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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Amino-6-(2-chlor-5-methyl-pyrimidinyl-(4)-mercapto)-purin 90800-00-3 C10H8ClN7S
    2-Amino-6-(2-chlor-5-methyl-pyrimidinyl-(4)-mercapto)-purin
    —— N-(4-methylthiophenyl)-N'-[2-(2-trimethylsilylethynyl)phenyl]carbodiimide 450380-96-8 C19H20N2SSi
    N-(4-methylthiophenyl)-N'-[2-(2-trimethylsilylethynyl)phenyl]carbodiimide
    —— N-<2-<(4-methylphenyl)thio>ethyl>propanamide 82772-76-7 C12H17NOS
    N-<2-<(4-methylphenyl)thio>ethyl>propanamide
    —— (diisopropylthiocarbamoylsulfanyl)methyl diisopropyldithiocarbamate 90276-57-6 C15H30N2S4
    (diisopropylthiocarbamoylsulfanyl)methyl diisopropyldithiocarbamate
    —— 1,3-dimethyl-6-sulfanylidene-8-thiophen-2-ylsulfanyl-7H-purin-2-one 6492-89-3 C11H10N4OS3
    1,3-dimethyl-6-sulfanylidene-8-thiophen-2-ylsulfanyl-7H-purin-2-one
    —— 4-(o-Hydroxybenzylidene)-4'-nitrodiphenylsulfid 20162-20-3 C19H14N2O3S
    4-(o-Hydroxybenzylidene)-4'-nitrodiphenylsulfid
    —— 1-(cyclohexylamino)-3-[(5-pyrazin-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propan-2-ol 134744-89-1 C15H22N6OS
    1-(cyclohexylamino)-3-[(5-pyrazin-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propan-2-ol
    —— 13,19,36,37-tetraaza-6,16,26-trioxa-3,9,11,21,23,29-hexathiotetracyclo-[29,3,1,1(10,13),1(19,22)]-heptatriaconta-1(35),10(36),22(37),31(32),33(34)-pentaene-12,20-dione 1041201-00-6 C24H32N4O5S6
    13,19,36,37-tetraaza-6,16,26-trioxa-3,9,11,21,23,29-hexathiotetracyclo-[29,3,1,1(10,13),1(19,22)]-heptatriaconta-1(35),10(36),22(37),31(32),33(34)-pentaene-12,20-dione
    —— 11-thiamethylundecylisothiocyanate 144027-76-9 C13H25NS2
    11-thiamethylundecylisothiocyanate
    —— DL-2-Amino-butyl-isothioharnstoff 63679-68-5 C5H13N3S
    DL-2-Amino-butyl-isothioharnstoff
    —— 6-(2-ethyl-5-nitro-3-propyl-3<i>H</i>-imidazol-4-ylsulfanyl)-7(9)<i>H</i>-purine 4526-64-1 C13H15N7O2S
    6-(2-ethyl-5-nitro-3-propyl-3<i>H</i>-imidazol-4-ylsulfanyl)-7(9)<i>H</i>-purine
    —— 2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetamide 886510-60-7 C10H8ClN3O2S
    2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetamide
    —— 9-amino-1,4,6,8-tetraazabenzo<b>phenothiazine 81562-25-6 C12H8N6S
    9-amino-1,4,6,8-tetraazabenzo<b>phenothiazine
    —— 5-methylthio-[1,2,5]thiadiazolo[3,4-d]pyrimidin-7(6H)-one 62700-64-5 C5H4N4OS2
    5-methylthio-[1,2,5]thiadiazolo[3,4-d]pyrimidin-7(6H)-one
    —— 4-Amino-2-(methylamino)-6-(methylsulfanyl)pyrimidine-5-carbonitrile 112637-52-2 C7H9N5S
    4-Amino-2-(methylamino)-6-(methylsulfanyl)pyrimidine-5-carbonitrile
    —— 2-[[5-(1-Benzyl-5-oxopyrrolidin-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid 129913-26-4 C16H18N4O3S
