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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,3-dihydro-2,5-dimethyl-1,4-dithiin 61947-19-1 C6H10S2
    2,3-dihydro-2,5-dimethyl-1,4-dithiin
    —— 1,2-bis(methylthio)propane 67560-48-9 C5H12S2
    1,2-bis(methylthio)propane
    —— 2,3-dihydro-2,6-dimethyl-1,4-dithiin 61947-20-4 C6H10S2
    2,3-dihydro-2,6-dimethyl-1,4-dithiin
    —— 2-ethyl-5,6-dihydro-6-methyl-1,4-dithiin 61947-22-6 C7H12S2
    2-ethyl-5,6-dihydro-6-methyl-1,4-dithiin
    —— 2-ethyl-5,6-dihydro-5-methyl-1,4-dithiin 61947-21-5 C7H12S2
    2-ethyl-5,6-dihydro-5-methyl-1,4-dithiin
    —— 2,9-dimercapto-3,5,8-trimethyl-4,7-dithia-decane 78010-95-4 C11H24S4
    2,9-dimercapto-3,5,8-trimethyl-4,7-dithia-decane
    —— 2,2'-dimethoxy-6,4'-bis-methylsulfanyl-[4,5']bipyrimidinyl 59549-55-2 C12H14N4O2S2
    2,2'-dimethoxy-6,4'-bis-methylsulfanyl-[4,5']bipyrimidinyl
    —— 6-phenylsulfanyl-[1,2,4]triazolo[4,3-<i>b</i>]pyridazine 99974-48-8 C11H8N4S
    6-phenylsulfanyl-[1,2,4]triazolo[4,3-<i>b</i>]pyridazine
    —— 4-Nitro-3',4',5'-trimethoxydiphenylsulfide 24891-42-7 C15H15NO5S
    4-Nitro-3',4',5'-trimethoxydiphenylsulfide
    —— 1-{[4-(Bromomethyl)phenyl]thio}-2-nitro-4-(trifluoromethyl)benzene 650615-78-4 C14H9BrF3NO2S
    1-{[4-(Bromomethyl)phenyl]thio}-2-nitro-4-(trifluoromethyl)benzene
    —— 2-acetoxymethyl-2,3-dihydrobenzothiophene 99338-94-0 C11H12O2S
    2-acetoxymethyl-2,3-dihydrobenzothiophene
    —— methylenedithiotetrathiafulvalene 118148-29-1 C7H4S6
    methylenedithiotetrathiafulvalene
    —— 3,4,5-tris(methylsulfanyl)-1,2-dithiolium iodide 82504-66-3 C6H9S5*I
    3,4,5-tris(methylsulfanyl)-1,2-dithiolium iodide
    —— (R)-(-)-2-methylbutyl phenyl sulfide 87106-26-1 C11H16S
    (R)-(-)-2-methylbutyl phenyl sulfide
    —— 1-(pentafluorophenylsulfanyl)hex-5-en-2-one 165531-79-3 C12H9F5OS
    1-(pentafluorophenylsulfanyl)hex-5-en-2-one
    —— 2,4-Dihydroxy-6-(2-naphthylthio)chinazolin 52979-05-2 C18H12N2O2S
    2,4-Dihydroxy-6-(2-naphthylthio)chinazolin
    —— Ethyl 2-amino-5-[2-naphthylthio]benzoate 52979-20-1 C19H17NO2S
    Ethyl 2-amino-5-[2-naphthylthio]benzoate
    —— 1-Chloro-3-(pyridin-4-ylthio)propane 134186-64-4 C8H10ClNS
    1-Chloro-3-(pyridin-4-ylthio)propane
    —— 4,5,6,4',5',6'-Hexamethyl-5H,5'H-[2,2']bi[[1,3]dithiolo[4,5-c]pyrrolylidene] 183479-89-2 C16H18N2S4
    4,5,6,4',5',6'-Hexamethyl-5H,5'H-[2,2']bi[[1,3]dithiolo[4,5-c]pyrrolylidene]
    —— S-Ethyl-N,N'-dimethylisothioharnstoff —— C5H12N2S
    S-Ethyl-N,N'-dimethylisothioharnstoff
    —— 2,4-Dioxo-3-phenyl-6-p-tolylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde 80947-66-6 C18H14N2O3S
    2,4-Dioxo-3-phenyl-6-p-tolylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde
    —— 4-(2-chloropyridin-4-ylthio)naphthalen-1-amine 1338815-51-2 C15H11ClN2S
    4-(2-chloropyridin-4-ylthio)naphthalen-1-amine
    —— 2,4-Dioxo-3-phenyl-6-phenylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde 80947-64-4 C17H12N2O3S
    2,4-Dioxo-3-phenyl-6-phenylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde
    —— 6-(4-Chloro-phenylsulfanyl)-2,4-dioxo-3-phenyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde 80947-65-5 C17H11ClN2O3S
    6-(4-Chloro-phenylsulfanyl)-2,4-dioxo-3-phenyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde
    —— 3-Phenyl-6-p-tolylsulfanyl-1H-pyrimidine-2,4-dione 80947-56-4 C17H14N2O2S
    3-Phenyl-6-p-tolylsulfanyl-1H-pyrimidine-2,4-dione
