-bromophenylthio)-N-tert-butylbenzamide
    —— 1-<2,2-Dimethyl-1-(methylthio)propylthio>-2-fluorbenzol 116865-00-0 C12H17FS2
    1-<2,2-Dimethyl-1-(methylthio)propylthio>-2-fluorbenzol
    —— 2-Trimethylsilylthioanisol 33356-46-6 C10H16SSi
    2-Trimethylsilylthioanisol
    —— 5-<3',3'-(ethylenedithio)pentyl>pyrrolidin-2-one 116454-72-9 C11H19NOS2
    5-<3',3'-(ethylenedithio)pentyl>pyrrolidin-2-one
    —— <i>N</i>,<i>N</i>'-(2,2'-sulfanediyl-diphenyl)-bis-hydroxylamine 69341-53-3 C12H12N2O2S
    <i>N</i>,<i>N</i>'-(2,2'-sulfanediyl-diphenyl)-bis-hydroxylamine
    —— 2-[(4-methylsulfanylphenyl)methylidene]-6,7-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidin-3-one 731821-54-8 C14H14N2OS2
    2-[(4-methylsulfanylphenyl)methylidene]-6,7-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidin-3-one
    —— (2-bromobenzyl)(2-bromophenyl)sulfane 71403-31-1 C13H10Br2S
    (2-bromobenzyl)(2-bromophenyl)sulfane
    —— Pyridine amide, 11 912923-82-1 C18H19ClN2OS
    Pyridine amide, 11
    —— (1'R,2R,5R,6R)-5-[1'-(2-bromophenyl)sulfanylisobutyl]-2-tert-butyl-6-methyl-1,3-dioxan-4-one 334816-39-6 C19H27BrO3S
    (1'R,2R,5R,6R)-5-[1'-(2-bromophenyl)sulfanylisobutyl]-2-tert-butyl-6-methyl-1,3-dioxan-4-one
    —— 2,3-diethylthiopropanal 77890-03-0 C7H14OS2
    2,3-diethylthiopropanal
    —— 3-ethyl-2,3-dihydrobenzo[b]thiophene 6383-23-9 C10H12S
    3-ethyl-2,3-dihydrobenzo[b]thiophene
    —— (S)-3-(2-bromophenylthio)cyclohexanone 1215843-27-8 C12H13BrOS
    (S)-3-(2-bromophenylthio)cyclohexanone
    —— (1'R,2R,5R,6R)-5-[1'-(2-bromophenyl)sulfanylethyl]-2-tert-butyl-6-methyl-1,3-dioxan-4-one 334816-35-2 C17H23BrO3S
    (1'R,2R,5R,6R)-5-[1'-(2-bromophenyl)sulfanylethyl]-2-tert-butyl-6-methyl-1,3-dioxan-4-one
    —— 1,3-Benzodithiole, methyl-2-(7-(methyl-1,3-benzodithiol-2-ylidene)bicyclo(4.4.1)undeca-3,5,8,10-tetraen-2-ylidene)-, 1-oxide 82801-75-0 C27H20OS4
    1,3-Benzodithiole, methyl-2-(7-(methyl-1,3-benzodithiol-2-ylidene)bicyclo(4.4.1)undeca-3,5,8,10-tetraen-2-ylidene)-, 1-oxide
    —— benzothiirene 65330-66-7 C6H4S
    benzothiirene
    —— 2'-Brom-4-chlor-5-hydroxy-2-nitro-diphenylsulfid 17844-93-8 C12H7BrClNO3S
    2'-Brom-4-chlor-5-hydroxy-2-nitro-diphenylsulfid
    —— (E)-3-(2-bromophenyl)-1-(4-chlorophenyl)-3-methylaminopropenethione 449814-60-2 C16H13BrClNS2
    (E)-3-(2-bromophenyl)-1-(4-chlorophenyl)-3-methylaminopropenethione
    —— 3,4,5,6-tetrahydro-2H-benzo[b][1,4]thiazocine 46047-92-1 C10H13NS
    3,4,5,6-tetrahydro-2H-benzo[b][1,4]thiazocine
    —— 2-(2-Bromo-phenylsulfanyl)-5-trifluoromethyl-phenylamine 328-14-3 C13H9BrF3NS
    2-(2-Bromo-phenylsulfanyl)-5-trifluoromethyl-phenylamine
    —— 1,3,3a,8b-Tetrahydro-benzo[b]thieno[3,4-d]thiophene 2,2-dioxide 194085-43-3 C10H10O2S2