    2-[[5-(1-Benzyl-5-oxopyrrolidin-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-methyl-4-phenylthio-5,7-dihydrothieno<3,4-d>pyrimidine 6,6-dioxide 154697-87-7 C13H12N2O2S2
    2-methyl-4-phenylthio-5,7-dihydrothieno<3,4-d>pyrimidine 6,6-dioxide
    —— Acetic acid, ((4-(dibutylamino)-6-methyl-2-pyrimidinyl)thio)-, hydrazide 77940-24-0 C15H27N5OS
    Acetic acid, ((4-(dibutylamino)-6-methyl-2-pyrimidinyl)thio)-, hydrazide
    —— Methyl 2-(4-methyl-6-piperidin-1-ylpyrimidin-2-yl)sulfanylacetate 77940-21-7 C13H19N3O2S
    Methyl 2-(4-methyl-6-piperidin-1-ylpyrimidin-2-yl)sulfanylacetate
    —— Methyl 2-{[4-methyl-6-(morpholin-4-YL)pyrimidin-2-YL]sulfanyl}acetate 77940-22-8 C12H17N3O3S
    Methyl 2-{[4-methyl-6-(morpholin-4-YL)pyrimidin-2-YL]sulfanyl}acetate
    —— Acetic acid, ((6-methyl-4-piperidino-2-pyrimidinyl)thio)-, hydrazide 77940-25-1 C12H19N5OS
    Acetic acid, ((6-methyl-4-piperidino-2-pyrimidinyl)thio)-, hydrazide
    —— Acetic acid, ((6-methyl-4-morpholino-2-pyrimidinyl)thio)-, hydrazide 77965-40-3 C11H17N5O2S
    Acetic acid, ((6-methyl-4-morpholino-2-pyrimidinyl)thio)-, hydrazide
    —— ethyl <4-(4'-methylphenyl)thiazol-2-ylthio>acetate 112779-70-1 C14H15NO2S2
    ethyl <4-(4'-methylphenyl)thiazol-2-ylthio>acetate
    —— 1-Methylsulfonylsulfanyltriacontane 887407-63-8 C31H64O2S2
    1-Methylsulfonylsulfanyltriacontane
    —— 3-Methyl-3-phenylsulfanyl-5-propanoyloxan-2-one 89665-24-7 C15H18O3S
    3-Methyl-3-phenylsulfanyl-5-propanoyloxan-2-one
    —— 2,4-dithiaoctane 29098-64-4 C6H14S2
    2,4-dithiaoctane
    —— β-(p-Brom-phenylmercapto)-ethanthiol 19366-34-8 C8H9BrS2
    β-(p-Brom-phenylmercapto)-ethanthiol
    —— (8-chloro-octyl)-methyl sulfide 98956-33-3 C9H19ClS
    (8-chloro-octyl)-methyl sulfide
    —— 1,1-Dimethyl-3-(prop-2-ynoxymethyl)thiourea 81066-26-4 C7H12N2OS
    1,1-Dimethyl-3-(prop-2-ynoxymethyl)thiourea
    —— Isobutyl-neopentyl-sulfoxd 10269-13-3 C9H20OS
    Isobutyl-neopentyl-sulfoxd
    —— (2S)-1-[(2S)-oxiran-2-yl]-4-phenylsulfanylbutan-2-ol 197520-81-3 C12H16O2S
    (2S)-1-[(2S)-oxiran-2-yl]-4-phenylsulfanylbutan-2-ol
    —— [(2R,4S)-1,4-dihydroxy-6-phenylsulfanylhexan-2-yl] methanesulfonate 197520-80-2 C13H20O5S2
    [(2R,4S)-1,4-dihydroxy-6-phenylsulfanylhexan-2-yl] methanesulfonate
    —— 4-((4-chlorophenyl)thio)-4-(p-tolyl)butan-2-one 1420293-48-6 C17H17ClOS
    4-((4-chlorophenyl)thio)-4-(p-tolyl)butan-2-one
    —— N-((5-(2-(methylthio)phenyl)isoxazol-3-yl)methyl)adamantan-1-amine 1443123-69-0 C21H26N2OS
    N-((5-(2-(methylthio)phenyl)isoxazol-3-yl)methyl)adamantan-1-amine
    —— Methyl (S)-2-hydroxy-2-<<(4-methylphenyl)sulfenyl>methyl>hexadecanoate 154079-05-7 C25H42O3S