    —— 3-Phenyl-6-phenylsulfanyl-1H-pyrimidine-2,4-dione 80947-54-2 C16H12N2O2S
    3-Phenyl-6-phenylsulfanyl-1H-pyrimidine-2,4-dione
    —— 6-(4-Chloro-phenylsulfanyl)-3-phenyl-1H-pyrimidine-2,4-dione 80947-55-3 C16H11ClN2O2S
    6-(4-Chloro-phenylsulfanyl)-3-phenyl-1H-pyrimidine-2,4-dione
    —— 2,3-Dihydrothiepin 37996-46-6 C6H8S
    2,3-Dihydrothiepin
    —— (R)-N-((S)-2,2-difluoro-1-(3-fluorophenyl)-2-(phenylthio)ethyl)-2-methylpropane-2-sulfinamide 1365214-60-3 C18H20F3NOS2
    (R)-N-((S)-2,2-difluoro-1-(3-fluorophenyl)-2-(phenylthio)ethyl)-2-methylpropane-2-sulfinamide
    —— 5-tert-butyldimethylsiloxymethyl-1-phenylthiomethyl-2,6,6-trimethyl-1-cyclohexene 171504-25-9 C23H38OSSi
    5-tert-butyldimethylsiloxymethyl-1-phenylthiomethyl-2,6,6-trimethyl-1-cyclohexene
    —— 2,3-diisothiocyanatobuta-1,3-diene 137768-86-6 C6H4N2S2
    2,3-diisothiocyanatobuta-1,3-diene
    —— (S)-N-(2,2-difluoro-1-(3-fluorophenyl)-2-(phenylthio)ethyl)prop-2-en-1-amine 1365214-61-4 C17H16F3NS
    (S)-N-(2,2-difluoro-1-(3-fluorophenyl)-2-(phenylthio)ethyl)prop-2-en-1-amine
    —— 5-methylmercapto-1,2,3-thiadiazole 106220-55-7 C3H4N2S2
    5-methylmercapto-1,2,3-thiadiazole
    —— 3-Bromo-2-methylsulfanyl-furan 57102-25-7 C5H5BrOS
    3-Bromo-2-methylsulfanyl-furan
    —— 1-acetoxy-4-methyl-3-phenylthio-2-pentanone 69798-60-3 C14H18O3S
    1-acetoxy-4-methyl-3-phenylthio-2-pentanone
    —— 1-chloro-4-methyl-3-phenylthio-2-pentanone 69798-75-0 C12H15ClOS
    1-chloro-4-methyl-3-phenylthio-2-pentanone
    —— 2,2-Bis-ethylsulfanyl-pentanedioic acid dimethyl ester 43227-76-5 C11H20O4S2
    2,2-Bis-ethylsulfanyl-pentanedioic acid dimethyl ester
    —— 3-Bromo-4-methyl-2-methylsulfanyl-furan 204760-88-3 C6H7BrOS
    3-Bromo-4-methyl-2-methylsulfanyl-furan
    —— 4-Methylthio-3-buten-1-yne 3448-56-4 C5H6S
    4-Methylthio-3-buten-1-yne
    —— 2,2-Bis-ethylsulfanyl-5-oxo-hexanenitrile 89450-19-1 C10H17NOS2
    2,2-Bis-ethylsulfanyl-5-oxo-hexanenitrile
    —— Bis-ethylsulfanyl-(3-oxo-cyclohexyl)-acetic acid methyl ester 43227-87-8 C13H22O3S2
    Bis-ethylsulfanyl-(3-oxo-cyclohexyl)-acetic acid methyl ester
    —— 4-Cyano-4,4-bis-ethylsulfanyl-butyric acid methyl ester 89450-20-4 C10H17NO2S2
    4-Cyano-4,4-bis-ethylsulfanyl-butyric acid methyl ester
    —— (Z)-2,2,8,8-Tetrakis-ethylsulfanyl-4-formyl-non-4-enedinitrile 89450-26-0 C18H28N2OS4
    (Z)-2,2,8,8-Tetrakis-ethylsulfanyl-4-formyl-non-4-enedinitrile
    —— (2R,3R,8R,4E,6E)-8-tert-butyldimethylsilyloxy-2-chloroacetoxy-3-phenylthiotrideca-4,6-dienyl 2,2-dimethylpropanoate 286930-14-1 C32H51ClO5SSi
    (2R,3R,8R,4E,6E)-8-tert-butyldimethylsilyloxy-2-chloroacetoxy-3-phenylthiotrideca-4,6-dienyl 2,2-dimethylpropanoate
    —— 2,2-Bis-ethylsulfanyl-5-oxo-pentanenitrile 89450-24-8 C9H15NOS2
    2,2-Bis-ethylsulfanyl-5-oxo-pentanenitrile
    —— 3-Methanesulfinyl-4-thia-1,2-diaza-spiro[5.5]undec-2-ene-5-carboxylic acid ethyl ester 172472-26-3 C12H20N2O3S2
    3-Methanesulfinyl-4-thia-1,2-diaza-spiro[5.5]undec-2-ene-5-carboxylic acid ethyl ester
    —— 3-Methanesulfonyl-hept-6-en-2-ol 568578-32-5 C8H16O3S
    3-Methanesulfonyl-hept-6-en-2-ol
    —— (E)-thiacyclonon-4-ene 1,1-dioxide 79760-37-5 C8H14O2S
    (E)-thiacyclonon-4-ene 1,1-dioxide
    —— ((4-(tert-butylthio)phenyl)ethynyl)triisopropylsilane 795274-48-5 C21H34SSi
    ((4-(tert-butylthio)phenyl)ethynyl)triisopropylsilane
    —— 5-(tert-butyl)-3-(phenylthiomethyl)pyrazole 493038-65-6 C14H18N2S
    5-(tert-butyl)-3-(phenylthiomethyl)pyrazole