    1,3,3a,8b-Tetrahydro-benzo[b]thieno[3,4-d]thiophene 2,2-dioxide
    —— 2-(((2-bromophenyl)thio)methyl)pyridine 83782-30-3 C12H10BrNS
    2-(((2-bromophenyl)thio)methyl)pyridine
    —— 4-(2-Bromo-phenylsulfanyl)-3-trifluoromethyl-benzaldehyde 387873-59-8 C14H8BrF3OS
    4-(2-Bromo-phenylsulfanyl)-3-trifluoromethyl-benzaldehyde
    —— (E)-3-(2-bromophenylthio)-3-methylamino-1-phenylpropenethione 449814-56-6 C16H14BrNS2
    (E)-3-(2-bromophenylthio)-3-methylamino-1-phenylpropenethione
    —— 2-((2-bromophenyl)thio)benzene-1,4-diol 1310712-82-3 C12H9BrO2S
    2-((2-bromophenyl)thio)benzene-1,4-diol
    —— (1'S,2R,5R,6R)-5-[1'-(2-bromophenyl)sulfanylisobutyl]-2-tert-butyl-6-methyl-1,3-dioxan-4-one 334816-51-2 C19H27BrO3S
    (1'S,2R,5R,6R)-5-[1'-(2-bromophenyl)sulfanylisobutyl]-2-tert-butyl-6-methyl-1,3-dioxan-4-one
    —— 2-(2-bromophenylthio)-N,N-dimethylethanamine 1222866-87-6 C10H14BrNS
    2-(2-bromophenylthio)-N,N-dimethylethanamine
    —— 3-(difluoromethyl)-2,3-dihydrobenzo[b]thiophene 1565823-42-8 C9H8F2S
    3-(difluoromethyl)-2,3-dihydrobenzo[b]thiophene
    —— 1-Bromo-2-[3-(2-bromophenyl)sulfanylpropylsulfanyl]benzene 869336-01-6 C15H14Br2S2
    1-Bromo-2-[3-(2-bromophenyl)sulfanylpropylsulfanyl]benzene
    —— 4-Methyl-2-methylsulfanyl-5-oxo-8,9,10,11-tetrahydro-5H,7H,16bH-6-oxa-12-thia-1,3-diaza-dibenzo[a,c]cyclododecene-1-carboxylic acid tert-butyl ester 145457-88-1 C23H30N2O4S2
    4-Methyl-2-methylsulfanyl-5-oxo-8,9,10,11-tetrahydro-5H,7H,16bH-6-oxa-12-thia-1,3-diaza-dibenzo[a,c]cyclododecene-1-carboxylic acid tert-butyl ester
    —— (1'R,2R,5R,6R)-5-[1'-(2-bromophenyl)sulfanylpropyl]-2-tert-butyl-6-methyl-1,3-dioxan-4-one 334816-37-4 C18H25BrO3S
    (1'R,2R,5R,6R)-5-[1'-(2-bromophenyl)sulfanylpropyl]-2-tert-butyl-6-methyl-1,3-dioxan-4-one
    —— 2-<(2-Acetoxyethyl)thio>bromobenzene 117341-25-0 C10H11BrO2S
    2-<(2-Acetoxyethyl)thio>bromobenzene
    —— 4-(2-bromobenzenethio)tetrafluoropyridine 1292800-78-2 C11H4BrF4NS
    4-(2-bromobenzenethio)tetrafluoropyridine
    —— (2-bromophenyl)(methyl-d3)sulfane 892416-07-8 C7H7BrS
    (2-bromophenyl)(methyl-d3)sulfane
    —— (1'S,2R,5R,6R)-5-{1'-[(2-bromophenyl)sulfanyl]-3'-phenylpropyl}-2-tert-butyl-6-methyl-1,3-dioxan-4-one 334816-53-4 C24H29BrO3S
    (1'S,2R,5R,6R)-5-{1'-[(2-bromophenyl)sulfanyl]-3'-phenylpropyl}-2-tert-butyl-6-methyl-1,3-dioxan-4-one
    —— (1'S,2R,5R,6R)-5-[1'-(2-bromophenyl)sulfanylpropyl]-2-tert-butyl-6-methyl-1,3-dioxan-4-one 334816-49-8 C18H25BrO3S
    (1'S,2R,5R,6R)-5-[1'-(2-bromophenyl)sulfanylpropyl]-2-tert-butyl-6-methyl-1,3-dioxan-4-one
    —— o-Bromophenyl 2-chloro-1-pentyl sulfide 54403-51-9 C11H14BrClS
    o-Bromophenyl 2-chloro-1-pentyl sulfide