    Methyl (S)-2-hydroxy-2-<<(4-methylphenyl)sulfenyl>methyl>hexadecanoate
    —— β-Vinylsulfonyl-propionsaeure-amid 1562-41-0 C5H9NO3S
    β-Vinylsulfonyl-propionsaeure-amid
    —— 3-(2-chloroethylsulfonyl)-N-[[3-(2-chloroethylsulfonyl)propanoylamino]methyl]propanamide 42514-09-0 C11H20Cl2N2O6S2
    3-(2-chloroethylsulfonyl)-N-[[3-(2-chloroethylsulfonyl)propanoylamino]methyl]propanamide
    —— 2,7-Dimethyl-4,5-dioxo-3,6-dioxa-9-thia-3,4,5,6,9,10-hexahydroanthracene 101560-45-6 C13H10O4S
    2,7-Dimethyl-4,5-dioxo-3,6-dioxa-9-thia-3,4,5,6,9,10-hexahydroanthracene
    —— 5-Acetyl-3-methyl-3-phenylsulfanyloxan-2-one 89665-22-5 C14H16O3S
    5-Acetyl-3-methyl-3-phenylsulfanyloxan-2-one
    —— 4-amino-2,3-dihydro-3-phenyl-6-thioxo-6H-thieno[3,2-c]thiopyran-7-carbonitrile 1222510-76-0 C14H10N2S3
    4-amino-2,3-dihydro-3-phenyl-6-thioxo-6H-thieno[3,2-c]thiopyran-7-carbonitrile
    —— Pyridinium, 2,2'-[1,5-pentanediylbis(thio)]bis[1-methyl- 184679-70-7 C17H24N2S2+2
    Pyridinium, 2,2'-[1,5-pentanediylbis(thio)]bis[1-methyl-
    —— 2-hydroxymethyl(6-tert-butylbenzo)-4-oxathiane 113769-02-1 C13H18O2S
    2-hydroxymethyl(6-tert-butylbenzo)-4-oxathiane
    —— 5-(4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-yl)-2-propylthio-1,3,4-oxadiazole 313257-96-4 C11H15ClN4OS
    5-(4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-yl)-2-propylthio-1,3,4-oxadiazole
    —— 1-[5-(4-Bromo-phenyl)-[1,3,4]oxadiazol-2-ylsulfanyl]-propan-2-one 81555-90-0 C11H9BrN2O2S
    1-[5-(4-Bromo-phenyl)-[1,3,4]oxadiazol-2-ylsulfanyl]-propan-2-one
    —— 4-isopropyl-3',3',5,5',5'-pentamethyl-2H-1,3-oxathiole-2-spiro-4',3',5'-dihydropyrazole 114522-86-0 C13H22N2OS
    4-isopropyl-3',3',5,5',5'-pentamethyl-2H-1,3-oxathiole-2-spiro-4',3',5'-dihydropyrazole
    —— thiophosphoric acid <i>O</i>,<i>O</i>'-diethyl ester <i>S</i>-(5-methylsulfanyl-[1,3,4]thiadiazol-2-ylmethyl) ester 38090-94-7 C8H15N2O3PS3
    thiophosphoric acid <i>O</i>,<i>O</i>'-diethyl ester <i>S</i>-(5-methylsulfanyl-[1,3,4]thiadiazol-2-ylmethyl) ester
    —— dithiophosphoric acid <i>O</i>,<i>O</i>'-dimethyl ester <i>S</i>-(5-methylsulfanyl-[1,3,4]thiadiazol-2-ylmethyl) ester 38090-92-5 C6H11N2O2PS4
    dithiophosphoric acid <i>O</i>,<i>O</i>'-dimethyl ester <i>S</i>-(5-methylsulfanyl-[1,3,4]thiadiazol-2-ylmethyl) ester
    —— 2-(4-chlorophenyl)-5-cyano-4-methylsulfanyl-1H-pyrimidin-6-one 87693-97-8 C12H8ClN3OS
    2-(4-chlorophenyl)-5-cyano-4-methylsulfanyl-1H-pyrimidin-6-one
    —— 1,1,2-tris-propylsulfanyl-ethene 66566-70-9 C11H22S3
    1,1,2-tris-propylsulfanyl-ethene
    —— 6-(ethylthio)-3-methyl[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole 958785-71-2 C6H8N4S2
    6-(ethylthio)-3-methyl[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole